Nickel tetracarbonyl
- Formula: C4NiO4
- Molecular weight: 170.7338
- IUPAC Standard InChI: InChI=1S/4CO.Ni/c4*1-2;
- IUPAC Standard InChIKey: AWDHUGLHGCVIEG-UHFFFAOYSA-N
- CAS Registry Number: 13463-39-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Nickel carbonyl (Ni(CO)4); Nickel carbonyl (Ni(CO)4), (T-4)-; Nickel carbonyl; Tetracarbonyl nickel; Ni(CO)4; Nickel carbonyle; Nichel tetracarbonile; Nikkeltetracarbonyl; Nickel tetracarbonyle; Rcra waste number P073; UN 1259
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Gas phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -143.78 | kcal/mol | Review | Chase, 1998 | Data last reviewed in March, 1978 |
| ΔfH°gas | -142.2 ± 1.0 | kcal/mol | Review | Martinho Simões | MS |
| ΔfH°gas | -144.8 ± 1.1 | kcal/mol | Review | Martinho Simões | MS |
| ΔfH°gas | -144.0 ± 0.62 | kcal/mol | Review | Martinho Simões | MS |
| Quantity | Value | Units | Method | Reference | Comment |
| S°gas,1 bar | 99.314 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in March, 1978 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 700. to 1500. | 1500. to 6000. |
|---|---|---|
| A | 33.98279 | 48.43760 |
| B | 17.48360 | 0.675459 |
| C | -7.026231 | -0.108995 |
| D | 0.884686 | 0.007077 |
| E | -0.258372 | -4.396511 |
| F | -155.4940 | -167.6980 |
| G | 134.0780 | 145.7150 |
| H | -143.7800 | -143.7800 |
| Reference | Chase, 1998 | Chase, 1998 |
| Comment | Data last reviewed in March, 1978 | Data last reviewed in March, 1978 |
References
Go To: Top, Gas phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Notes
Go To: Top, Gas phase thermochemistry data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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