Isothermal Properties for Hydrogen

Fluid Data

Isothermal Data for T = 15.000 C

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Auxiliary Data

Reference States, Normal Boiling Point Convention

Additional fluid properties

References and Notes

Equation of state

Leachman, J.W.; Jacobsen, R.T.; Penoncello, S.G.; Lemmon, E.W., Fundamental Equations of State for Parahydrogen, Normal Hydrogen, and Orthohydrogen, J. Phys. Chem. Ref. Data, 2009, 38, 3, 721-748, https://doi.org/10.1063/1.3160306 . [all data]

Leachman, J.W., Jacobsen, R.T, Penoncello, S.G., and Lemmon, E.W., "Fundamental Equations of State for Parahydrogen, Normal Hydrogen, and Orthohydrogen," J. Phys. Chem. Ref. Data, 38(3):721-748, 2009.

The uncertainty in density is 0.1% at temperatures from the triple point to 250 K and at pressures up to 40 MPa, except in the critical region, where an uncertainty of 0.2% in pressure is generally attained. In the region between 250 and 450 K and at pressures to 300 MPa, the uncertainty in density is 0.04%. At temperatures between 450 and 1000 K, the uncertainty in density increases to 1%. At pressures between 300 and 2000 MPa, the uncertainty in density is 8%. Speed of sound data are represented within 0.5% below 100 MPa. The estimated uncertainty for heat capacities is 1.0%. The estimated uncertainties of vapor pressures and saturated liquid densities calculated with the Maxwell criterion are 0.2% for each property.

Auxillary model, Cp0

Leachman, J.W., Jacobsen, R.T, Penoncello, S.G., and Lemmon, E.W., 2009.

Auxillary model, PX0

Leachman, J.W., Jacobsen, R.T, Penoncello, S.G., and Lemmon, E.W., 2009.

Auxillary model, PH0

Leachman, J.W., Jacobsen, R.T, Penoncello, S.G., and Lemmon, E.W., 2009.

Viscosity

Muzny, C.D.; Huber, M.L.; Kazakov, A.F., Correlation for the Viscosity of Normal Hydrogen Obtained from Symbolic Regression, J. Chem. Eng. Data, 2013, 58, 4, 969-979, https://doi.org/10.1021/je301273j . [all data]

Muzny, C.D., Huber, M.L., and Kazakov, A.F., "Correlation for the Viscosity of Normal Hydrogen Obtained from Symbolic Regression," J. Chem. Eng. Data, 58:969-979, 2013.

The estimated uncertainty is 4% for the saturated liquid from the triple point to 31 K, with larger deviations as the critical region is approached. The estimated uncertainty is 4% for the supercritical fluid phase at pressures to 200 MPa. For the limited range of 200 K to 400 K at pressures up to 0.1 MPa, the uncertainty is 0.1%.

Thermal conductivity

Assael, M.J.; Assael, J.-A.M.; Huber, M.L.; Perkins, R.A.; Takata, Y., Correlation of the Thermal Conductivity of Normal and Parahydrogen from the Triple Point to 1000 K and up to 100 MPa, J. Phys. Chem. Ref. Data, 2011, 40, 3, 033101, https://doi.org/10.1063/1.3606499 . [all data]

Assael, M.J., Assael, J.-A.M., Huber, M.L., Perkins, R.A., and Takata, Y., "Correlation of the Thermal Conductivity of Normal and Parahydrogen from the Triple Point to 1000 K and up to 100 MPa," J. Phys. Chem. Ref. Data, 40(3), 033101, 2011.

The estimated uncertainty is less than 4% from 100 K to 1000 K at pressures to 100 MPa. For temperatures from the triple point to 100 K, at pressures to 12 MPa, we estimate the uncertainty to be 7%, except near the critical point. The model behaves in a physically reasonable manner for extrapolations to pressures above 12 MPa at temperatures below 100 K, but will be subject to larger uncertainties.

Auxillary model, the thermal conductivity critical enhancement

Assael, M.J., Assael, J.-A.M., Huber, M.L., Perkins, R.A., and Takata, Y., 2011.

Surface tension

Mulero, A.; Cachadiña, I.; Parra, M.I., Recommended Correlations for the Surface Tension of Common Fluids, J. Phys. Chem. Ref. Data, 2012, 41, 4, 043105, https://doi.org/10.1063/1.4768782 . [all data]

Dielectric constant

Harvey, A.H.; Lemmon, E.W., Method for Estimating the Dielectric Constant of Natural Gas Mixtures, Int. J. Thermophys., 2005, 26, 1, 31-46, https://doi.org/10.1007/s10765-005-2351-5 . [all data]

Metling line

Preliminary equation, 2007.

Sublimation line

Lemmon, E.W., 2003.

Vapor pressure

Functional Form: P=Pc*EXP[SUM(Ni*Theta^ti)*Tc/T] where Theta=1-T/Tc, Tc and Pc are the reducing parameters below, which are followed by rows containing Ni and ti.

Saturated liquid density

Lemmon, C.K. and Lemmon, E.W., 2010.

Functional Form: D=Dc*[1+SUM(Ni*Theta^ti)] where Theta=1-T/Tc, Tc and Dc are the reducing parameters below, which are followed by rows containing Ni and ti.

Saturated liquid volume

Lemmon, C.K. and Lemmon, E.W., 2010.

Functional Form: D=Dc*EXP[SUM(Ni*Theta^ti)] where Theta=1-T/Tc, Tc and Dc are the reducing parameters below, which are followed by rows containing Ni and ti.

The fluid data above is also available from the NIST Reference Fluid Thermodynamic and Transport Properties Database. This product includes additional features not available from this web site.

Notes