Iodine atom
- Formula: I
- Molecular weight: 126.90447
- IUPAC Standard InChIKey: ZCYVEMRRCGMTRW-UHFFFAOYSA-N
- CAS Registry Number: 14362-44-8
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C12H4F3IO4W (g) + (g) = C12H4BrF3O4W (g) + (g)
By formula: C12H4F3IO4W (g) + Br (g) = C12H4BrF3O4W (g) + I (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -13. | kcal/mol | EqS | Fischer and Seitz, 1984 | The reaction enthalpy relies on a single measurement of the equilibrium constant in 1,1,2-trichloroethane (at 263 K) for the reaction W(CO)4(CC6H4CF3)(I)(solution) + Br(-)(solution) = W(CO)4(CC6H4CF3)(Br)(solution) + I(-)(solution), and on solvation and electron affinity data. It assumes that the reaction entropy is negligible Fischer and Seitz, 1984; MS |
C12H7IO4W (g) + (g) = C12H7BrO4W (g) + (g)
By formula: C12H7IO4W (g) + Br (g) = C12H7BrO4W (g) + I (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -13. | kcal/mol | EqS | Fischer and Seitz, 1984 | The reaction enthalpy relies on a single measurement of the equilibrium constant in 1,1,2-trichloroethane (at 263 K) for the reaction W(CO)4(CC6H4Me)(I)(solution) + Br(-)(solution) = W(CO)4(CC6H4Me)(Br)(solution) + I(-)(solution), and on solvation and electron affinity data. It assumes that the reaction entropy is negligible Fischer and Seitz, 1984; MS |
C11H5IO4W (g) + (g) = C11H5BrO4W (g) + (g)
By formula: C11H5IO4W (g) + Br (g) = C11H5BrO4W (g) + I (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -13. | kcal/mol | EqS | Fischer and Seitz, 1984 | The reaction enthalpy relies on a single measurement of the equilibrium constant in 1,1,2-trichloroethane (at 263 K) for the reaction W(CO)4(CPh)(I)(solution) + Br(-)(solution) = W(CO)4(CPh)(Br)(solution) + I(-)(solution), and on solvation and electron affinity data. It assumes that the reaction entropy is negligible Fischer and Seitz, 1984; MS |
By formula: (I2- • 4294967295I) + I = I2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 23.79 ± 0.17 | kcal/mol | N/A | Zanni, Taylor, et al., 1997 | gas phase; B |
By formula: C2H4ClI = I + Cl + C2H4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 76.5 ± 1.0 | kcal/mol | Kin | Minton, Felder, et al., 1984 | gas phase; ALS |
By formula: I (g) + H4Ge (g) = HI (g) + H3Ge (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.2 ± 0.98 | kcal/mol | KinG | Noble and Walsh, 1983 | MS |
(g) + C3H10Ge (g) = C3H9Ge (g) + (g)
By formula: I (g) + C3H10Ge (g) = C3H9Ge (g) + HI (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.0 ± 0.43 | kcal/mol | KinG | Doncaster and Walsh, 1979 | MS |
C4BrClO4Re + = C4BrIO4Re-
By formula: C4BrClO4Re + I = C4BrIO4Re-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >57.20 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
C4ClO4Re + = C4ClIO4Re-
By formula: C4ClO4Re + I = C4ClIO4Re-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >57.20 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
C4BrIMnO4 + = C4BrIMnO4-
By formula: C4BrIMnO4 + I = C4BrIMnO4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >55.00 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
C4ClIMnO4 + = C4ClIMnO4-
By formula: C4ClIMnO4 + I = C4ClIMnO4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >55.00 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
C6H5O3Re + = C6H5IO3Re-
By formula: C6H5O3Re + I = C6H5IO3Re-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >57.20 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
CAS Reg. No. 121175-69-7 + = C6H5IMnO3-
By formula: CAS Reg. No. 121175-69-7 + I = C6H5IMnO3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >57.20 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
By formula: C5CrO5- + I = C5CrIO5-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >57.20 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
By formula: C3NiO3- + I = C3INiO3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >55.00 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
By formula: C4FeO4- + I = C4FeIO4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >55.00 | kcal/mol | IMRB | Jones, McDonald, et al., 1989 | gas phase; B |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Fischer and Seitz, 1984
Fischer, H.; Seitz, F.,
J. Organometal. Chem., 1984, 268, 247. [all data]
Zanni, Taylor, et al., 1997
Zanni, M.T.; Taylor, T.R.; Greenblatt, J.; Soep, B.; Neumark, D.M.,
Characterization of the I2- Anion Ground State Using Conventional and Femtosecond Photoelectron Spectroscopy,
J. Chem. Phys., 1997, 107, 19, 7613, https://doi.org/10.1063/1.475110
. [all data]
Minton, Felder, et al., 1984
Minton, T.K.; Felder, P.; Brudzynski, R.J.; Lee, Y.T.,
Photodissociation of 1,2-chloroiodoethane at 248 and 266 nm: The enthalpy of formation of CH2ClCH2I,
J. Chem. Phys., 1984, 81, 1759-1769. [all data]
Noble and Walsh, 1983
Noble, P.N.; Walsh, R.,
Kinetics of the gas phase reaction between iodine and monogermane and the bond dissociation energy D(H3Ge-H),
Int. J. Chem. Kinet., 1983, 15, 547. [all data]
Doncaster and Walsh, 1979
Doncaster, A.M.; Walsh, R.,
J. Phys. Chem., 1979, 83, 578. [all data]
Jones, McDonald, et al., 1989
Jones, M.T.; McDonald, R.N.; Schell, P.L.; Ali, M.H.,
Kinetics and Mechanism of Halogen Atom Transfer Reactions between Haloalkanes and Several 17-Electron Transition Metal Complex Negative Ions in the Gas Phase,
J. Am. Chem. Soc., 1989, 111, 16, 5983, https://doi.org/10.1021/ja00198a001
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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