Manganese ion (1+)

• Formula: Mn⁺
• Molecular weight: 54.937496
• IUPAC Standard InChI: InChI=1S/Mn/q+1 Copy

  
• IUPAC Standard InChIKey: LIASWTUFJMBWEN-UHFFFAOYSA-N Copy
• CAS Registry Number: 14127-69-6
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Manganese cation
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Ion clustering data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
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Ion clustering data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 +  = ( • )

By formula: Mn⁺ + CH₃ = (Mn⁺ • CH₃)

 +  = ( • )

By formula: Mn⁺ + CO = (Mn⁺ • CO)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Mn⁺ • CO) + CO = (Mn⁺ • 2CO)

Enthalpy of reaction

( • 2) +  = ( • 3)

By formula: (Mn⁺ • 2CO) + CO = (Mn⁺ • 3CO)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Mn⁺ • 3CO) + CO = (Mn⁺ • 4CO)

Enthalpy of reaction

( • 4) +  = ( • 5)

By formula: (Mn⁺ • 4CO) + CO = (Mn⁺ • 5CO)

Enthalpy of reaction

( • 5) +  = ( • 6)

By formula: (Mn⁺ • 5CO) + CO = (Mn⁺ • 6CO)

Enthalpy of reaction

 +  = ( • )

By formula: Mn⁺ + CS = (Mn⁺ • CS)

 +  = ( • )

By formula: Mn⁺ + C₂H₄ = (Mn⁺ • C₂H₄)

( • ) +  = ( • 2)

By formula: (Mn⁺ • C₂H₄) + C₂H₄ = (Mn⁺ • 2C₂H₄)

 +  = ( • )

By formula: Mn⁺ + C₃D₆O = (Mn⁺ • C₃D₆O)

 +  = ( • )

By formula: Mn⁺ + C₃H₆O = (Mn⁺ • C₃H₆O)

 +  = ( • )

By formula: Mn⁺ + C₄H₄N₂ = (Mn⁺ • C₄H₄N₂)

 +  = ( • )

By formula: Mn⁺ + C₄H₅N = (Mn⁺ • C₄H₅N)

( • ) +  = ( • 2)

By formula: (Mn⁺ • C₄H₅N) + C₄H₅N = (Mn⁺ • 2C₄H₅N)

 +  = ( • )

By formula: Mn⁺ + C₅H₅N = (Mn⁺ • C₅H₅N)

 +  = ( • )

By formula: Mn⁺ + C₅H₅N₅ = (Mn⁺ • C₅H₅N₅)

 +  = ( • )

By formula: Mn⁺ + C₆H₆ = (Mn⁺ • C₆H₆)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Mn⁺ • C₆H₆) + C₆H₆ = (Mn⁺ • 2C₆H₆)

Enthalpy of reaction

 +  = ( • )

By formula: Mn⁺ + H₂O = (Mn⁺ • H₂O)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Mn⁺ • H₂O) + H₂O = (Mn⁺ • 2H₂O)

Enthalpy of reaction

( • 2) +  = ( • 3)

By formula: (Mn⁺ • 2H₂O) + H₂O = (Mn⁺ • 3H₂O)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Mn⁺ • 3H₂O) + H₂O = (Mn⁺ • 4H₂O)

Enthalpy of reaction

 +  = ( • )

By formula: Mn⁺ + H₃N = (Mn⁺ • H₃N)

( • ) +  = ( • 2)

By formula: (Mn⁺ • H₃N) + H₃N = (Mn⁺ • 2H₃N)

( • 2) +  = ( • 3)

By formula: (Mn⁺ • 2H₃N) + H₃N = (Mn⁺ • 3H₃N)

( • 3) +  = ( • 4)

By formula: (Mn⁺ • 3H₃N) + H₃N = (Mn⁺ • 4H₃N)

 +  = ( • )

By formula: Mn⁺ + Mn = (Mn⁺ • Mn)

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Georgiadis and Armentrout, 1989
Georgiadis, R.; Armentrout, P.B., Translational and Electronic Energy Dependence of the Reaction of Mn+ with Ethane, Int. J. Mass Spectrom. Ion Proc., 1989, 91, 2, 123, https://doi.org/10.1016/0168-1176(89)83003-4 . [all data]

Dearden, Hayashibara, et al., 1989
Dearden, D.V.; Hayashibara, K.; Beauchamp, J.L.; Kirschner, N.J.; Van Koppen, P.A.M.; Bowers, M.T., Fundamental Studies of the Energetics and Dynamics of Ligand Dissociation and Exchange Processes at Transition - Metal Centers in the Gas Phase: Mn(COx)+, x = 1 - 6, J. Am. Chem. Soc., 1989, 111, 7, 2401, https://doi.org/10.1021/ja00189a005 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of the State-Specific Reactions of Cr+ and Mn+ with CS2 and COS, Int. J. Mass Spectrom., 2001, 210/211, 283, https://doi.org/10.1016/S1387-3806(01)00400-6 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Lin, Chen, et al., 1997
Lin, C.-Y.; Chen, Q.; Chen, H.; Freiser, B.S., Bond Dissociation Energy Determinations for MOC(CH3)2+ and MOC(CD3)2+ (M=Cr, Mn) Using Continuous Ejection and Radiative Association Methods, Int. J. Mass Spectrom. Ion Proc., 1997, 167/168, 713, https://doi.org/10.1016/S0168-1176(97)00131-6 . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Lin, Chen, et al., 1997, 2
Lin, C.-Y.; Chen, Q.; Chen, H.; Freiser, B.S., Observing Unimolecular Dissociation of Metastable Ions in FT-ICR: A Novel Application of the Continuous Ejection Technique, J. Phys. Chem. A, 1997, 101, 34, 6023, https://doi.org/10.1021/jp970446a . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Houriet and Vulpius, 1989
Houriet, R.; Vulpius, T., Formation of Metal Cluster Ions by Gas - Phase Ion - Molecule Reactions: the Bond Energies of Cr2+ and Mn2+, Chem. Phys. Lett., 1989, 154, 5, 454, https://doi.org/10.1016/0009-2614(89)87130-1 . [all data]

Jarrold, Illies, et al., 1985
Jarrold, M.F.; Illies, A.J.; Wagner-Redeker, W.; Bowers, M.T., Photodissociation of Weakly Bound Ion - Molecule Clusters: The Kr.CO2+ Cluster, J. Phys. Chem., 1985, 89, 15, 3269, https://doi.org/10.1021/j100261a020 . [all data]

Ervin, Loh, et al., 1983
Ervin, K.; Loh, S.K.; Aristov, N.; Armentrout, P.B., Metal cluster ions: The bond energy of Mn₂⁺, J. Phys. Chem., 1983, 87, 3593. [all data]

Notes

Go To: Top, Ion clustering data, References

• Symbols used in this document:
  

  T	Temperature
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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