Nitric oxide anion


Reaction thermochemistry data

Go To: Top, Constants of diatomic molecules, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Nitric oxide anion + Nitrogen = (Nitric oxide anion • Nitrogen)

By formula: NO- + N2 = (NO- • N2)

Quantity Value Units Method Reference Comment
Δr19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Δr20.kJ/molDTGheno and Fitaire, 1987gas phase; ΔrS+-12. J/mol*K; M
Δr18.kJ/molHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
Δr22.kJ/molHPMSTurner and Conway, 1976gas phase; M
Δr19.kJ/molDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Δr71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
Δr57.7J/mol*KDTGheno and Fitaire, 1987gas phase; ΔrS+-12. J/mol*K; M
Δr55.6J/mol*KHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
Δr79.1J/mol*KHPMSTurner and Conway, 1976gas phase; M
Δr65.7J/mol*KDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
2.200.FADunkin, Fehsenfeld, et al., 1971gas phase; M

Nitric oxide anion + Nitrous oxide = (Nitric oxide anion • Nitrous oxide)

By formula: NO- + N2O = (NO- • N2O)

Quantity Value Units Method Reference Comment
Δr60. ± 100.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr75.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Δr62.3J/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=32.2 kJ/mol; M

Nitric oxide anion + Water = (Nitric oxide anion • Water)

By formula: NO- + H2O = (NO- • H2O)

Quantity Value Units Method Reference Comment
Δr77.4kJ/molPHPMSFrench, Hills, et al., 1973gas phase; M
Δr69.5kJ/molPESEaton, Arnold, et al., 1990gas phase; M
Δr95.0kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Quantity Value Units Method Reference Comment
Δr96.2J/mol*KPHPMSFrench, Hills, et al., 1973gas phase; M
Δr100.J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
53.1296.SAMSPuckett and Teague, 1971gas phase; switching reaction(NO+)NO; M

(Nitric oxide anion • Water) + Water = (Nitric oxide anion • 2Water)

By formula: (NO- • H2O) + H2O = (NO- • 2H2O)

Quantity Value Units Method Reference Comment
Δr65.69kJ/molN/AEaton, Arnold, et al., 1990gas phase; Vertical Detachment Energy: 1.860±0.020 eV; B,M
Δr67.4kJ/molPHPMSFrench, Hills, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr107.J/mol*KPHPMSFrench, Hills, et al., 1973gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
35.293.HPMSMcAdams and Bone, 1972gas phase; M
36.296.FAHoward, Rundle, et al., 1971gas phase; M
36.296.SAMSPuckett and Teague, 1971gas phase; M

Nitric oxide anion + Carbon dioxide = (Nitric oxide anion • Carbon dioxide)

By formula: NO- + CO2 = (NO- • CO2)

Quantity Value Units Method Reference Comment
Δr36. ± 1.kJ/molDTIllies, 1988gas phase; ΔrH(0 K)=36.0 kJ/mol; M
Δr32. ± 2.kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Δr57.7kJ/molFADunkin, Fehsenfeld, et al., 1971gas phase; switching reaction(NO+)NO, ΔrH<; M
Quantity Value Units Method Reference Comment
Δr75.3J/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=36.0 kJ/mol; M
Δr57.3J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M

(Nitric oxide anion • Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 2Nitrous oxide)

By formula: (NO- • N2O) + N2O = (NO- • 2N2O)

Quantity Value Units Method Reference Comment
Δr24.7 ± 3.8kJ/molN/AHendricks, de Clercq, et al., 2002gas phase; B
Δr19.2kJ/molN/ACoe, Snodgrass, et al., 1987gas phase; B
Δr23.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Δr30.kJ/molPESCoe, Snodgrass, et al., 1986gas phase; D(N2O)2 not accounted for; M
Quantity Value Units Method Reference Comment
Δr-4.2 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion • 2Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 3Nitrous oxide)

By formula: (NO- • 2N2O) + N2O = (NO- • 3N2O)

Quantity Value Units Method Reference Comment
Δr21.8 ± 3.8kJ/molN/AHendricks, de Clercq, et al., 2002gas phase; B
Δr21.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase; M
Δr88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr-5.0 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion • 2Water) + Water = (Nitric oxide anion • 3Water)

By formula: (NO- • 2H2O) + H2O = (NO- • 3H2O)

Quantity Value Units Method Reference Comment
Δr74.5kJ/molPESEaton, Arnold, et al., 1990gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.308.PHPMSFrench, Hills, et al., 1973gas phase; M
25.293.HPMSMcAdams and Bone, 1972gas phase; M
25.296.FAHoward, Rundle, et al., 1971gas phase; M
25.296.SAMSPuckett and Teague, 1971gas phase; M

