Pyridine, 3-methyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid61.1 ± 1.3kJ/molCcbGerasimov, Gubareva, et al., 1992%hf298_condensed[kJ/mol]=-61.1±1.3; ALS
Δfliquid61.71 ± 0.59kJ/molCcbScott, Good, et al., 1963ALS
Δfliquid68.3 ± 1.0kJ/molCcbCox, Challoner, et al., 1954ALS
Δfliquid33.kJ/molCcbConstam and White, 1903ALS
Quantity Value Units Method Reference Comment
Δcliquid-3300.4 ± 1.3kJ/molCcbGerasimov, Gubareva, et al., 1992%hf298_condensed[kJ/mol]=-61.1±1.3; ALS
Δcliquid-3423.2 ± 0.50kJ/molCcbScott, Good, et al., 1963ALS
Δcliquid-3429.8 ± 1.0kJ/molCcbCox, Challoner, et al., 1954ALS
Δcliquid-3402.kJ/molCcbConstam and White, 1903ALS
Quantity Value Units Method Reference Comment
liquid216.31J/mol*KN/AScott, Good, et al., 1963DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
158.69298.15Scott, Good, et al., 1963T = 12 to 400 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gerasimov, Gubareva, et al., 1992
Gerasimov, P.A.; Gubareva, A.I.; Tarbeeva, N.A.; Kunderenko, V.M., Physicochemical characteristics of β-picoline, J. Appl. Chem. USSR, 1992, 65, 388-390. [all data]

Scott, Good, et al., 1963
Scott, D.W.; Good, W.D.; Guthrie, G.B.; Todd, S.S.; Hossenlopp, I.A.; Osborn, A.G.; McCullough, J.P., Chemical thermodynamic properties and internal rotation of methylpyridines. II. 3-methylpyridine, J. Phys. Chem., 1963, 67, 685-689. [all data]

Cox, Challoner, et al., 1954
Cox, J.D.; Challoner, A.R.; Meetham, A.R., The heats of combustion of pyridine and certain of its derivatives, J. Chem. Soc., 1954, 265-271. [all data]

Constam and White, 1903
Constam, E.J.; White, J., Physico-chemical investigations in the pyridine series, Am. Chem. J., 1903, 29, 1-49. [all data]


Notes

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