Octatetracontylfluorobuckminsterfullerene
- Formula: C60F48
- Molecular weight: 1632.5654
- CAS Registry Number: 143471-98-1
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of sublimation
| ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 26.1 ± 1.7 | 476. | ME,MS | Boltalina, Markov, et al., 1999 | Based on data from 395. to 528. K. See also Boltalina and Galeva, 2007. |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 4.06 ± 0.30 | IMRB | Jin, Hettich, et al., 1994 | |
| <7.269995 | N/A | Vasilev, Boltalina, et al., 1998 | Seems way too high |
References
Go To: Top, Phase change data, Gas phase ion energetics data, NIST Subscription Links, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Boltalina, Markov, et al., 1999
Boltalina, O.V.; Markov, V.Yu.; Borschevskii, A.Ya.; Galeva, N.A.; Sidorov, L.N.; Gigli, G.; Balducci, G.,
Saturated Vapor Pressure and Sublimation Enthalpy of Fluorine Derivatives of C 60,
J. Phys. Chem. B, 1999, 103, 19, 3828-3832, https://doi.org/10.1021/jp983786k
. [all data]
Boltalina and Galeva, 2007
Boltalina, Olga V.; Galeva, Nadezhda A.,
Direct fluorination of fullerenes,
Russ. Chem. Rev., 2007, 69, 7, 609-621, https://doi.org/10.1070/RC2000v069n07ABEH000579
. [all data]
Jin, Hettich, et al., 1994
Jin, C.; Hettich, R.L.; Compton, R.N.; Tuinman, A.; Derecskei-Kovacs, A.; Marynik, D.S.; Dunlap, B.I.,
Attachment of Two Electrons to C60F48: Coulomb Barriers in Doubly Charged Anions,
Phys. Rev. Lett., 1994, 73, 21, 282, https://doi.org/10.1103/PhysRevLett.73.2821
. [all data]
Vasilev, Boltalina, et al., 1998
Vasilev, Y.V.; Boltalina, O.V.; Tuktarov, R.F.; Mazunov, V.A.; Sidorov, L.N.,
Resonant free electron capture spectra of C60F48,
Int. J. Mass Spectrom., 1998, 173, 1-2, 113-125, https://doi.org/10.1016/S0168-1176(97)00279-6
. [all data]
Notes
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- Symbols used in this document:
EA Electron affinity ΔsubH Enthalpy of sublimation - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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