Carbon disulfide, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

CHS2+ + Carbon disulfide = (CHS2+ • Carbon disulfide)

By formula: CHS2+ + CS2 = (CHS2+ • CS2)

Quantity Value Units Method Reference Comment
Δr38.kJ/molPHPMSHiraoka, Fujimaki, et al., 1993gas phase
Δr46.4kJ/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase
Quantity Value Units Method Reference Comment
Δr60.7J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase
Δr110.J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase

(CHS2+ • Carbon disulfide) + Carbon disulfide = (CHS2+ • 2Carbon disulfide)

By formula: (CHS2+ • CS2) + CS2 = (CHS2+ • 2CS2)

Quantity Value Units Method Reference Comment
Δr20.kJ/molPHPMSHiraoka, Fujimaki, et al., 1993gas phase
Quantity Value Units Method Reference Comment
Δr59.8J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Fujimaki, et al., 1993
Hiraoka, K.; Fujimaki, S.; Aruga, K., Proton-Held Dimer and Trimer of Carbon Disulfide, Chem. Phys. Lett., 1993, 202, 1-2, 167, https://doi.org/10.1016/0009-2614(93)85367-W . [all data]

Meot-Ner (Mautner) and Field, 1977
Meot-Ner (Mautner), M.; Field, F.H., Proton Affinity and Ion - Molecule Clustering in CO2 and CS2. Applications in Martian Ionospheric Chemistry, J. Chem. Phys., 1977, 66, 10, 4527, https://doi.org/10.1063/1.433706 . [all data]


Notes

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