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1,3-Propanediamine, N,N-dimethyl-

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Deltafgas-8.29 ± 0.96kcal/molCcbPapina, Pimenova, et al., 1992ALS
Deltafgas-8.39kcal/molN/ALebedeva, Gutner, et al., 1984Value computed using «DELTA»fHliquid° value of -77.3±0.5 kj/mol from Lebedeva, Gutner, et al., 1984 and «DELTA»vapH° value of 42.2 kj/mol from Papina, Pimenova, et al., 1992.; DRB
Deltafgas-10.7kcal/molCcbVasil'eva and Kotov, 1977hf298 calculated possible error by author; ALS

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-18.4 ± 0.96kcal/molCcbPapina, Pimenova, et al., 1992ALS
Deltafliquid-18.5 ± 0.1kcal/molCcbLebedeva, Gutner, et al., 1984ALS
Quantity Value Units Method Reference Comment
Deltacliquid-930.09 ± 0.96kcal/molCcbPapina, Pimenova, et al., 1992ALS
Deltacliquid-930.0 ± 0.1kcal/molCcbLebedeva, Gutner, et al., 1984ALS
Deltacliquid-926.5 ± 0.5kcal/molCcbVasil'eva and Kotov, 1977hf298 calculated possible error by author; ALS
Quantity Value Units Method Reference Comment
liquid77.20cal/mol*KN/ADzhafarov, Karasharli, et al., 1982DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
59.443298.Lebedeva, Gutner, et al., 1984, 2T = 295 to 360 K.; DH
61.11298.15Dzhafarov, Karasharli, et al., 1982T = 12 to 300 K.; DH
59.51295.96Lebedeva, Ryadnenko, et al., 1981T = 296 to 359 K.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil406.KN/ALebedeva, Gutner, et al., 1984, 2P = 9.972x104 kPa.; DH
Tboil405.2KN/AWeast and Grasselli, 1989BS
Tboil408.05KN/AAnonymous, 1968TRC
Quantity Value Units Method Reference Comment
Ttriple194.43KN/ADzhafarov, Karasharli, et al., 1982, 2Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Deltavap10.10 ± 0.02kcal/molCPapina, Pimenova, et al., 1992ALS
Deltavap10.1kcal/molN/APapina, Pimenova, et al., 1992DRB
Deltavap11.30kcal/molVVasil'eva and Kotov, 1977hf298 calculated possible error by author; ALS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
10.5 ± 0.05290.VLebedeva, Gutner, et al., 1984ALS

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
2.9601194.43Dzhafarov, Karasharli, et al., 1982Glass to crystal transition at 135 K shown graphically.; DH

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
15.22194.43Dzhafarov, Karasharli, et al., 1982Glass; DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW- 595
NIST MS number 227656

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Papina, Pimenova, et al., 1992
Papina, T.S.; Pimenova, S.M.; Zakharov, V.Yu.; Kolesov, V.P., Standard enthalpies of formation of derivatives of perfluoro-2-methyl-3-oxahexanoic acid and 3-(N,N-dimethylamino)propyl amine, Zh. Khim. Termodin. Termokhim., 1992, 1, 207-211. [all data]

Lebedeva, Gutner, et al., 1984
Lebedeva, N.D.; Gutner, N.M.; Katin, Yu.A.; Kozlova, N.M.; Kiseleva, N.N.; Makhina, E.F.; Dobychin, S.L., Thermochemical study of bis-hydroxyethylpiperazine, N,N-dimethylpropylenediamine, and 2,2-azodiisobutyrodinitrile, J. Appl. Chem. USSR, 1984, 57, 2118-2122. [all data]

Vasil'eva and Kotov, 1977
Vasil'eva, T.F.; Kotov, V.I., Heats of combustion of dimethyl-substituted amides and dimethylalkylamines, Vses. Konf. Kalorim. Rasshir. Tezisy Dokl. 7th, 1977, 1, 102-106. [all data]

Dzhafarov, Karasharli, et al., 1982
Dzhafarov, O.I.; Karasharli, K.A.; Kuliev, A.M., Study of the real heat capacity of N,N-dimethyl-1,3-propanediamine in the range 12-300K, Azerb. Khim. Zhur., 1982, No.3, 111-113. [all data]

Lebedeva, Gutner, et al., 1984, 2
Lebedeva, N.D.; Gutner, N.M.; Katin, Yu.A.; Kozlova, N.M.; Kiseleva, N.N.; Machinya, E.F.; Dobychin, S.L.; Thermochemical study of bis(hydroxyethyl)piperazine, N., N-dimethylpropylenediamine and 2,2-azodiisobutyric acid dinitrile, Zhur. Prikl. Khim. (Leningrad), 1984, 57(10), 2297-2301. [all data]

Lebedeva, Ryadnenko, et al., 1981
Lebedeva, N.D.; Ryadnenko, V.L.; Kozlova, N.M.; Karpenko, N.A.; Stepanov, V.B., Heat capacities of some organic compounds, 1981, Termodinam. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Anonymous, 1968
Anonymous, X., Chemicals and Plastics Physical Properties, 1968, Union Carbide Corp., product bulletin, 1968. [all data]

Dzhafarov, Karasharli, et al., 1982, 2
Dzhafarov, O.I.; Karasharli, K.A.; Kuliev, A.M., Study of the real heat capacity of N,N,-dimethyl-1,3-propanediamine in range 12-3oo K, Azerb. Khim. Zh., 1982, 1982, 111. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References