Saturation Properties for Methane — Temperature Increments

The following adjustments were made to the specified data range:

Liquid Phase Data

Data on Saturation Curve

Temperature (F)Pressure (psia)Density (lbm/ft3)Volume (ft3/lbm)Internal Energy (Btu/lbm)Enthalpy (Btu/lbm)Entropy (Btu/lbm*R)Cv (Btu/lbm*R)Cp (Btu/lbm*R)Sound Spd. (ft/s)Joule-Thomson (F/psia)Viscosity (cP)Therm. Cond. (W/m*K)Surf. Tension (lb/ft)Phase
-260.0013.82226.4340.037830-1.2071-1.1103-0.00551150.492310.830734414.3-0.00520600.118580.184730.00089524liquid
-259.7713.97226.4220.037847-1.0137-0.91578-0.00454320.492170.830954410.1-0.00519930.118260.184550.00089350liquid
-259.5314.12426.4100.037864-0.82023-0.72121-0.00357580.492030.831174405.8-0.00519260.117940.184370.00089176liquid
-259.3014.27626.3990.037881-0.62672-0.52658-0.00260920.491880.831394401.6-0.00518590.117620.184190.00089003liquid
-259.0714.43026.3870.037898-0.43317-0.33190-0.00164360.491740.831624397.3-0.00517910.117310.184010.00088829liquid
-258.8314.58626.3750.037915-0.23956-0.13716-0.000678820.491600.831844393.1-0.00517230.116990.183830.00088656liquid
-258.6014.74226.3630.037931-0.0459140.0576350.000285070.491450.832074388.8-0.00516540.116680.183650.00088482liquid
-258.3714.90026.3520.0379480.147780.252490.00124810.491310.832294384.6-0.00515860.116360.183470.00088309liquid
-258.1315.06026.3400.0379660.341530.447400.00221020.491170.832524380.3-0.00515170.116050.183290.00088135liquid
-257.9015.22026.3280.0379830.535320.642370.00317150.491030.832744376.1-0.00514480.115740.183110.00087962liquid
-257.6715.38226.3160.0380000.729160.837400.00413180.490890.832974371.8-0.00513780.115430.182920.00087789liquid
-257.4315.54526.3040.0380170.923051.03250.00509130.490740.833204367.6-0.00513090.115120.182740.00087615liquid
-257.2015.71026.2920.0380341.11701.22760.00605000.490600.833434363.3-0.00512390.114820.182560.00087442liquid
-256.9715.87526.2800.0380511.31101.42280.00700780.490460.833664359.0-0.00511680.114510.182380.00087269liquid
-256.7316.04326.2690.0380681.50501.61810.00796470.490320.833894354.8-0.00510980.114200.182200.00087096liquid
-256.5016.21126.2570.0380861.69911.81340.00892080.490180.834134350.5-0.00510270.113900.182020.00086922liquid
-256.2716.38126.2450.0381031.89322.00880.00987600.490040.834364346.2-0.00509560.113600.181840.00086749liquid
-256.0316.55226.2330.0381202.08742.20420.0108300.489900.834594342.0-0.00508840.113300.181650.00086576liquid
-255.8016.72526.2210.0381372.28162.39970.0117840.489760.834834337.7-0.00508130.112990.181470.00086403liquid
-255.5716.89926.2090.0381552.47592.59530.0127360.489620.835064333.4-0.00507410.112690.181290.00086230liquid
-255.3317.07426.1970.0381722.67022.79090.0136880.489480.835304329.1-0.00506680.112400.181110.00086057liquid
-255.1017.25126.1850.0381892.86462.98660.0146390.489340.835544324.8-0.00505960.112100.180930.00085884liquid
-254.8717.42926.1730.0382073.05903.18230.0155890.489200.835774320.6-0.00505230.111800.180750.00085711liquid
-254.6317.60926.1610.0382243.25353.37810.0165390.489060.836014316.3-0.00504500.111510.180560.00085538liquid
-254.4017.79026.1490.0382423.44803.57400.0174870.488920.836254312.0-0.00503760.111210.180380.00085366liquid
-254.1717.97226.1370.0382593.64263.76990.0184350.488780.836494307.7-0.00503030.110920.180200.00085193liquid
-253.9318.15626.1250.0382773.83723.96590.0193820.488640.836744303.4-0.00502290.110630.180020.00085020liquid
-253.7018.34126.1130.0382944.03194.16190.0203280.488500.836984299.1-0.00501540.110330.179830.00084847liquid
-253.4718.52826.1010.0383124.22664.35800.0212730.488360.837224294.8-0.00500800.110040.179650.00084675liquid
