2-Methyl-bicyclo[2.2.2]-oct-2-ene

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-18.6 ± 2.3kJ/molCmKozina, Bychikhina, et al., 1974 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-62.0 ± 2.2kJ/molCmKozina, Bychikhina, et al., 1974 
Quantity Value Units Method Reference Comment
Δcliquid-5480.5 ± 2.1kJ/molCmKozina, Bychikhina, et al., 1974Corresponding Δfliquid = -61.97 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap43.35 ± 0.75kJ/molVKozina, Bychikhina, et al., 1974ALS
Δvap43.4kJ/molN/AKozina, Bychikhina, et al., 1974DRB
Δvap43.5 ± 0.4kJ/molEBVarushchenko, Druzhimina, et al., 1974See also Kozina, Bychikhina, et al., 1974, 2.; AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
40.2378.AStephenson and Malanowski, 1987Based on data from 363. to 402. K.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kozina, Bychikhina, et al., 1974
Kozina, M.P.; Bychikhina, L.V.; Gal'chenko, G.L.; Kalinichenko, A.N.; Bobyleva, A.A.; Belikova, N.A.; Plate, A.F., Enthalpies of combustion and formation of 2-methylenebicyclo-[2,2,2]octane and 2-methylbicylo-[2,2,2]oct-2-ene, Russ. J. Phys. Chem. (Engl. Transl.), 1974, 48, 1226-1227. [all data]

Varushchenko, Druzhimina, et al., 1974
Varushchenko, R.M.; Druzhimina, A.I.; Kovner, O.Y.; Mil'vitskaya, E.M.; Bobyleva, A.A.; Belikova, N.A.; Gal'chenko, G.L., Russ. J. Phys. Chem., 1974, 48, 1121. [all data]

Kozina, Bychikhina, et al., 1974, 2
Kozina, M.P.; Bychikhina, L.V.; Gal'chenko, G.L.; Kalinichenko, A.N.; Bobyleva, A.A.; Belikova, N.A.; Plate, A.F., Zh. Fiz. Khim., 1974, 48, 2075. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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