Furan
- Formula: C4H4O
- Molecular weight: 68.0740
- IUPAC Standard InChIKey: YLQBMQCUIZJEEH-UHFFFAOYSA-N
- CAS Registry Number: 110-00-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Divinylene oxide; Furfuran; Oxacyclopentadiene; Oxole; Tetrole; Furane; Furfurane; NCI-C56202; Rcra waste number U124; UN 2389; 1,4-Epoxy-1,3-butadiene
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -27.7 | kJ/mol | N/A | Zaheeruddin and Lodhi, 1991 | Value computed using ΔfHliquid° value of -55.4 kj/mol from Zaheeruddin and Lodhi, 1991 and ΔvapH° value of 27.6 kj/mol from Guthrie, Scott, et al., 1952.; DRB |
ΔfH°gas | -34.7 | kJ/mol | Ccb | Guthrie, Scott, et al., 1952 | ALS |
ΔfH°gas | -29.8 | kJ/mol | N/A | Landrieu, Baylocq, et al., 1929 | Value computed using ΔfHliquid° value of -57.5 kj/mol from Landrieu, Baylocq, et al., 1929 and ΔvapH° value of 27.6 kj/mol from Guthrie, Scott, et al., 1952.; DRB |
Constant pressure heat capacity of gas
Cp,gas (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
33.26 | 50. | Dorofeeva O.V., 1992 | p=1 bar. Selected entropies and heat capacities are in good agreement with those obtained in other statistical calculations [ Guthrie G.B., 1952, Bak B., 1955, Rico M., 1967, Soptrajanov B., 1968, Chao J., 1986, Klots T.D., 1994].; GT |
33.53 | 100. | ||
36.39 | 150. | ||
43.60 | 200. | ||
59.43 | 273.15 | ||
65.4 ± 1.5 | 298.15 | ||
65.85 | 300. | ||
88.80 | 400. | ||
107.82 | 500. | ||
122.77 | 600. | ||
134.59 | 700. | ||
144.13 | 800. | ||
152.00 | 900. | ||
158.60 | 1000. | ||
164.20 | 1100. | ||
168.97 | 1200. | ||
173.08 | 1300. | ||
176.62 | 1400. | ||
179.69 | 1500. |
Constant pressure heat capacity of gas
Cp,gas (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
70.29 | 317.25 | Guthrie G.B., 1952 | GT |
80.12 | 358.20 | ||
90.00 | 402.20 | ||
99.58 | 449.20 | ||
106.48 | 487.20 |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | Ccb | Zaheeruddin and Lodhi, 1991 | uncertain value: -55.36 kJ/mol; ALS | ||
ΔfH°liquid | -62.34 | kJ/mol | Ccb | Guthrie, Scott, et al., 1952 | ALS |
ΔfH°liquid | -57.45 | kJ/mol | Ccb | Landrieu, Baylocq, et al., 1929 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | Ccb | Zaheeruddin and Lodhi, 1991 | uncertain value: -2090.36 kJ/mol; ALS | ||
ΔcH°liquid | -2083.5 | kJ/mol | Ccb | Guthrie, Scott, et al., 1952 | Corresponding ΔfHºliquid = -62.17 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°liquid | -2088. | kJ/mol | Ccb | Landrieu, Baylocq, et al., 1929 | Corresponding ΔfHºliquid = -57.3 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 176.65 | J/mol*K | N/A | Guthrie, Scott, et al., 1952, 2 | DH |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
114.56 | 298.15 | Guthrie, Scott, et al., 1952, 2 | T = 11 to 300 K.; DH |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 304.7 ± 0.6 | K | AVG | N/A | Average of 12 out of 13 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 187.44 | K | N/A | Guanquan, Ott, et al., 1986 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tfus | 187.56 | K | N/A | Goates, Ott, et al., 1973 | Uncertainty assigned by TRC = 0.05 K; TRC |
Tfus | 187.15 | K | N/A | Brooks and Pilcher, 1959 | Uncertainty assigned by TRC = 1. K; TRC |
Tfus | 187.47 | K | N/A | Boord, Greenlee, et al., 1946 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tfus | 187.55 | K | N/A | Dolliver, Gresham, et al., 1938 | Uncertainty assigned by TRC = 0.3 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 187.54 | K | N/A | Wilhoit, Chao, et al., 1985 | Crystal phase 1 phase; Uncertainty assigned by TRC = 0.05 K; TRC |
Ttriple | 187.55 | K | N/A | Guthrie, Scott, et al., 1952, 3 | Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 490.2 | K | N/A | Majer and Svoboda, 1985 | |