-253.2318.71626.0890.0383304.42144.55420.0222170.488220.837474290.5-0.00500050.109750.179470.00084502liquid
-253.0018.90526.0770.0383474.61624.75040.0231610.488080.837714286.2-0.00499290.109470.179290.00084329liquid
-252.7719.09626.0650.0383654.81114.94670.0241030.487940.837964281.9-0.00498540.109180.179110.00084157liquid
-252.5319.28926.0530.0383835.00605.14310.0250450.487810.838204277.6-0.00497780.108890.178920.00083984liquid
-252.3019.48326.0410.0384005.20105.33950.0259860.487670.838454273.3-0.00497020.108610.178740.00083812liquid
-252.0719.67826.0290.0384185.39605.53600.0269260.487530.838704269.0-0.00496250.108320.178560.00083639liquid
-251.8319.87526.0170.0384365.59115.73250.0278660.487390.838954264.7-0.00495480.108040.178370.00083467liquid
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-249.9721.50625.9200.0385807.15367.30720.0353530.486300.840984230.1-0.00489220.105800.176910.00082089liquid
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-249.5021.92925.8960.0386167.54477.70150.0372170.486030.841504221.4-0.00487630.105250.176540.00081746liquid
-249.2722.14325.8840.0386347.74047.89880.0381470.485890.841764217.1-0.00486820.104980.176360.00081574liquid
-249.0322.35825.8720.0386527.93618.09610.0390770.485760.842024212.8-0.00486010.104710.176180.00081402liquid
-248.8022.57525.8600.0386708.13188.29350.0400070.485620.842284208.4-0.00485200.104430.176000.00081230liquid
-248.5722.79425.8470.0386898.32768.49090.0409350.485490.842544204.1-0.00484390.104160.175810.00081058liquid
-248.3323.01425.8350.0387078.52358.68850.0418630.485350.842814199.7-0.00483570.103890.175630.00080886liquid
-248.1023.23625.8230.0387258.71948.88610.0427900.485220.843074195.4-0.00482750.103630.175440.00080715liquid
-247.8723.46025.8110.0387438.91549.08370.0437160.485080.843344191.0-0.00481930.103360.175260.00080543liquid
-247.6323.68525.7990.0387629.11149.28140.0446410.484950.843614186.7-0.00481100.103090.175080.00080371liquid
-247.4023.91225.7860.0387809.30759.47920.0455660.484810.843874182.3-0.00480270.102820.174890.00080200liquid
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-246.0025.30725.7130.03889110.48510.6670.0510980.484010.845504156.2-0.00475210.101240.173790.00079171liquid
-245.7725.54525.7000.03891010.68210.8660.0520170.483880.845784151.8-0.00474350.100980.173610.00079000liquid
-245.5325.78525.6880.03892910.87811.0640.0529360.483740.846064147.4-0.00473500.100720.173420.00078829liquid
-245.3026.02725.6760.03894711.07511.2620.0538540.483610.846334143.1-0.00472630.100460.173240.00078658liquid
-245.0726.27125.6630.03896611.27111.4610.0547710.483480.846614138.7-0.00471770.100210.173060.00078487liquid
-244.8326.51625.6510.03898511.46811.6590.0556880.483350.846894134.3-0.00470900.0999500.172870.00078316liquid
-244.6026.76325.6390.03900311.66511.8580.0566030.483210.847174129.9-0.00470020.0996930.172690.00078145liquid
-244.3727.01225.6260.03902211.86212.0570.0575180.483080.847454125.6-0.00469140.0994380.172500.00077974liquid
-244.1327.26225.6140.03904112.05812.2560.0584330.482950.847744121.2-0.00468260.0991830.172320.00077803liquid
-243.9027.51425.6020.03906012.25512.4540.0593460.482820.848024116.8-0.00467380.0989290.172140.00077632liquid
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-243.2028.28125.5640.03911712.84713.0510.0620830.482420.848884103.6-0.00464700.0981720.171580.00077120liquid
-242.9728.54125.5520.03913613.04413.2510.0629930.482290.849174099.2-0.00463800.0979220.171400.00076949liquid
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-242.5029.06525.5270.03917413.43813.6490.0648130.482030.849754090.4-0.00461990.0974220.171030.00076608liquid
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Vapor Phase Data

