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Tetrahydrofuran, 2,2-dimethyl-

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Phase change data

Go To: Top, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director

Quantity Value Units Method Reference Comment
Tboil363.15KN/AAnsell and Thomas, 1958Uncertainty assigned by TRC = 2. K
Tboil364.15KN/AFavorskaya and Shcherbinskaya, 1953Uncertainty assigned by TRC = 1. K
Tboil365.4KN/ASlabey and Wise, 1951Uncertainty assigned by TRC = 0.05 K
Tboil364.65KN/APaul and Tchelitcheff, 1950Uncertainty assigned by TRC = 1.5 K
Tboil370.KN/AVan Keersbilck, 1929Uncertainty assigned by TRC = 4. K
Quantity Value Units Method Reference Comment
Tfus158.69KN/ASlabey and Wise, 1951Uncertainty assigned by TRC = 0.05 K

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated by: Edward P. Hunter and Sharon G. Lias

Quantity Value Units Method Reference Comment
Proton affinity (review)202.6kcal/molN/AHunter and Lias, 1998 
Quantity Value Units Method Reference Comment
Gas basicity195.6kcal/molN/AHunter and Lias, 1998 

IR Spectrum

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
State gas
Instrument HP-GC/MS/IRD

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1990.
NIST MS number 114781

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


Gas Chromatography

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryMethyl Silicone700.Farkas, Héberger, et al., 2004Program: not specified

References

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ansell and Thomas, 1958
Ansell, M.F.; Thomas, D.A., J. Chem. Soc., 1958, 1958, 1163. [all data]

Favorskaya and Shcherbinskaya, 1953
Favorskaya, T.A.; Shcherbinskaya, N.V., Zh. Obshch. Khim., 1953, 23, 1485. [all data]

Slabey and Wise, 1951
Slabey, V.A.; Wise, P.H., , Natl. Advis. Comm. Aeronaut., Tech. Notes, No. 2258, Lewis Fligt Propulsion Lab., Cleveland, OH, 1951. [all data]

Paul and Tchelitcheff, 1950
Paul, R.; Tchelitcheff, S., The Methylenyl-2-tetrahydrofuran. Application to the Preparation of beta-Ethylenic Alcohols. Synthesis of Sylvanne, Bull. Soc. Chim. Fr., 1950, 1950, 520. [all data]

Van Keersbilck, 1929
Van Keersbilck, N., Cyclopropane derivatives, Bull. Soc. Chim. Belg., 1929, 38, 205-11. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Farkas, Héberger, et al., 2004
Farkas, O.; Héberger, K.; Zenkevich, I.G., Quantitative structure-retention relationships. XIV. Prediction of gas chromatographic retention indices for saturated O-, N-, and S-heterocyclic compounds, Chemom. Intell. Lab. Syst., 2004, 72, 2, 173-184, https://doi.org/10.1016/j.chemolab.2004.01.012 . [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References