(Nitric oxide anion • Nitrogen) + Nitrogen = (Nitric oxide anion • 2Nitrogen)

By formula: (NO- • N2) + N2 = (NO- • 2N2)

Quantity Value Units Method Reference Comment
Δr17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Δr16.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr72.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
Δr52.7J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Nitric oxide anion • 3Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 4Nitrous oxide)

By formula: (NO- • 3N2O) + N2O = (NO- • 4N2O)

Quantity Value Units Method Reference Comment
Δr20.9 ± 3.8kJ/molN/AHendricks, de Clercq, et al., 2002gas phase; B
Δr19.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr-5.0 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion • 4Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 5Nitrous oxide)

By formula: (NO- • 4N2O) + N2O = (NO- • 5N2O)

Quantity Value Units Method Reference Comment
Δr17.6 ± 3.8kJ/molN/AHendricks, de Clercq, et al., 2002gas phase; B
Δr19.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr-6.3 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion • 2Nitrogen) + Nitrogen = (Nitric oxide anion • 3Nitrogen)

By formula: (NO- • 2N2) + N2 = (NO- • 3N2)

Quantity Value Units Method Reference Comment
Δr16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr70.3J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
4.204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Nitric oxide anion • 3Nitrogen) + Nitrogen = (Nitric oxide anion • 4Nitrogen)

By formula: (NO- • 3N2) + N2 = (NO- • 4N2)

Quantity Value Units Method Reference Comment
Δr14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
2.204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Nitric oxide anion • 9Nitrogen) + Nitrogen = (Nitric oxide anion • 10Nitrogen)

By formula: (NO- • 9N2) + N2 = (NO- • 10N2)

Quantity Value Units Method Reference Comment
Δr7.03kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr79.J/mol*KN/AHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M

(Nitric oxide anion • 5Carbon dioxide) + Carbon dioxide = (Nitric oxide anion • 6Carbon dioxide)

By formula: (NO- • 5CO2) + CO2 = (NO- • 6CO2)

Quantity Value Units Method Reference Comment
Δr21.kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M

Nitric oxide anion + Oxygen = (Nitric oxide anion • Oxygen)

By formula: NO- + O2 = (NO- • O2)

Quantity Value Units Method Reference Comment
Δr12.1 ± 0.8kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr60.7J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
-2.200.FADunkin, Fehsenfeld, et al., 1971gas phase; DG>; M

Nitric oxide anion + Hydrogen cation = Nitrosyl hydride

By formula: NO- + H+ = HNO

Quantity Value Units Method Reference Comment
Δr1511.6 ± 0.63kJ/molD-EATravers, Cowles, et al., 1989gas phase; ground state triplet anion; B
Quantity Value Units Method Reference Comment
Δr1484.0 ± 1.4kJ/molH-TSTravers, Cowles, et al., 1989gas phase; ground state triplet anion; B

Nitric oxide anion + Propanal = (Nitric oxide anion • Propanal)

By formula: NO- + C3H6O = (NO- • C3H6O)

Quantity Value Units Method Reference Comment
Δr159.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978, ref. to PA(NH3)=872. kJ/mol; M

Nitric oxide anion + Nitric oxide = (Nitric oxide anion • Nitric oxide)

By formula: NO- + NO = (NO- • NO)

Quantity Value Units Method Reference Comment
Δr57.7kJ/molPILinn, Ono, et al., 1981gas phase; M
Δr56.9kJ/molPINg, Tiedemann, et al., 1977gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
29.296.SAMSPuckett and Teague, 1971gas phase; M

(Nitric oxide anion • 5Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 6Nitrous oxide)

By formula: (NO- • 5N2O) + N2O = (NO- • 6N2O)

Quantity Value Units Method Reference Comment
Δr18.4 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M,M
Quantity Value Units Method Reference Comment
Δr-7.9 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

(Nitric oxide anion • 6Nitrous oxide) + Nitrous oxide = (Nitric oxide anion • 7Nitrous oxide)

By formula: (NO- • 6N2O) + N2O = (NO- • 7N2O)

Quantity Value Units Method Reference Comment
Δr17.6 ± 1.3kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B,M,M
Quantity Value Units Method Reference Comment
Δr-11. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1994, 2gas phase; B

Nitric oxide anion + Ethylbenzene = (Nitric oxide anion • Ethylbenzene)

By formula: NO- + C8H10 = (NO- • C8H10)

Quantity Value Units Method Reference Comment
Δr186.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Benzonitrile = (Nitric oxide anion • Benzonitrile)