Data on Saturation Curve

Temperature (F)Pressure (psia)Density (lbm/ft3)Volume (ft3/lbm)Internal Energy (Btu/lbm)Enthalpy (Btu/lbm)Entropy (Btu/lbm*R)Cv (Btu/lbm*R)Cp (Btu/lbm*R)Sound Spd. (ft/s)Joule-Thomson (F/psia)Viscosity (cP)Therm. Cond. (W/m*K)Phase
-260.0013.8220.107199.3292195.35219.231.09800.385560.52870888.540.373940.00429770.011314vapor
-259.7713.9720.108269.2371195.43219.331.09720.385640.52893888.910.373030.00430240.011331vapor
-259.5314.1240.109349.1461195.50219.421.09640.385720.52916889.280.372140.00430700.011349vapor
-259.3014.2760.110429.0563195.57219.511.09560.385800.52940889.640.371240.00431160.011367vapor
-259.0714.4300.111518.9675195.64219.611.09470.385880.52963890.010.370350.00431620.011385vapor
-258.8314.5860.112618.8798195.71219.701.09390.385960.52987890.370.369460.00432080.011402vapor
-258.6014.7420.113728.7932195.79219.791.09310.386040.53011890.730.368580.00432550.011420vapor
-258.3714.9000.114848.7076195.86219.881.09230.386120.53035891.100.367710.00433010.011438vapor
-258.1315.0600.115978.6231195.93219.981.09150.386200.53059891.450.366830.00433470.011456vapor
-257.9015.2200.117108.5396196.00220.071.09070.386290.53083891.810.365960.00433940.011474vapor
-257.6715.3820.118248.4571196.07220.161.08990.386370.53107892.170.365100.00434400.011492vapor
-257.4315.5450.119398.3756196.15220.251.08910.386450.53132892.530.364240.00434860.011510vapor
-257.2015.7100.120558.2950196.22220.351.08830.386530.53156892.880.363380.00435330.011528vapor
-256.9715.8750.121728.2155196.29220.441.08750.386620.53181893.230.362530.00435790.011546vapor
-256.7316.0430.122908.1368196.36220.531.08670.386700.53206893.590.361680.00436260.011564vapor
-256.5016.2110.124088.0591196.43220.621.08590.386780.53231893.940.360840.00436720.011582vapor
-256.2716.3810.125287.9824196.50220.711.08510.386870.53256894.290.360000.00437180.011600vapor
-256.0316.5520.126487.9065196.57220.811.08430.386950.53281894.640.359160.00437650.011618vapor
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-254.4017.7900.135147.3998197.07221.441.07890.387540.53460897.040.353420.00440910.011746vapor
-254.1717.9720.136417.3308197.14221.531.07810.387630.53486897.380.352620.00441370.011764vapor
-253.9318.1560.137697.2626197.21221.621.07730.387710.53513897.720.351820.00441840.011782vapor
-253.7018.3410.138987.1951197.28221.711.07660.387800.53539898.050.351020.00442300.011801vapor
-253.4718.5280.140287.1285197.35221.801.07580.387890.53566898.390.350230.00442770.011819vapor
-253.2318.7160.141597.0626197.42221.891.07500.387970.53592898.720.349440.00443240.011837vapor
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-252.7719.0960.144246.9330197.56222.071.07350.388150.53646899.390.347870.00444170.011874vapor
-252.5319.2890.145576.8694197.62222.161.07270.388230.53673899.720.347090.00444640.011893vapor
-252.3019.4830.146926.8064197.69222.251.07200.388320.53700900.040.346320.00445100.011911vapor
-252.0719.6780.148276.7442197.76222.341.07120.388410.53728900.370.345550.00445570.011930vapor
