D-Mannitol

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus439.1KN/ABarone, DellaGatta, et al., 1990Uncertainty assigned by TRC = 0.1 K; TRC
Tfus439.KN/ASchwarz, Grundstein, et al., 1972Uncertainty assigned by TRC = 1. K; TRC
Tfus439.2KN/ASpaght, Thomas, et al., 1932Uncertainty assigned by TRC = 0.2 K; TRC
Tfus439.13KN/ABurriel, 1931Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Δsub48.3kcal/molBBarone, Gatta, et al., 1990AC

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
568.20.005Weast and Grasselli, 1989BS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
32.41 ± 0.26479.TEBarone, Gatta, et al., 1990Based on data from 458. - 501. K.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
13.408439.1N/ABarone and Della Gatta, 1990DH
12.806433.2N/ASpaght, Thomas, et al., 1932, 2DH
13.07437.3DSCTong, Liu, et al., 2010AC
13.4439.1DSCDomalski and Hearing, 1996See also Barone, Gatta, et al., 1990.; AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
30.54439.1Barone and Della Gatta, 1990DH
29.57433.2Spaght, Thomas, et al., 1932, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Barone, DellaGatta, et al., 1990
Barone, G.; DellaGatta, G.; Ferro, D.; Piacente, V., Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, J. Chem. Soc., Faraday Trans., 1990, 86, 75. [all data]

Schwarz, Grundstein, et al., 1972
Schwarz, E.M.; Grundstein, V.V.; Ievins, A.F., Thermal investigation off polyols: 1. hexitols and pentitols., J. Therm. Anal., 1972, 4, 331-7. [all data]

Spaght, Thomas, et al., 1932
Spaght, M.E.; Thomas, S.B.; Parks, G.S., Some heat capacity data on organic compounds obtained with a radiation calorimeter, J. Phys. Chem., 1932, 36, 882-8. [all data]

Burriel, 1931
Burriel, F., Physico-Chemical Study of Some Solid Organic Compounds at Ordinary Temperatures, and Their COrrelationo with Temperature, An. R. Soc. Esp. Fis. Quim., 1931, 29, 89. [all data]

Barone, Gatta, et al., 1990
Barone, Guido; Gatta, Giuseppe Della; Ferro, Daniela; Piacente, Vincenzo, Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, Faraday Trans., 1990, 86, 1, 75, https://doi.org/10.1039/ft9908600075 . [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Barone and Della Gatta, 1990
Barone, G.; Della Gatta, G., Ferro D., and Piacente, V., Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, J. Chem. Soc., Faraday Trans., 1990, 86(1), 75-79. [all data]

Spaght, Thomas, et al., 1932, 2
Spaght, M.E.; Thomas, S.B.; Parks, G.S., Some heat capacity data on organic compounds obtained with a radiation calorimeter, J. Phys. Chem., 1932, 36, 882-888. [all data]

Tong, Liu, et al., 2010
Tong, Bo; Liu, Rui-Bin; Meng, Chang-Gong; Yu, Feng-Yun; Ji, Shou-Hua; Tan, Zhi-Cheng, Heat Capacities and Nonisothermal Thermal Decomposition Reaction Kinetics of, J. Chem. Eng. Data, 2010, 55, 1, 119-124, https://doi.org/10.1021/je900285w . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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