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As3


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

View reactions leading to As3+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
1.450 ± 0.030LPESLippa, Xu, et al., 1998 
0.84 ± 0.25R-ABennett, Margrave, et al., 1973From As4

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 2900 T gas Lippa, Xu, et al., 1998, 2

Additional references: Jacox, 2003, page 127

Notes

TTentative assignment or approximate value
xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lippa, Xu, et al., 1998
Lippa, T.P.; Xu, S.J.; Lyapustina, S.A.; Nilles, J.M.; Bowen, K.H., Photoelectron spectroscopy of As-, As-2(-), As-3(-), As-4(-), and As-5(-), J. Chem. Phys., 1998, 109, 24, 10727-10731, https://doi.org/10.1063/1.477771 . [all data]

Bennett, Margrave, et al., 1973
Bennett, S.L.; Margrave, J.L.; Franklin, J.L.; Hudson, J.E., High temperature negative ions: Electron impact of As4 vapor, J. Chem. Phys., 1973, 59, 5814. [all data]

Lippa, Xu, et al., 1998, 2
Lippa, T.P.; Xu, S.-J.; Lyapustina, S.A.; Nilles, J.M.; Bowen, K.H., Photoelectron spectroscopy of As[sup -], As[sub 2][sup -], As[sub 3][sup -], As[sub 4][sup -], and As[sub 5][sup -], J. Chem. Phys., 1998, 109, 24, 10727, https://doi.org/10.1063/1.477771 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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