Methane, fluorotrinitro-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Condensed phase thermochemistry data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-220.2 ± 2.0kJ/molCcrZimmer, Robb, et al., 1966Corrected for CODATA value of ΔfH; hcomb of the compound with Ethyl oxalate
Quantity Value Units Method Reference Comment
Δcliquid-3336.6 ± 2.0kJ/molCcrZimmer, Robb, et al., 1966Corrected for CODATA value of ΔfH; hcomb of the compound with Ethyl oxalate

Phase change data

Go To: Top, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus244.15KN/AZimmer, Robb, et al., 1966, 2Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Δvap34.7 ± 0.42kJ/molVZimmer, Robb, et al., 1966Corrected for CODATA value of ΔfH; Reanalyzed by Cox and Pilcher, 1970, Original value = 34.19 kJ/mol; hcomb of the compound with Ethyl oxalate; ALS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
34.2289.A,TStephenson and Malanowski, 1987Based on data from 274. to 358. K. See also Zimmer, Robb, et al., 1966.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zimmer, Robb, et al., 1966
Zimmer, M.F.; Robb, R.A.; Baroody, E.E.; Carpenter, G.A., Heat of formation and other properties of trinitrofluoromethane, J. Chem. Eng. Data, 1966, 11, 577-579. [all data]

Zimmer, Robb, et al., 1966, 2
Zimmer, M.F.; Robb, R.A.; Baroody, E.E.; Carpenter, G.A., Heat of Formation and Other Properties of Trinitrofluoromethane, J. Chem. Eng. Data, 1966, 11, 577. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, References