By formula: NO- + C7H5N = (NO- • C7H5N)

Quantity Value Units Method Reference Comment
Δr172.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Benzaldehyde = (Nitric oxide anion • Benzaldehyde)

By formula: NO- + C7H6O = (NO- • C7H6O)

Quantity Value Units Method Reference Comment
Δr183.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Benzene, propyl- = (Nitric oxide anion • Benzene, propyl-)

By formula: NO- + C9H12 = (NO- • C9H12)

Quantity Value Units Method Reference Comment
Δr189.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Toluene = (Nitric oxide anion • Toluene)

By formula: NO- + C7H8 = (NO- • C7H8)

Quantity Value Units Method Reference Comment
Δr185.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Benzene, chloro- = (Nitric oxide anion • Benzene, chloro-)

By formula: NO- + C6H5Cl = (NO- • C6H5Cl)

Quantity Value Units Method Reference Comment
Δr161.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + n-Propyl acetate = (Nitric oxide anion • n-Propyl acetate)

By formula: NO- + C5H10O2 = (NO- • C5H10O2)

Quantity Value Units Method Reference Comment
Δr176.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Butanal = (Nitric oxide anion • Butanal)

By formula: NO- + C4H8O = (NO- • C4H8O)

Quantity Value Units Method Reference Comment
Δr164.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Ethyl Acetate = (Nitric oxide anion • Ethyl Acetate)

By formula: NO- + C4H8O2 = (NO- • C4H8O2)

Quantity Value Units Method Reference Comment
Δr174.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Benzene, fluoro- = (Nitric oxide anion • Benzene, fluoro-)

By formula: NO- + C6H5F = (NO- • C6H5F)

Quantity Value Units Method Reference Comment
Δr158.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + 3-Pentanone, 2,4-dimethyl- = (Nitric oxide anion • 3-Pentanone, 2,4-dimethyl-)

By formula: NO- + C7H14O = (NO- • C7H14O)

Quantity Value Units Method Reference Comment
Δr187.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Ethyl ether = (Nitric oxide anion • Ethyl ether)

By formula: NO- + C4H10O = (NO- • C4H10O)

Quantity Value Units Method Reference Comment
Δr173.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Acetone = (Nitric oxide anion • Acetone)

By formula: NO- + C3H6O = (NO- • C3H6O)

Quantity Value Units Method Reference Comment
Δr172.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Benzene = (Nitric oxide anion • Benzene)

By formula: NO- + C6H6 = (NO- • C6H6)

Quantity Value Units Method Reference Comment
Δr172.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Acetaldehyde = (Nitric oxide anion • Acetaldehyde)

By formula: NO- + C2H4O = (NO- • C2H4O)

Quantity Value Units Method Reference Comment
Δr164.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + 2-Butanone = (Nitric oxide anion • 2-Butanone)

By formula: NO- + C4H8O = (NO- • C4H8O)

Quantity Value Units Method Reference Comment
Δr177.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Acetic acid, methyl ester = (Nitric oxide anion • Acetic acid, methyl ester)

By formula: NO- + C3H6O2 = (NO- • C3H6O2)

Quantity Value Units Method Reference Comment
Δr167.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + 3-Pentanone = (Nitric oxide anion • 3-Pentanone)

By formula: NO- + C5H10O = (NO- • C5H10O)

Quantity Value Units Method Reference Comment
Δr179.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Benzene, (1-methylethyl)- = (Nitric oxide anion • Benzene, (1-methylethyl)-)

By formula: NO- + C9H12 = (NO- • C9H12)

Quantity Value Units Method Reference Comment
Δr189.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Benzene, nitro- = (Nitric oxide anion • Benzene, nitro-)

By formula: NO- + C6H5NO2 = (NO- • C6H5NO2)

Quantity Value Units Method Reference Comment
Δr164.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

Nitric oxide anion + Benzene, (trifluoromethyl)- = (Nitric oxide anion • Benzene, (trifluoromethyl)-)

By formula: NO- + C7H5F3 = (NO- • C7H5F3)

Quantity Value Units Method Reference Comment
Δr150.kJ/molICRReents and Freiser, 1981gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M

(Nitric oxide anion • 2Oxygen) + Oxygen = (Nitric oxide anion • 3Oxygen)

By formula: (NO- • 2O2) + O2 = (NO- • 3O2)

Quantity Value Units Method Reference Comment
Δr11.8 ± 0.8kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr65.7J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M

(Nitric oxide anion • 3Oxygen) + Oxygen = (Nitric oxide anion • 4Oxygen)

By formula: (NO- • 3O2) + O2 = (NO- • 4O2)

