Phenol, 2,3,6-trimethyl-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Phase change data

Go To: Top, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus354.65KN/ABaglai, Gurarii, et al., 1988Uncertainty assigned by TRC = 0.4 K; TRC
Tfus335.KN/AGubareva, Bulaeva, et al., 1985Uncertainty assigned by TRC = 2. K; TRC
Tfus335.15KN/AKarr, 1957Uncertainty assigned by TRC = 2. K; TRC
Tfus335.45KN/ASears and Kitchen, 1949Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Δsub86.7 ± 0.6kJ/molGSVerevkin, 1999AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
51.1 ± 0.2431.Baglay, Gurariy, et al., 1988Based on data from 359. to 503. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
22.05331.2Verevkin, 1999AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin RADIAN CORP
NIST MS number 70281

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Baglai, Gurarii, et al., 1988
Baglai, A.K.; Gurarii, L.L.; Kuleshov, G.G., Physical Properties of Compounds Used in Vitamin Synthesis, J. Chem. Eng. Data, 1988, 33, 512. [all data]

Gubareva, Bulaeva, et al., 1985
Gubareva, A.I.; Bulaeva, N.V.; Gerasimov, P.A.; Gadzhiev, S.N., Physicochemical propeties of 2,3,6-trimethylphenol, Zh. Prikl. Khim. (Leningrad), 1985, 58, 191. [all data]

Karr, 1957
Karr, C., , U. S. Bur. Mines, Inform. Circ. IC 7802, 1957. [all data]

Sears and Kitchen, 1949
Sears, W.C.; Kitchen, L.J., Infrared Studies of Hindered Phenols, J. Am. Chem. Soc., 1949, 71, 4110. [all data]

Verevkin, 1999
Verevkin, Sergey P., Thermochemistry of phenols: buttress effects in sterically hindered phenols, The Journal of Chemical Thermodynamics, 1999, 31, 11, 1397-1416, https://doi.org/10.1006/jcht.1999.0466 . [all data]

Baglay, Gurariy, et al., 1988
Baglay, A.K.; Gurariy, L.L.; Kuleshov, G.G., Physical properties of compounds used in vitamin synthesis, J. Chem. Eng. Data, 1988, 33, 512-518. [all data]


Notes

Go To: Top, Phase change data, Mass spectrum (electron ionization), References