Methan-d3-ol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference
84.8298.15Filatov and Afanas'ev, 1992

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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on behalf of the United States of America. All rights reserved.
NIST MS number 37

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Vibrational and/or electronic energy levels

Go To: Top, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Gas     Symmetry:   Cs     Symmetry Number σ = 1


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a' 1 OH str 3690  D 3690 S gas
a' 2 CD3 d-str 2260  E 2260 M sh gas
a' 3 CD3 s-str 2077  C 2077 S gas
a' 4 CD3 d-deform 1047  D 1047 W gas
a' 5 CD3 s-deform 1134  C 1134 VS gas
a' 6 OH bend 1297  C 1297 VS gas
a' 7 CD3 rock 858  C 858 M gas
a' 8 CO str 988  C 988 VS gas
a 9 CD3 d-str 2235  D 2235 S gas
a 10 CD3 d-deform 1075  C 1075 W gas
a 11 CD3 rock 877  D 877 M gas
a 12 Torsion 256  E CF

Source: Shimanouchi, 1972

Liquid     Symmetry:   Cs     Symmetry Number σ = 1


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a' 1 OH str 3310  D 3310 S vb liq. 3350 W vb liq.
a' 2 CD3 d-str 2235  D 2235 M liq. 2230 M dp liq. Value obtained in vitreous solid (-ν180 )degrees C)
a' 3 CD3 s-str 2078  C 2078 S liq. 2074 VS p liq.
a' 4 CD3 d-deform 1069  C 1069 W liq. 1072 M dp liq. OV10)
a' 5 CD3 s-deform 1122  C 1122 VS liq. 1127 M p liq.
a' 6 OH bend 1391  C 1391 S b liq. 1360 VW liq.
a' 7 CD3 rock 882  C 882 M liq. 894 M dp liq. OV11)
a' 8 CO str 982  C 982 VS liq. 986 VS p liq.
a 9 CD3 d-str 2213  D 2213 M liq. 2213 VW liq. Value obtained in vitreous solid (-ν180 )degrees C)
a 10 CD3 d-deform 1069  C 1069 W liq. 1072 M dp liq. OV4)
a 11 CD3 rock 882  D 882 M liq. 894 M dp liq. OV7)
a 12 Torsion 665  D 665 S vb liq.

Source: Shimanouchi, 1972

Notes

VSVery strong
SStrong
MMedium
WWeak
VWVery weak
bBroad
vbVery broad
shShoulder
pPolarized
dpDepolarized
CFCalculated frequency
OVOverlapped by band indicated in parentheses.
C3~6 cm-1 uncertainty
D6~15 cm-1 uncertainty
E15~30 cm-1 uncertainty

References

Go To: Top, Condensed phase thermochemistry data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Filatov and Afanas'ev, 1992
Filatov, V.A.; Afanas'ev, V.N., Differential heat-flux calorimeter, Izv. Vysshikh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1992, 35(8), 97-100. [all data]

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume I, National Bureau of Standards, 1972, 1-160. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, References