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2-Adamantanone

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-55.1 ± 1.1kcal/molCcbArora and Steele, 1978 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafsolid-74.3 ± 0.9kcal/molCcbArora and Steele, 1978 
Quantity Value Units Method Reference Comment
Deltacsolid-1344.4 ± 0.9kcal/molCcbArora and Steele, 1978Corresponding «DELTA»fsolid = -74.3 kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltavap14.5 ± 0.05kcal/molGCvan Roon, Parsons, et al., 2002AC
Quantity Value Units Method Reference Comment
Deltasub15.9 ± 0.07kcal/molCBazyleva, Blokhin, et al., 2006AC
Deltasub15.8 ± 0.2kcal/molMEBazyleva, Blokhin, et al., 2006Based on data from 280. - 333. K.; AC
Deltasub18.2 ± 0.36kcal/molN/AMiroshnichenko, Lebedev, et al., 2002See also Bazyleva, Blokhin, et al., 2006.; AC
Deltasub19.2 ± 0.6kcal/molVArora and Steele, 1978ALS
Deltasub19.2 ± 0.60kcal/molBGArora and Steele, 1978AC

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Method Reference Comment
2.813557.5DSCBazyleva, Blokhin, et al., 2006AC

Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 156033

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arora and Steele, 1978
Arora, M.; Steele, W.V., The standard enthalpies of formation of adamantanoid compounds 5. Adamantanols and adamantanone, J. Chem. Thermodyn., 1978, 10, 403-407. [all data]

van Roon, Parsons, et al., 2002
van Roon, André; Parsons, John R.; Govers, Harrie A.J., Gas chromatographic determination of vapour pressure and related thermodynamic properties of monoterpenes and biogenically related compounds, Journal of Chromatography A, 2002, 955, 1, 105-115, https://doi.org/10.1016/S0021-9673(02)00200-5 . [all data]

Bazyleva, Blokhin, et al., 2006
Bazyleva, Ala B.; Blokhin, Andrey V.; Kabo, Gennady J.; Kabo, Andrey G.; Sevruk, Viktor M., Thermodynamic properties of 2-adamantanone in the condensed and ideal gaseous states, Thermochimica Acta, 2006, 451, 1-2, 65-72, https://doi.org/10.1016/j.tca.2006.08.018 . [all data]

Miroshnichenko, Lebedev, et al., 2002
Miroshnichenko, E.A.; Lebedev, V.P.; Matyushin, Yu.N., Doklady Physical Chemistry, 2002, 382, 4/6, 40-42, https://doi.org/10.1023/A:1014499229527 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References