Propane, 1,1,1,2,3,3,3-heptafluoro-
- Formula: C3HF7
- Molecular weight: 170.0289
- CAS Registry Number: 431-89-0
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Constant pressure heat capacity of liquid
Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
32.82 | 303.15 | Wirbser, Brauning, et al., 1992 | T = 253 to 423 K. Extrapolation to p = 0 kPa. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 255.0 | K | N/A | Hwang, DesMarteau, et al., 1992 | Uncertainty assigned by TRC = 0.5 K; TRC |
Tboil | 293. | K | N/A | PCR Inc., 1990 | BS |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 142. | K | N/A | Salvi-Narkhede, Wang, et al., 1992 | Uncertainty assigned by TRC = 2. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 374.83 | K | N/A | Salvi-Narkhede, Wang, et al., 1992 | Uncertainty assigned by TRC = 0.2 K; method of measurement not clearly described; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 28.735 | atm | N/A | Salvi-Narkhede, Wang, et al., 1992 | Uncertainty assigned by TRC = 0.03 atm; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Vc | 0.275 | l/mol | N/A | Salvi-Narkhede, Wang, et al., 1992 | Uncertainty assigned by TRC = 0.005 l/mol; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 4.52 | kcal/mol | N/A | Eckl, Huang, et al., 2007 | AC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
5.43 | 293. | Bobbo, Artico, et al., 2002 | Based on data from 278. to 308. K.; AC |
5.40 | 308. | Valtz, Coquelet, et al., 2002 | Based on data from 293. to 353. K.; AC |
5.33 | 250. | Salvi-Narkhede, Wang, et al., 1992, 2 | Based on data from 237. to 370. K.; AC |
3.47 | 300. | Salvi-Narkhede, Wang, et al., 1992, 2 | Based on data from 237. to 370. K.; AC |
2.99 | 325. | Salvi-Narkhede, Wang, et al., 1992, 2 | Based on data from 237. to 370. K.; AC |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Site Links, NIST Free Links, NIST Subscription Links, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wirbser, Brauning, et al., 1992
Wirbser, H.; Brauning, G.; Gurtner, J.; Ernst, G.,
Flow-calorimetric specific heat capacities and Joule-Thoson coefficients of CF3CHFCF3 (R227) - a new working fluid in energy technics - at pressures up to 15 MPa and temperatures between 253 and 423 K,
J. Chem. Thermodynam., 1992, 24, 761-772. [all data]
Hwang, DesMarteau, et al., 1992
Hwang, S.H.; DesMarteau, D.D.; Beyerlein, A.L.; Smith, N.D.; Joyner, P.,
The heat capacity of fluorinated propane and butane derivatives by differential scanning calorimetry,
J. Therm. Anal., 1992, 38, 2515-28. [all data]
PCR Inc., 1990
PCR Inc.,
Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]
Salvi-Narkhede, Wang, et al., 1992
Salvi-Narkhede, M.; Wang, B.H.; Adcock, J.I.; Van Hook, W.A.,
Vapor pressures, liquid molar volumes, vapor non-ideality, and critical properties of some partially fluorinated ethers (CF3OCF2CF2H, CF3OCF2H, and CF3OCH3), some perfluoroethers (CF3OCF2OCF3, c-CF2O,
J. Chem. Thermodyn., 1992, 24, 1065-75. [all data]
Eckl, Huang, et al., 2007
Eckl, Bernhard; Huang, Yow-Lin; Vrabec, Jadran; Hans, Hasse,
Vapor pressure of R227ea + ethanol at 343.13 K by molecular simulation,
Fluid Phase Equilibria, 2007, 260, 2, 177-182, https://doi.org/10.1016/j.fluid.2007.05.011
. [all data]
Bobbo, Artico, et al., 2002
Bobbo, Sergio; Artico, Gianpiero; Fedele, Laura; Scattolini, Mauro; Camporese, Roberto,
Vapor-Liquid Equilibrium Measurements and Correlation of the Binary Refrigerant Mixture Propane (HC-290) + 1,1,1,2,3,3,3-Heptafluoropropane (HFC-227ea) at 278.15, 293.15, and 308.15 K,
J. Chem. Eng. Data, 2002, 47, 4, 839-842, https://doi.org/10.1021/je010269d
. [all data]
Valtz, Coquelet, et al., 2002
Valtz, A.; Coquelet, C.; Baba-Ahmed, A.; Richon, D.,
Vapor--liquid equilibrium data for the propane+1,1,1,2,3,3,3-heptafluoropropane (R227ea) system at temperatures from 293.16 to 353.18 K and pressures up to 3.4 MPa,
Fluid Phase Equilibria, 2002, 202, 1, 29-47, https://doi.org/10.1016/S0378-3812(02)00056-0
. [all data]
Salvi-Narkhede, Wang, et al., 1992, 2
Salvi-Narkhede, M.; Wang, Bao-Huai; Adcock, James L.; Alexander Van Hook, W.,
Vapor pressures, liquid molar volumes, vapor non-ideality, and critical properties of some partially fluorinated ethers (CF3OCF2CF2H, CF3OCF2H, and CF3OCH3), some perfluoroethers (CF3OCF2OCF3, c-CF2OCF2OCF2, and c-CF2CF2CF2O), and of CHF2Br and CF3CFHCF3,
The Journal of Chemical Thermodynamics, 1992, 24, 10, 1065-1075, https://doi.org/10.1016/S0021-9614(05)80017-5
. [all data]
Notes
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- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Pc Critical pressure Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Vc Critical volume ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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