Stibine, trimethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas7.7 ± 6.0kcal/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid0.2 ± 6.0kcal/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Δcliquid-698.2 ± 6.0kcal/molCC-SBLong and Sackman, 1955Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δvap7.77 ± 0.002kcal/molN/AFulem, Moravek, et al., 2010Based on data from 249. to 296. K.; AC
Δvap7.50 ± 0.31kcal/molCC-SBBamford, Levi, et al., 1946Please also see Long and Sackman, 1955, 2.; MS

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Stibine, trimethyl- (g) = C2H6Sb (g) + Methane (g)

By formula: C3H9Sb (g) = C2H6Sb (g) + CH4 (g)

Quantity Value Units Method Reference Comment
Δr59.0 to 61.9kcal/molN/ASmith and Patrick, 1983 
Δr61.0 ± 4.0kcal/molN/AMcMillen and Golden, 1982 

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Long and Sackman, 1955
Long, L.H.; Sackman, J.F., The heat of formation of antimony trimethyl, Trans. Faraday Soc., 1955, 51, 1062, https://doi.org/10.1039/tf9555101062 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Fulem, Moravek, et al., 2010
Fulem, Michal; Moravek, Pavel; Pangrac, Jiri; Hulicius, Eduard; Simecek, Tomislav; Ruzicka, Kvetoslav; Ruzicka, Vlastimil; Kozyrkin, Boris; Shatunov, Valery, Vapor Pressure of Trimethylantimony and tert -Butyldimethylantimony, J. Chem. Eng. Data, 2010, 55, 1, 362-365, https://doi.org/10.1021/je900372v . [all data]

Bamford, Levi, et al., 1946
Bamford, C.H.; Levi, D.L.; Newitt, D.M., J. Chem. Soc., 1946, 468.. [all data]

Long and Sackman, 1955, 2
Long, L.H.; Sackman, J.F., Research (Correspondence), 1955, 8, 523. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]


Notes

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