FCO anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

CFO- + Hydrogen cation = CHFO

By formula: CFO- + H+ = CHFO

Quantity Value Units Method Reference Comment
Δr1475. ± 19.kJ/molEIAEKarpas and Klein, 1977gas phase; From HCOF. G3MP2B3 calculations indicate an EA of ca. 2.3 eV, HOF(A-) 7 kcal/mol less stable.
Δr1463. ± 14.kJ/molAcidThynne and MacNeil, 1970gas phase; From CF2O

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Karpas and Klein, 1977
Karpas, Z.; Klein, F.S., The gas phase ion chemistry of carbonyl compounds: Formyl fluoride and a binary mixture of H2CO-F2CO or H2CO-Cl2CO, Int. J. Mass Spectrom. Ion Phys., 1977, 24, 137. [all data]

Thynne and MacNeil, 1970
Thynne, J.C.J.; MacNeil, K.A.G., Ionisation and dissociation of carbonyl fluoride and trifluoromethyl hypofluorite by electron impact, Intern. J. Mass Spectrom. Ion Phys., 1970, 5, 95. [all data]


Notes

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