cyclobutane, 1,2-dimethyl-, trans-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tboil330.0KN/AKazanskii and Lukina, 1954Uncertainty assigned by TRC = 0.5 K
Quantity Value Units Method Reference Comment
Tfus150.7KN/AKazanskii and Lukina, 1954Uncertainty assigned by TRC = 2. K

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2Hydrogen + Cyclobutane, 1,2-bis(methylene)- = cyclobutane, 1,2-dimethyl-, trans-

By formula: 2H2 + C6H8 = C6H12

Quantity Value Units Method Reference Comment
Δr-244. ± 0.8kJ/molChydRoth, Lennartz, et al., 1986liquid phase; solvent: Isooctane; Mixture cis and trans

3Hydrogen + 3,4-Dimethylenecyclobut-1-ene = cyclobutane, 1,2-dimethyl-, trans-

By formula: 3H2 + C6H6 = C6H12

Quantity Value Units Method Reference Comment
Δr-376. ± 1.kJ/molChydRoth, Lennartz, et al., 1986liquid phase; solvent: Isooctane; Mixture cis and trans

2-Butene, (E)- + Ethylene = cyclobutane, 1,2-dimethyl-, trans-

By formula: C4H8 + C2H4 = C6H12

Quantity Value Units Method Reference Comment
Δr-69.9kJ/molEqkScacchi and Back, 1977liquid phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kazanskii and Lukina, 1954
Kazanskii, B.A.; Lukina, M.Y., Synthesis of 1,2-Dimethylcyclobutane, Doklady Akad. Nauk. S.S.S.R., 1954, 94, 887-9. [all data]

Roth, Lennartz, et al., 1986
Roth, W.E.; Lennartz, H.W.; Vogel, E.; Leiendecker, M.; Masaji, O., Heats of hydrogenation. 6. Resonance energy of fused [4n]annulenes, Chem. Ber., 1986, 119, 837-843. [all data]

Scacchi and Back, 1977
Scacchi, G.; Back, M.H., The cycloaddition of ethylene to butene-2. II. Energy relations, Int. J. Chem. Kinet., 1977, 9, 525-534. [all data]


Notes

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