Tc | 490.2 | K | N/A | Cheng, McCoubrey, et al., 1962 | Uncertainty assigned by TRC = 0.3 K; Visual (5-cm 2-mm bore tubes) in nitrate-nitrite bath, TE or TH cal. vs NPL thermometer.; TRC |
Tc | 487. | K | N/A | Kobe, Ravicz, et al., 1956 | Uncertainty assigned by TRC = 2. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 53.20 | bar | N/A | Kobe, Ravicz, et al., 1956 | Uncertainty assigned by TRC = 1.172 bar; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Vc | 0.219 | l/mol | N/A | Kobe, Ravicz, et al., 1956 | Uncertainty assigned by TRC = 0.005 l/mol; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 27.71 | kJ/mol | N/A | Majer and Svoboda, 1985 | |
ΔvapH° | 28.2 | kJ/mol | N/A | Moiseev and Antonova, 1970 | Based on data from 277. to 323. K.; AC |
ΔvapH° | 27.6 | kJ/mol | N/A | Guthrie, Scott, et al., 1952 | DRB |
Reduced pressure boiling point
Tboil (K) | Pressure (bar) | Reference | Comment |
---|---|---|---|
305.2 | 1.01 | Aldrich Chemical Company Inc., 1990 | BS |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
27.1 | 304.5 | N/A | Majer and Svoboda, 1985 | |
27.451 | 298.15 | N/A | Guthrie, Scott, et al., 1952, 2 | P = 79.934 kPa; DH |
30.2 | 253. | A | Stephenson and Malanowski, 1987 | Based on data from 238. to 356. K.; AC |
27.7 | 304.36 | E | Guthrie, Scott, et al., 1952 | ALS |
28.6 | 290. | N/A | Guthrie, Scott, et al., 1952, 2 | Based on data from 275. to 334. K. See also Boublik, Fried, et al., 1984.; AC |
27.2 | 304.2 | V | Mathews and Fehlandt, 1931 | ALS |
Enthalpy of vaporization
ΔvapH =
A exp(-βTr) (1 − Tr)β
ΔvapH =
Enthalpy of vaporization (at saturation pressure)
(kJ/mol)
Tr = reduced temperature (T / Tc)
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Temperature (K) | A (kJ/mol) | β | Tc (K) | Reference | Comment |
---|---|---|---|---|---|
279. to 305. | 42.32 | 0.2802 | 490.2 | Majer and Svoboda, 1985 |
Entropy of vaporization
ΔvapS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
92.07 | 298.15 | Guthrie, Scott, et al., 1952, 2 | P; DH |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
275.70 to 334.58 | 4.10003 | 1060.801 | -45.416 | Guthrie, Scott, et al., 1952, 2 | Coefficents calculated by NIST from author's data. |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
3.8 | 187.6 | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
13.64 | 150.0 | Domalski and Hearing, 1996 | CAL |
20.29 | 187.6 |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
2.0468 | 150.0 | crystaline, II | crystaline, I | Guthrie, Scott, et al., 1952, 2 | DH |
3.8024 | 187.55 | crystaline, I | liquid | Guthrie, Scott, et al., 1952, 2 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
13.65 | 150.0 | crystaline, II | crystaline, I | Guthrie, Scott, et al., 1952, 2 | DH |
20.27 | 187.55 | crystaline, I | liquid | Guthrie, Scott, et al., 1952, 2 | DH |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
RCD - Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: C4H5O+ + C4H4O = (C4H5O+ • C4H4O)
Bond type: Hydrogen bonds of the type OH-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 42. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1987 | gas phase; ΔrH<; M |
ΔrH° | 79. | kJ/mol | PHPMS | Meot-Ner (Mautner), Ross, et al., 1985 | gas phase; Entropy change calculated or estimated, ΔrH<; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 130. | J/mol*K | N/A | Meot-Ner (Mautner), Ross, et al., 1985 | gas phase; Entropy change calculated or estimated, ΔrH<; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
28. | 382. | PHPMS | Meot-Ner (Mautner), Ross, et al., 1985 | gas phase; Entropy change calculated or estimated, ΔrH<; M |
C4H3O- + =
By formula: C4H3O- + H+ = C4H4O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1636.2 ± 1.5 | kJ/mol | G+TS | Grabowski and Owusu | gas phase; B |
