Perfluorobicyclo-[4.4.0]-dec-1,6-ene
- Formula: C10F16
- Molecular weight: 424.0815
- IUPAC Standard InChIKey: LSBZKGFVMTVTCT-UHFFFAOYSA-N
- CAS Registry Number: 54939-04-7
- Chemical structure:
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -765.7 ± 1.1 | kcal/mol | Ccr | Zhogina, Papina, et al., 1988 | Uc=-3560.0±4.6 kJ/mol |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -776.5 ± 1.1 | kcal/mol | Ccr | Zhogina, Papina, et al., 1988 | Uc=-3560.0±4.6 kJ/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -848.5 ± 1.1 | kcal/mol | Ccr | Zhogina, Papina, et al., 1988 | Uc=-3560.0±4.6 kJ/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 117.4 | cal/mol*K | N/A | Zhogin, Kosarukina, et al., 1981 | DH |
Constant pressure heat capacity of liquid
Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
102.4 | 298.15 | Zhogin, Kosarukina, et al., 1981 | T = 6 to 300 K. 0.41 mole % impurity of sample; DH |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Ttriple | 264.09 | K | N/A | Zhogin, Kosarukina, et al., 1981 | Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 10.8 ± 0.02 | kcal/mol | C | Varushchenko, Druzhinina, et al., 1996 | AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
2.502 | 263. | Domalski and Hearing, 1996 | AC |
Enthalpy of phase transition
ΔHtrs (kcal/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
0.190 | 200.0 | crystaline, III | crystaline, II | Zhogin, Kosarukina, et al., 1981 | DH |
0.2660 | 233.4 | crystaline, II | crystaline, I | Zhogin, Kosarukina, et al., 1981 | DH |
2.5031 | 264.09 | crystaline, I | liquid | Zhogin, Kosarukina, et al., 1981 | DH |
Entropy of phase transition
ΔStrs (cal/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
0.901 | 200.0 | crystaline, III | crystaline, II | Zhogin, Kosarukina, et al., 1981 | DH |
1.14 | 233.4 | crystaline, II | crystaline, I | Zhogin, Kosarukina, et al., 1981 | DH |
9.479 | 264.09 | crystaline, I | liquid | Zhogin, Kosarukina, et al., 1981 | DH |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zhogina, Papina, et al., 1988
Zhogina, E.V.; Papina, T.S.; Kolesov, V.P.; Prokudin, I.P.; Mel'nichenko, B.A.,
Standard enthalpy of formation of perfluorobicyclo-[4,4,0]-dec-1,6-ene,
Russ. J. Phys. Chem. (Engl. Transl.), 1988, 62, 569-570. [all data]
Zhogin, Kosarukina, et al., 1981
Zhogin, D.Yu.; Kosarukina, E.A.; Kolesov, V.P.; Prokudin, I.P.; Mel'nichenko, B.A.,
The heat capacity in the temperature range 6-300 K, phase transformations, and thermodynamic functions of perfluorobicyclo(4,4,0)dec-1,6-ene,
Zhur. Fiz. Khim., 1981, 55, 98-103. [all data]
Varushchenko, Druzhinina, et al., 1996
Varushchenko, Raisa M.; Druzhinina, Anna I.; Pashchenko, Larisa L.,
Thermodynamics of vaporization of some cyclic perfluorocarbons,
Fluid Phase Equilibria, 1996, 126, 1, 93-104, https://doi.org/10.1016/S0378-3812(96)03111-1
. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Notes
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- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid S°liquid Entropy of liquid at standard conditions Ttriple Triple point temperature ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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