OCS+


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

COS+ + Acetylene = (COS+ • Acetylene)

By formula: COS+ + C2H2 = (COS+ • C2H2)

Quantity Value Units Method Reference Comment
Δr27.7kcal/molPD/KERDGraul S.T. and Bowers, 1991gas phase; ΔrH>=
Δr34.kcal/molPDissOrlando, Friedman, et al., 1990gas phase
Δr34.kcal/molPDissOrlando, Friedman, et al., 1990gas phase
Δr33.7 ± 5.3kcal/molPDissOrlando, Friedman, et al., 1990gas phase; ΔrH<

(COS+ • Carbonyl sulfide) + Carbonyl sulfide = (COS+ • 2Carbonyl sulfide)

By formula: (COS+ • COS) + COS = (COS+ • 2COS)

Quantity Value Units Method Reference Comment
Δr1.6kcal/molPIOno, Osuch, et al., 1981gas phase

COS+ + Carbonyl sulfide = (COS+ • Carbonyl sulfide)

By formula: COS+ + COS = (COS+ • COS)

Quantity Value Units Method Reference Comment
Δr17.2kcal/molPIOno, Osuch, et al., 1981gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Graul S.T. and Bowers, 1991
Graul S.T.; Bowers, M.T., Dynamics of Metastable Dissociation and Photodissociation of the Gas Phase Cluster Ion (OCS.C2H2)+, J. Phys. Chem., 1991, 95, 21, 8328, https://doi.org/10.1021/j100174a055 . [all data]

Orlando, Friedman, et al., 1990
Orlando, T.M.; Friedman, A.; Maier, J.P., Photodissociation Spectroscopy of the [OCS C2H2]+ Cluster, J. Chem. Phys., 1990, 92, 12, 7365, https://doi.org/10.1063/1.458222 . [all data]

Ono, Osuch, et al., 1981
Ono, Y.; Osuch, E.A.; Ng, C.Y., Molecular beam photoionization study of OCS, (OCS)2, (OCS)3, and OCS.CS2, J. Chem. Phys., 1981, 74, 1645. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References