ΔrH° | 1624. ± 13. | kJ/mol | G+TS | DePuy, Kass, et al., 1988 | gas phase; Order:H2O < furan < 2-Me-furan < MeOH. D exchange indicates anion at C-2.; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1602.1 ± 0.84 | kJ/mol | IMRE | Grabowski and Owusu | gas phase; B |
ΔrG° | 1590. ± 13. | kJ/mol | IMRB | DePuy, Kass, et al., 1988 | gas phase; Order:H2O < furan < 2-Me-furan < MeOH. D exchange indicates anion at C-2.; B |
By formula: C4H4O + 2H2 = C4H8O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -151.1 ± 0.50 | kJ/mol | Chyd | Dolliver, Gresham, et al., 1938, 2 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -153.3 ± 0.50 kJ/mol; At 355 °K; ALS |
By formula: C4H4O+ + C4H4O = (C4H4O+ • C4H4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 72.0 | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 99.2 | J/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1987 | gas phase; M |
By formula: (C4H4O+ • C4H4O) + C4H4O = (C4H4O+ • 2C4H4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 30. | kJ/mol | PHPMS | Hiraoka, Takimoto, et al., 1987 | gas phase; ΔrH<; M |
By formula: Na+ + C4H4O = (Na+ • C4H4O)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
49.0 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zaheeruddin and Lodhi, 1991
Zaheeruddin, M.; Lodhi, Z.H.,
Enthalpies of formation of some cyclic compounds,
Phys. Chem. (Peshawar Pak.), 1991, 10, 111-118. [all data]
Guthrie, Scott, et al., 1952
Guthrie, G.B., Jr.; Scott, D.W.; Hubbard, W.N.; Katz, C.; McCullough, J.P.; Gross, M.E.; Williamson, K.D.; Waddington, G.,
Thermodynamic properties of furan,
J. Am. Chem. Soc., 1952, 74, 4662-46. [all data]
Landrieu, Baylocq, et al., 1929
Landrieu, P.; Baylocq, F.; Johnson, J.R.,
Etude thermochimique dans la serie furanique,
Bull. Soc. Chim. France, 1929, 45, 36-49. [all data]
Dorofeeva O.V., 1992
Dorofeeva O.V.,
Ideal gas thermodynamic properties of oxygen heterocyclic compounds. Part 1. Three-membered, four-membered and five-membered rings,
Thermochim. Acta, 1992, 194, 9-46. [all data]
Guthrie G.B., 1952
Guthrie G.B., Jr.,
Thermodynamic properties of furan,
J. Am. Chem. Soc., 1952, 74, 4662-4669. [all data]
Bak B., 1955
Bak B.,
Infrared absorption spectra of alpha and beta monodeutero, and alpha, alpha' dideutero furan vapors. Heat capacity and entropy of furan,
Acta Chem. Scand., 1955, 9, 749-762. [all data]
Rico M., 1967
Rico M.,
Fundamental vibrations of furan and deuterated derivatives,
J. Mol. Spectrosc., 1967, 24, 133-148. [all data]
Soptrajanov B., 1968
Soptrajanov B.,
Thermodynamic functions of furan and deuterated furans,
Croat. Chem. Acta, 1968, 40, 241-245. [all data]
Chao J., 1986
Chao J.,
Thermodynamic properties of key organic oxygen compounds in the carbon range C1 to C4. Part 2. Ideal gas properties,
J. Phys. Chem. Ref. Data, 1986, 15, 1369-1436. [all data]
Klots T.D., 1994
Klots T.D.,
Complete vapor phase assignment for the fundamental vibrations of furan, pyrrole and thiophene,
Spectrochim. Acta, 1994, A50, 765-795. [all data]
Guthrie, Scott, et al., 1952, 2
Guthrie, G.B., Jr.; Scott, D.W.; Hubbard, W.N.; Katz, C.; McCullough, J.P.; Gross, M.E.; Williamson, K.D.; Waddington, G.,
Thermodynamic properties of furan,
J. Am. Chem. Soc., 1952, 74, 4662-4669. [all data]
Guanquan, Ott, et al., 1986
Guanquan, C.; Ott, J.B.; Goates, J.R.,
(Solid + liquid) Phase Equilibria and Solid-Compound Formation in Tetrachloromethane + furan, + Pyridine, and + N-methylpyrrole,
J. Chem. Thermodyn., 1986, 18, 603. [all data]
Goates, Ott, et al., 1973
Goates, J.R.; Ott, J.B.; Reeder, J.,
Solid + liquid phae equilibria and solid compound formation in hexafluorobenzene + benzene, + pyridine, + furan, and + thiophen,
J. Chem. Thermodyn., 1973, 5, 135. [all data]
Brooks and Pilcher, 1959
Brooks, J.H.; Pilcher, G.,
A Simple Melting Point Calorimeter for Moderately Precise Determination of Purity,
