Ru(Cp*)(PMe3)2(H)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C16H34OP2Ru (solution) + Hydrogen (solution) = C16H34P2Ru (solution) + Water (solution)

By formula: C16H34OP2Ru (solution) + H2 (solution) = C16H34P2Ru (solution) + H2O (solution)

Quantity Value Units Method Reference Comment
Δr-24.7 ± 3.3kJ/molEqSBryndza, Fong, et al., 1987solvent: Tetrahydrofuran; The reaction enthalpy was identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987

C16H34P2Ru (solution) + Methane, iodo- (solution) = C16H33IP2Ru (solution) + Methane (solution)

By formula: C16H34P2Ru (solution) + CH3I (solution) = C16H33IP2Ru (solution) + CH4 (solution)

Quantity Value Units Method Reference Comment
Δr-188.3 ± 2.9kJ/molRSCLuo, Li, et al., 1995solvent: Tetrahydrofuran

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bryndza, Fong, et al., 1987
Bryndza, H.E.; Fong, L.K.; Paciello, R.A.; Tam, W.; Bercaw, J.E., J. Am. Chem. Soc., 1987, 109, 1444. [all data]

Luo, Li, et al., 1995
Luo, L.; Li, C.; Cucullu, M.E.; Nolan, S.P., Organometallics, 1995, 14, 1333. [all data]


Notes

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