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IrBr6 dianion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
0.960 ± 0.060LPESWang and Wang, 1999 Rensing, Ehrler, et al., 2009 time-resolved LPES indicates a Coulomb barrier of 0.93 eV to dissociation to Br- + IrBr5-

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang and Wang, 1999
Wang, X.B.; Wang, L.S., Photodetachment of free hexahalogenometallate doubly charged anions in the gas phase: [ML6](2-), (M=Re, Os, Ir, Pt; L=Cl and Br), J. Chem. Phys., 1999, 111, 10, 4497-4509, https://doi.org/10.1063/1.479213 . [all data]

Rensing, Ehrler, et al., 2009
Rensing, C.; Ehrler, O.T.; Yang, J.P.; Unterreiner, A.N.; Kappes, M.M., Photodissociation dynamics of IrBr62- dianions by time-resolved photoelectron spectroscopy, J. Chem. Phys., 2009, 130, 23, 234306, https://doi.org/10.1063/1.3148377 . [all data]


Notes

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