Quantity Value Units Method Reference Comment
Δr10.2 ± 0.8kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr67.4J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M

(Nitric oxide anion • 4Nitrogen) + Nitrogen = (Nitric oxide anion • 5Nitrogen)

By formula: (NO- • 4N2) + N2 = (NO- • 5N2)

Quantity Value Units Method Reference Comment
Δr13. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr89.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 4Oxygen) + Oxygen = (Nitric oxide anion • 5Oxygen)

By formula: (NO- • 4O2) + O2 = (NO- • 5O2)

Quantity Value Units Method Reference Comment
Δr9.8 ± 0.8kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr80.3J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M

(Nitric oxide anion • 5Nitrogen) + Nitrogen = (Nitric oxide anion • 6Nitrogen)

By formula: (NO- • 5N2) + N2 = (NO- • 6N2)

Quantity Value Units Method Reference Comment
Δr13. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 6Nitrogen) + Nitrogen = (Nitric oxide anion • 7Nitrogen)

By formula: (NO- • 6N2) + N2 = (NO- • 7N2)

Quantity Value Units Method Reference Comment
Δr12. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr95.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 7Nitrogen) + Nitrogen = (Nitric oxide anion • 8Nitrogen)

By formula: (NO- • 7N2) + N2 = (NO- • 8N2)

Quantity Value Units Method Reference Comment
Δr11. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr97.5J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 8Nitrogen) + Nitrogen = (Nitric oxide anion • 9Nitrogen)

By formula: (NO- • 8N2) + N2 = (NO- • 9N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr81.6J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Constants of diatomic molecules

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through March, 1977

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for 14N16O-
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
Evidence for additional compound states ("resonance" related to the "grandparents" b 3Π, A 1Π, and c 3Π, of NO+) in the 12-18 eV region of the electron transmission Sanche and Schulz, 1971, Schulz, 1973 and electroionization Carbonneau and Marmet, 1974 spectra of NO.
The nature of the state (or states) involved in the production of N(2D) + O- by dissociative electron attachmnet (7-12 eV) has been discussed by van Brunt and Kieffer, 1974; see also Thulstrup, Thulstrup, et al., 1974.
(3Σ-) 51700 1 2320 13 2         
(3Σ+) 43800 1 2380 12 2         
(3Π) 43400 1 2370 12 2         
(1Σ+) 40400 1 2330 8 2         
b 1Σ+ (9300) 3           
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
a 1Δ 6050 1492 3 (8)       1.262 3  
X 3Σ- 0 1363 3 8  1.427 4     1.258 4  

Notes

1Symmetries assigned on the basis of theoretical calculations Lefebvre-Brion, 1973. The states consist of two Rydberg electrons temporarily bound to the NO+ X 1Σ+ core.
2Short vibrational progressions of resonances in teh electron transmission current Sanche and Schulz, 1971 predicted widths range from 1 to 25 meV Pearson and Lefebvre-Brion, 1976.
3From the analysis Tronc, Huetz, et al., 1975, Teillet-Billy and Fiquet-Fayard, 1977 of electron scattering data Spence and Schulz, 1971, Schulz, 1973, Burrow, 1974, Zecca, Lazzizzera, et al., 1974. For the ground state Siegel, Celotta, et al., 1972 estimate ωe ~1470 cm-1 Siegel, Celotta, et al., 1972, see 4.
4Franck-Condon factor analysis of the photodetachment spectrum Siegel, Celotta, et al., 1972. The analysis of electron scattering data Teillet-Billy and Fiquet-Fayard, 1977 leads to re = 1.267 Å Teillet-Billy and Fiquet-Fayard, 1977.
5From D00(NO) and the electron affinities of O and NO.
6From the photodetachment spectrum Siegel, Celotta, et al., 1972. Good agreement with McFarland, Dunkin, et al., 1972 and Parkes and Sugden, 1972.

References

Go To: Top, Reaction thermochemistry data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Gheno and Fitaire, 1987
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Speller, Fitaire, et al., 1983
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Turner and Conway, 1976
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Johnsen, Huang, et al., 1975
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Hendricks, de Clercq, et al., 2002
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McFarland, Dunkin, et al., 1972
McFarland, M.; Dunkin, D.B.; Fehsenfeld, F.C.; Schmeltekopf, A.L.; Ferguson, E.E., Collisional detachment studies of NO-, J. Chem. Phys., 1972, 56, 2358. [all data]

Parkes and Sugden, 1972
Parkes, D.A.; Sugden, T.M., Electron attachment and detachment in nitric oxide, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 600. [all data]


Notes

Go To: Top, Reaction thermochemistry data, Constants of diatomic molecules, References