-251.8319.8750.149646.6827197.83222.431.07050.388500.53755900.700.344780.00446040.011949vapor
-251.6020.0740.151016.6219197.90222.521.06970.388590.53783901.020.344020.00446510.011967vapor
-251.3720.2740.152406.5618197.97222.611.06900.388670.53810901.350.343260.00446970.011986vapor
-251.1320.4750.153796.5024198.04222.691.06820.388760.53838901.670.342500.00447440.012005vapor
-250.9020.6780.155196.4436198.11222.781.06750.388850.53866901.990.341750.00447910.012023vapor
-250.6720.8830.156606.3855198.18222.871.06680.388940.53894902.310.341000.00448380.012042vapor
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-247.8723.4600.174325.7367198.99223.911.05800.390030.54243906.040.332270.00454010.012269vapor
-247.6323.6850.175865.6864199.06224.001.05730.390130.54273906.350.331570.00454480.012288vapor
-247.4023.9120.177415.6367199.13224.091.05660.390220.54303906.650.330870.00454950.012307vapor
-247.1724.1400.178975.5875199.20224.171.05590.390310.54333906.950.330170.00455420.012326vapor
-246.9324.3700.180545.5389199.26224.261.05520.390410.54363907.250.329470.00455890.012345vapor
-246.7024.6020.182125.4908199.33224.341.05440.390500.54394907.550.328780.00456360.012365vapor
-246.4724.8350.183725.4432199.40224.431.05370.390590.54424907.840.328090.00456830.012384vapor
-246.2325.0700.185325.3961199.46224.511.05300.390690.54455908.140.327400.00457310.012403vapor
-246.0025.3070.186935.3495199.53224.601.05230.390780.54486908.430.326720.00457780.012422vapor
-245.7725.5450.188565.3034199.60224.681.05160.390880.54517908.730.326040.00458250.012442vapor
-245.5325.7850.190195.2578199.66224.771.05090.390970.54549909.020.325360.00458720.012461vapor
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-243.4328.0240.205394.8688200.26225.521.04470.391840.54837911.580.319400.00462980.012637vapor
-243.2028.2810.207134.8279200.32225.601.04400.391930.54870911.860.318760.00463450.012656vapor
-242.9728.5410.208884.7873200.39225.691.04330.392030.54903912.130.318110.00463930.012676vapor
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-241.8029.8640.217824.5909200.71226.101.03990.392530.55070913.500.314930.00466300.012775vapor
-241.5730.1340.219644.5528200.78226.181.03920.392620.55104913.770.314310.00466780.012795vapor
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Auxiliary Data

Reference States, Normal Boiling Point Convention

Additional fluid properties

References and Notes

Equation of state

Setzmann, U.; Wagner, W., A New Equation of State and Tables of Thermodynamic Properties for Methane Covering the Range from the Melting Line to 625 K at Pressures up to 1000 MPa, J. Phys. Chem. Ref. Data, 1991, 20, 6, 1061-1155, https://doi.org/10.1063/1.555898 . [all data]

Setzmann, U. and Wagner, W., "A New Equation of State and Tables of Thermodynamic Properties for Methane Covering the Range from the Melting Line to 625 K at Pressures up to 1000 MPa," J. Phys. Chem. Ref. Data, 20(6):1061-1151, 1991.

