Acetic acid, sodium salt

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2Sodium hydroxide + acetyl fluoride = Acetic acid, sodium salt + sodium fluoride + Water

By formula: 2HNaO + C2H3FO = C2H3NaO2 + FNa + H2O

Quantity Value Units Method Reference Comment
Δr-56.15 ± 0.08kJ/molCmPritchard and Skinner, 1950liquid phase; Corrected for CODATA value of ΔfH; HF(100)
Δr-177.kJ/molCmCarson and Skinner, 1949liquid phase

Sodium hydroxide + Ketene = Acetic acid, sodium salt

By formula: HNaO + C2H2O = C2H3NaO2

Quantity Value Units Method Reference Comment
Δr-208.2 ± 1.6kJ/molCmNuttall, Laufer, et al., 1971gas phase
Δr-197.3kJ/molCmRice and Greenberg, 1934gas phase

Sodium hydroxide + Acetamide = Acetic acid, sodium salt + Ammonia

By formula: HNaO + C2H5NO = C2H3NaO2 + H3N

Quantity Value Units Method Reference Comment
Δr-45.6kJ/molCmCalvet, 1933solid phase; Heat of hydrolysis

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pritchard and Skinner, 1950
Pritchard, H.O.; Skinner, H.A., The heat of hydrolysis of acetyl fluoride, J. Chem. Soc., 1950, 1099. [all data]

Carson and Skinner, 1949
Carson, A.S.; Skinner, H.A., 201. Carbon-halogen bond energies in the acetyl halides, J. Chem. Soc., 1949, 936-939. [all data]

Nuttall, Laufer, et al., 1971
Nuttall, R.L.; Laufer, A.H.; Kilday, M.V., The enthalpy of formation of ketene, J. Chem. Thermodyn., 1971, 3, 167-174. [all data]

Rice and Greenberg, 1934
Rice, F.O.; Greenberg, J., Ketene. III. Heat of formation and heat of reaction with alcohols, J. Am. Chem. Soc., 1934, 38, 2268-2270. [all data]

Calvet, 1933
Calvet, E., Mesures thermochimiques directes en chimie organique vitesses et chaleurs de saponification des amides. II.-Mesures effectuees et resultats obtenus, J. Chim. Phys., 1933, 30, 140-146. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References