Cyclooctyl alcohol

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
380.20.029Aldrich Chemical Company Inc., 1990BS

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
0.483291.2DSCSingh and Murthy, 2008AC
0.471297.1N/ARute, Salud, et al., 2003AC
0.492295.N/ASciesinski, Mayer, et al., 1995Authors did not report enthalpic data for all transitions; AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
1.94261.3Sciesinski, Mayer, et al., 1995, 2CAL
1.67295.0

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + Cyclooctanone = Cyclooctyl alcohol

By formula: H2 + C8H14O = C8H16O

Quantity Value Units Method Reference Comment
Δr-13.32kcal/molChydWiberg, Crocker, et al., 1991liquid phase
Δr-12.70kcal/molChydWiberg, Crocker, et al., 1991solid phase
Δr-9.31kcal/molChydWiberg, Crocker, et al., 1991gas phase
Δr-12.70 ± 0.14kcal/molCmWiberg, Crocker, et al., 1991solid phase

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
State gas
Instrument HP-GC/MS/IRD

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-1321
NIST MS number 229932

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Singh and Murthy, 2008
Singh, L.P.; Murthy, S.S.N., Dielectric and Calorimetric Study of Orientationally Disordered Phases in Two Unusual Two-Component Systems, J. Phys. Chem. B, 2008, 112, 9, 2606-2615, https://doi.org/10.1021/jp077663o . [all data]

Rute, Salud, et al., 2003
Rute, M.A.; Salud, J.; Negrier, P.; López, D.O.; Tamarit, J.Ll.; Puertas, R.; Barrio, M.; Mondieig, D., Two-Component System Cycloheptanol (C7) + Cyclooctanol (C8): An Extraordinary System, J. Phys. Chem. B, 2003, 107, 24, 5914-5921, https://doi.org/10.1021/jp022193d . [all data]

Sciesinski, Mayer, et al., 1995
Sciesinski, J.; Mayer, J.; Wasiutynski, T.; Sciesinska, E.; Wójtowicz, J., Calorimetric study of cyclooctanol, Phase Transitions, 1995, 54, 1, 15-21, https://doi.org/10.1080/01411599508200401 . [all data]

Sciesinski, Mayer, et al., 1995, 2
Sciesinski, J.; Mayer, J.; Wasiutynski, T.; Sciesinska, E.; Wojtowicz, J., Calorimetric study of cyclooctanol, Phase Trans., 1995, 54, 1, 15, https://doi.org/10.1080/01411599508200401 . [all data]

Wiberg, Crocker, et al., 1991
Wiberg, K.B.; Crocker, L.S.; Morgan, K.M., Thermochemical studies of carbonyl compounds. 5. Enthalpies of reduction of carbonyl groups, J. Am. Chem. Soc., 1991, 113, 3447-3450. [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References