The uncertainties in density are 0.03% for pressures below 12 MPa and temperatures below 350 K and up to 0.07% for pressures less than 50 MPa. For the speed of sound, the uncertainty ranges from 0.03% (in the vapor phase) to 0.3% depending on temperature and pressure. Heat capacities may be generally calculated within an uncertainty of 1%.

Auxillary model, Cp0

Setzmann, U. and Wagner, W., 1991.

Auxillary model, PX0

Setzmann, U. and Wagner, W., 1991.

Auxillary model, PH0

Setzmann, U. and Wagner, W., 1991.

Viscosity

Quinones-Cisneros, S.E., Huber, M.L., and Deiters, U.K., unpublished work, 2011.

Detailed uncertainty analysis will be found in a future publication; however in general the estimated uncertainty in viscosity varies from less than 0.3% between 200-400 K for pressures less than 30 MPa, to less than 2% over the rest of the fluid surface up to 100 MPa, increasing up to 5% for 100 to 500 MPa, and 10% at 500 to 1000 MPa for temperatures to 625 K. Above uncertainties are valid when used with the equation of state of Setzmann, U. and Wagner, W., J. Phys. Chem. Ref. Data, 20(6):1061-1151, 1991. The use of other equations of state may result in larger uncertainties.

Thermal conductivity

Friend, D.G., Ely, J.F., and Ingham, H., "Tables for the Thermophysical Properties of Methane," NIST Technical Note 1325, 1989.

The uncertainty in thermal conductivity of the dilute gas between 130 and 625 K is 2.5%. For temperatures below 130 K, the uncertainty is less than 10%. Excluding the dilute gas, the uncertainty is 2% between 110 and 725 K at pressures up to 70 MPa, except near the critical point which has an uncertainty of 5% or greater. For the vapor at lower temperatures and the dense liquid near the triple point, an uncertainty of 10% is possible.

Auxillary model, the thermal conductivity critical enhancement

Friend, D.G., Ely, J.F., and Ingham, H., 1989.

Surface tension

Mulero, A.; Cachadiña, I.; Parra, M.I., Recommended Correlations for the Surface Tension of Common Fluids, J. Phys. Chem. Ref. Data, 2012, 41, 4, 043105, https://doi.org/10.1063/1.4768782 . [all data]

Dielectric constant

Harvey, A.H.; Lemmon, E.W., Method for Estimating the Dielectric Constant of Natural Gas Mixtures, Int. J. Thermophys., 2005, 26, 1, 31-46, https://doi.org/10.1007/s10765-005-2351-5 . [all data]

Metling line

Setzmann, U.; Wagner, W., A New Equation of State and Tables of Thermodynamic Properties for Methane Covering the Range from the Melting Line to 625 K at Pressures up to 1000 MPa, J. Phys. Chem. Ref. Data, 1991, 20, 6, 1061-1155, https://doi.org/10.1063/1.555898 . [all data]

Setzmann, U. and Wagner, W., "A New Equation of State and Tables of Thermodynamic Properties for Methane Covering the Range from the Melting Line to 625 K at Pressures up to 1000 MPa," J. Phys. Chem. Ref. Data, 20(6):1061-1151, 1991.

Sublimation line

Lemmon, E.W., 2002.

Vapor pressure

Functional Form: P=Pc*EXP[SUM(Ni*Theta^ti)*Tc/T] where Theta=1-T/Tc, Tc and Pc are the reducing parameters below, which are followed by rows containing Ni and ti.

Saturated liquid density

Functional Form: D=Dc*EXP[SUM(Ni*Theta^(ti/3))] where Theta=1-T/Tc, Tc and Dc are the reducing parameters below, which are followed by rows containing Ni and ti.

Saturated liquid volume

Functional Form: D=Dc*EXP[SUM(Ni*Theta^(ti/3))] where Theta=1-T/Tc, Tc and Dc are the reducing parameters below, which are followed by rows containing Ni and ti.

The fluid data above is also available from the NIST Reference Fluid Thermodynamic and Transport Properties Database. This product includes additional features not available from this web site.

Notes