nickel difluoride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
1350. - 1556.5.422967272.953-433.953McDougall and Kilpatrick, 1965Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
79.40 ± 0.981054. - 1106.MEEhlert, Kent, et al., 1964AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Fluorine anion + nickel difluoride = (Fluorine anion • nickel difluoride)

By formula: F- + F2Ni = (F- • F2Ni)

Quantity Value Units Method Reference Comment
Δr80.8 ± 3.6kcal/molTDEqNikitin, Igolkina, et al., 1986gas phase; Reanalyzed literature data, 35.9 kcal < AlF3

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

McDougall and Kilpatrick, 1965
McDougall, L.A.; Kilpatrick, J.E., Entropy and Related Thermodynamic Properties of Carbon Suboxide, J. Chem. Phys., 1965, 42, 7, 2311-2321, https://doi.org/10.1063/1.1696294 . [all data]

Ehlert, Kent, et al., 1964
Ehlert, T.C.; Kent, R.A.; Margrave, J.L., Mass Spectrometric Studies at High Temperatures. VI. The Sublimation Pressure of Nickel(II) Fluoride, J. Am. Chem. Soc., 1964, 86, 23, 5093-5095, https://doi.org/10.1021/ja01077a009 . [all data]

Nikitin, Igolkina, et al., 1986
Nikitin, M.I.; Igolkina, N.A.; Skokan, E.V.; Sorokin, I.D.; Sidirov, L.N., Enthalpies of formation of the AlF4- ion, J. Phys. Chem., 1986, 60, 22. [all data]


Notes

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