Xe2Cl

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   9G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 29900 T gas 9 2G-4 2G McCown, Ediger, et al., 1985
Geohegan and Eden, 1987

State:   8G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 23000 T gas 8 2G-4 2G Geohegan and Eden, 1987

State:   4G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 20600 gas 4 2G-1,2 2G 398 621 Mangano, Jacob, et al., 1977
Lorents, Huestis, et al., 1978
McKown and Eden, 1984
McCown, Ediger, et al., 1985
Geohegan and Eden, 1987
Tx = 30400 Ne 4 2G-1 2G 314 345 Bohling, Langen, et al., 1990
Tx = 17700 Ne 4 2G-1,2 2G 507 637 Bohling, Langen, et al., 1990
Tx = 17450 Ar 4 2G-1,2 2G 514 647 Fajardo and Apkarian, 1986
Fajardo and Apkarian, 1988
Tx = 17450 Kr 4 2G-1,2 2G 514 647 Fajardo and Apkarian, 1986
Fajardo and Apkarian, 1988
Tx = 17450 Xe 4 2G-1,2 2G 514 647 Fajardo and Apkarian, 1986
Fajardo and Apkarian, 1988

Additional references: Jacox, 1994, page 122

Notes

TTentative assignment or approximate value
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

McCown, Ediger, et al., 1985
McCown, A.W.; Ediger, M.N.; Geohegan, D.B.; Eden, J.G., Absorption of electronically excited Xe2Cl in the ultraviolet, J. Chem. Phys., 1985, 82, 11, 4862, https://doi.org/10.1063/1.448656 . [all data]

Geohegan and Eden, 1987
Geohegan, D.B.; Eden, J.G., Xe2Cl and Kr2F excited state (4 2Γ) absorption spectra: measurements of absolute cross sections, Chem. Phys. Lett., 1987, 139, 6, 519, https://doi.org/10.1016/0009-2614(87)87334-7 . [all data]

Mangano, Jacob, et al., 1977
Mangano, J.A.; Jacob, J.H.; Rokni, M.; Hawryluk, A., Three-body quenching of KrF* by Ar and broad-band emission at 415 nm, Appl. Phys. Lett., 1977, 31, 1, 26, https://doi.org/10.1063/1.89465 . [all data]

Lorents, Huestis, et al., 1978
Lorents, D.C.; Huestis, D.L.; McCusker, M.V.; Nakano, H.H.; Hill, R.M., Optical emissions of triatomic rare gas halides, J. Chem. Phys., 1978, 68, 10, 4657, https://doi.org/10.1063/1.435574 . [all data]

McKown and Eden, 1984
McKown, A.W.; Eden, J.G., Ultraviolet photoassociative production of XeCl(B,C) molecules in Xe/Cl2 gas mixtures: Radiative lifetime of Xe2Cl(4 2Γ), J. Chem. Phys., 1984, 81, 7, 2933, https://doi.org/10.1063/1.448042 . [all data]

Bohling, Langen, et al., 1990
Bohling, R.; Langen, J.; Schurath, U., Ne matrix hosting XenCl exciplexes: comparison with Ar and Xe hosts, J. Mol. Struct., 1990, 222, 1-2, 171, https://doi.org/10.1016/0022-2860(90)80014-B . [all data]

Fajardo and Apkarian, 1986
Fajardo, M.E.; Apkarian, V.A., Cooperative photoabsorption induced charge transfer reaction dynamics in rare gas solids. I. Photodynamics of localized xenon chloride exciplexes, J. Chem. Phys., 1986, 85, 10, 5660, https://doi.org/10.1063/1.451579 . [all data]

Fajardo and Apkarian, 1988
Fajardo, M.E.; Apkarian, V.A., Charge transfer photodynamics in halogen doped xenon matrices. II. Photoinduced harpooning and the delocalized charge transfer states of solid xenon halides (F, Cl, Br, I), J. Chem. Phys., 1988, 89, 7, 4102, https://doi.org/10.1063/1.454846 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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