J. Chem. Soc., 1959, 1959, 1535. [all data]
Boord, Greenlee, et al., 1946
Boord, C.E.; Greenlee, K.W.; Perilstein, W.L.,
The Synthesis, Purification and Prop. of Hydrocarbons of Low Mol. Weight, Am. Pet. Inst. Res. Proj. 45, Eighth Annu. Rep., Ohio State Univ., June 30, 1946. [all data]
Dolliver, Gresham, et al., 1938
Dolliver, M.A.; Gresham, T.L.; Kistiakowsky, G.B.; Smith, E.A.; Vaughan, W.E.,
Heats of Organic Reactions VI. Heats of Hydrogenation of Some Oxygen- Containing Compounds,
J. Am. Chem. Soc., 1938, 60, 440. [all data]
Wilhoit, Chao, et al., 1985
Wilhoit, R.C.; Chao, J.; Hall, K.R.,
Thermodynamic Properties of Key Organic Compounds in the Carbon Range C1 to C4. Part 1. Properties of Condensed Phases,
J. Phys. Chem. Ref. Data, 1985, 14, 1. [all data]
Guthrie, Scott, et al., 1952, 3
Guthrie, G.B.; Scott, D.W.; Hubbard, W.N.; Katz, C.; McCullough, J.P.; Gross, M.E.; Williamson, K.D.; Waddington, G.,
Thermodynamic properties of Furan,
J. Am. Chem. Soc., 1952, 74, 4662-9. [all data]
Majer and Svoboda, 1985
Majer, V.; Svoboda, V.,
Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]
Cheng, McCoubrey, et al., 1962
Cheng, D.C.H.; McCoubrey, J.C.; Phillips, D.G.,
Critical Temperatures of Some Organic Cyclic Compounds,
Trans. Faraday Soc., 1962, 58, 224. [all data]
Kobe, Ravicz, et al., 1956
Kobe, K.A.; Ravicz, A.E.; Vohra, S.P.,
Critical Properties and Vapor Pressures of Some Ethers and Heterocyclic Compounds,
J. Chem. Eng. Data, 1956, 1, 50. [all data]
Moiseev and Antonova, 1970
Moiseev, V.D.; Antonova, N.D.,
Zh. Fiz. Khim., 1970, 44, 11, 2912. [all data]
Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc.,
Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E.,
The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]
Mathews and Fehlandt, 1931
Mathews, J.H.; Fehlandt, P.R.,
The heats of vaporization of some organic compounds,
J. Am. Chem. Soc., 1931, 53, 3212-32. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Hiraoka, Takimoto, et al., 1987
Hiraoka, K.; Takimoto, H.; Yamabe, S.,
Stabilities and Structures in Cluster Ions of Five-Membered Heterocyclic Compounds Containing O, N and S Atoms,
J. Am. Chem. Soc., 1987, 109, 24, 7346, https://doi.org/10.1021/ja00258a018
. [all data]
Meot-Ner (Mautner), Ross, et al., 1985
Meot-Ner (Mautner), M.; Ross, M.M.; Campana, J.E.,
Stable Hydrogen - Bonded Isomers of Covalent Ions,
J. Am. Chem. Soc., 1985, 107, 4835. [all data]
Grabowski and Owusu
Grabowski, J.J.; Owusu, D.,
, as cited in 98CLI/WEN. [all data]
DePuy, Kass, et al., 1988
DePuy, C.H.; Kass, S.R.; Bean, G.P.,
Formation and Reactions of Heteroaromatic Anions in the Gas Phase,
J. Org. Chem., 1988, 53, 19, 4427, https://doi.org/10.1021/jo00254a001
. [all data]
Dolliver, Gresham, et al., 1938, 2
Dolliver, M.A.; Gresham, T.L.; Kistiakowsky, G.B.; Smith, E.A.; Vaughan, W.E.,
Heats of organic reactions. VI. Heats of hydrogenation of some oxygen-containing compounds,
J. Am. Chem. Soc., 1938, 60, 440-450. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
McMahon and Ohanessian, 2000
McMahon, T.B.; Ohanessian, G.,
An Experimental and Ab Initio Study of the Nature of the Binding in Gas-Phase Complexes of Sodium Ions,
Chem. Eur. J., 2000, 6, 16, 2931, https://doi.org/10.1002/1521-3765(20000818)6:16<2931::AID-CHEM2931>3.0.CO;2-7
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References
- Symbols used in this document:
Cp,gas Constant pressure heat capacity of gas Cp,liquid Constant pressure heat capacity of liquid Pc Critical pressure S°liquid Entropy of liquid at standard conditions T Temperature Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature Vc Critical volume ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions ΔvapS Entropy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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