Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Diethyl sulfide

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C4H10S+ + Diethyl sulfide = (C4H10S+ bullet Diethyl sulfide)

By formula: C4H10S+ + C4H10S = (C4H10S+ bullet C4H10S)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Deltar24.9kcal/molDTJames, McKee, et al., 1996gas phase; «DELTA»rH(0K) = 25.6 kcal/mol
Deltar26.8kcal/molDTDeng, Illies, et al., 1995gas phase; «DELTA»rH(0K) = 28.8 kcal/mol
Quantity Value Units Method Reference Comment
Deltar28.2cal/mol*KDTJames, McKee, et al., 1996gas phase; «DELTA»rH(0K) = 25.6 kcal/mol
Deltar34.2cal/mol*KDTDeng, Illies, et al., 1995gas phase; «DELTA»rH(0K) = 28.8 kcal/mol

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

James, McKee, et al., 1996
James, M.A.; McKee, M.L.; Illies, A.J., Gas-phase bond strength and atomic connectivity studies of the unsymmetrical two-center three-electron ion, [Et2S...SMe2]+, J. Am. Chem. Soc., 1996, 118, 33, 7836, https://doi.org/10.1021/ja960455h . [all data]

Deng, Illies, et al., 1995
Deng, Y.; Illies, A.J.; James, M.A.; McKee, M.L.; Peschke, M., A Definitive Investigation of the Gas-Phase Two-Center Three-electron Bond in [H2S:SH2+], [Me2S:SMe2]+, and [Et2S:SEt2]+: Therory and Experiment, J. Am. Chem. Soc., 1995, 117, 1, 420, https://doi.org/10.1021/ja00106a048 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References