Silicon tetrafluoride

• Formula: F₄Si
• Molecular weight: 104.0791
• IUPAC Standard InChI: InChI=1S/F4Si/c1-5(2,3)4 Copy

  
• IUPAC Standard InChIKey: ABTOQLMXBSRXSM-UHFFFAOYSA-N Copy
• CAS Registry Number: 7783-61-1
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Silane, tetrafluoro-; Silicon fluoride (SiF4); Tetrafluorosilane; SiF4; Silicon fluoride; UN 1859
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• Information on this page:
  • Phase change data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Vibrational and/or electronic energy levels
• Data at other public NIST sites:
  • Electron-Impact Ionization Cross Sections (on physics web site)
  • Gas Phase Kinetics Database
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Enthalpy of sublimation

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Booth and Swinehart, 1935
Booth, H.S.; Swinehart, C.F., Critical Constants and Vapor Pressure of Some Gaseous Fluorides of Group IV, J. Am. Chem. Soc., 1935, 57, 1337. [all data]

Pace and Mosser, 1963
Pace, E.L.; Mosser, J.S., Thermodynamic Properties of Silicon Tetrafluoride from 15 ºK to its Triple Point. The Entropy from Molecular and Spectroscopic Data, J. Chem. Phys., 1963, 39, 1, 154-158, https://doi.org/10.1063/1.1733993 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Patnode and Papish, 1929
Patnode, W.I.; Papish, Jacob, The Vapor Pressure of Silicon Tetrafluoride, J. Phys. Chem., 1929, 34, 7, 1494-1496, https://doi.org/10.1021/j150313a010 . [all data]

Notes

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• Symbols used in this document:
  

  Pc	Critical pressure
  Tboil	Boiling point
  Tc	Critical temperature
  ΔsubH	Enthalpy of sublimation

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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