Mixed valence iron oxo-centered complex with acetate
- Formula: C36H46Fe3N4O13
- Molecular weight: 910.304
- CAS Registry Number: 105943-92-8
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Constant pressure heat capacity of solid
| Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 1094.7 | 299.635 | Sorai, Shiomi, et al., 1987 | T = 12 to 350 K. Unsmoothed experimental datum. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Temperature of phase transition
| Ttrs (K) | Initial Phase | Final Phase | Reference | Comment |
|---|---|---|---|---|
| 181. | crystaline, V | crystaline, IV | Sorai, Shiomi, et al., 1987 | |
| 263.5 | crystaline, IV | crystaline, III | Sorai, Shiomi, et al., 1987 | |
| 271.5 | crystaline, III | crystaline, II | Sorai, Shiomi, et al., 1987 | |
| 282.2 | crystaline, II | crystaline, I | Sorai, Shiomi, et al., 1987 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sorai, Shiomi, et al., 1987
Sorai, M.; Shiomi, Y.; Hendrickson, D.N.; Oh, S.M.; Kambara, T.,
Heat capacity and phase transitions of the mixed-valence compound hexakis(acetato)tris(3-methylpyridine)oxotriiron.3-methylpyridine, [Fe3O(O2CCH3)6(3-Me-py)3].3-Me-py,
Inorg. Chem., 1987, 26, 223-230. [all data]
Notes
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- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid Ttrs Temperature of phase transition - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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