Nitric oxide anion
- Formula: NO-
- Molecular weight: 30.0066
- IUPAC Standard InChIKey: FZRKAZHKEDOPNN-UHFFFAOYSA-N
- CAS Registry Number: 14967-78-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: NO-; Nitrogen oxide, ion
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- Information on this page:
- Other data available:
- Reaction thermochemistry data: reactions 51 to 71
- Gas phase ion energetics data
- Ion clustering data
- Constants of diatomic molecules
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
By formula: NO- + N2 = (NO- • N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
ΔrH° | 20. | kJ/mol | DT | Gheno and Fitaire, 1987 | gas phase; ΔrS+-12. J/mol*K; M |
ΔrH° | 18. | kJ/mol | HPMS | Speller, Fitaire, et al., 1983 | gas phase; Entropy change is questionable; M |
ΔrH° | 22. | kJ/mol | HPMS | Turner and Conway, 1976 | gas phase; M |
ΔrH° | 19. | kJ/mol | DT | Johnsen, Huang, et al., 1975 | gas phase; corrected for ln T by Keesee and Castleman, 1986; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 71.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
ΔrS° | 57.7 | J/mol*K | DT | Gheno and Fitaire, 1987 | gas phase; ΔrS+-12. J/mol*K; M |
ΔrS° | 55.6 | J/mol*K | HPMS | Speller, Fitaire, et al., 1983 | gas phase; Entropy change is questionable; M |
ΔrS° | 79.1 | J/mol*K | HPMS | Turner and Conway, 1976 | gas phase; M |
ΔrS° | 65.7 | J/mol*K | DT | Johnsen, Huang, et al., 1975 | gas phase; corrected for ln T by Keesee and Castleman, 1986; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
2. | 200. | FA | Dunkin, Fehsenfeld, et al., 1971 | gas phase; M |
By formula: NO- + N2O = (NO- • N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 60. ± 100. | kJ/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 75. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
ΔrS° | 62.3 | J/mol*K | DT | Illies, 1988 | gas phase; ΔrH(0 K)=32.2 kJ/mol; M |
By formula: NO- + H2O = (NO- • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 77.4 | kJ/mol | PHPMS | French, Hills, et al., 1973 | gas phase; M |
ΔrH° | 69.5 | kJ/mol | PES | Eaton, Arnold, et al., 1990 | gas phase; M |
ΔrH° | 95.0 | kJ/mol | MS | Burdett and Hayhurst, 1982 | gas phase; flame source, about 1600 K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 96.2 | J/mol*K | PHPMS | French, Hills, et al., 1973 | gas phase; M |
ΔrS° | 100. | J/mol*K | MS | Burdett and Hayhurst, 1982 | gas phase; flame source, about 1600 K; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
53.1 | 296. | SAMS | Puckett and Teague, 1971 | gas phase; switching reaction(NO+)NO; M |
By formula: (NO- • H2O) + H2O = (NO- • 2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 65.69 | kJ/mol | N/A | Eaton, Arnold, et al., 1990 | gas phase; Vertical Detachment Energy: 1.860±0.020 eV; B,M |
ΔrH° | 67.4 | kJ/mol | PHPMS | French, Hills, et al., 1973 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 107. | J/mol*K | PHPMS | French, Hills, et al., 1973 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
35. | 293. | HPMS | McAdams and Bone, 1972 | gas phase; M |
36. | 296. | FA | Howard, Rundle, et al., 1971 | gas phase; M |
36. | 296. | SAMS | Puckett and Teague, 1971 | gas phase; M |
By formula: NO- + CO2 = (NO- • CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 36. ± 1. | kJ/mol | DT | Illies, 1988 | gas phase; ΔrH(0 K)=36.0 kJ/mol; M |
ΔrH° | 32. ± 2. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
ΔrH° | 57.7 | kJ/mol | FA | Dunkin, Fehsenfeld, et al., 1971 | gas phase; switching reaction(NO+)NO, ΔrH<; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 75.3 | J/mol*K | DT | Illies, 1988 | gas phase; ΔrH(0 K)=36.0 kJ/mol; M |
ΔrS° | 57.3 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: (NO- • N2O) + N2O = (NO- • 2N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 24.7 ± 3.8 | kJ/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
ΔrH° | 19.2 | kJ/mol | N/A | Coe, Snodgrass, et al., 1987 | gas phase; B |
ΔrH° | 23. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; M |
ΔrH° | 30. | kJ/mol | PES | Coe, Snodgrass, et al., 1986 | gas phase; D(N2O)2 not accounted for; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -4.2 ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B |
By formula: (NO- • 2N2O) + N2O = (NO- • 3N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 21.8 ± 3.8 | kJ/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
ΔrH° | 21. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 96. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
ΔrS° | 88. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -5.0 ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B |
By formula: (NO- • 2H2O) + H2O = (NO- • 3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 74.5 | kJ/mol | PES | Eaton, Arnold, et al., 1990 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
23. | 308. | PHPMS | French, Hills, et al., 1973 | gas phase; M |
25. | 293. | HPMS | McAdams and Bone, 1972 | gas phase; M |
25. | 296. | FA | Howard, Rundle, et al., 1971 | gas phase; M |
25. | 296. | SAMS | Puckett and Teague, 1971 | gas phase; M |
By formula: (NO- • N2) + N2 = (NO- • 2N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
ΔrH° | 16. | kJ/mol | HPMS | Speller and Fitaire, 1983 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 72.8 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
ΔrS° | 52.7 | J/mol*K | HPMS | Speller and Fitaire, 1983 | gas phase; Entropy change is questionable; M |
By formula: (NO- • 3N2O) + N2O = (NO- • 4N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20.9 ± 3.8 | kJ/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
ΔrH° | 19. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -5.0 ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B |
By formula: (NO- • 4N2O) + N2O = (NO- • 5N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17.6 ± 3.8 | kJ/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
ΔrH° | 19. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -6.3 ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B |
By formula: (NO- • 2N2) + N2 = (NO- • 3N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 16. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 70.3 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
4. | 204. | HPMS | Speller, Fitaire, et al., 1983 | gas phase; M |
By formula: (NO- • 3N2) + N2 = (NO- • 4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 74.9 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
2. | 204. | HPMS | Speller, Fitaire, et al., 1983 | gas phase; M |
By formula: (NO- • 9N2) + N2 = (NO- • 10N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.03 | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 79. | J/mol*K | N/A | Hiraoka and Yamabe, 1989 | gas phase; Entropy change calculated or estimated; M |
By formula: (NO- • 5CO2) + CO2 = (NO- • 6CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 21. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 120. | J/mol*K | N/A | Hiraoka and Yamabe, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: NO- + O2 = (NO- • O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.1 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 60.7 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
-2. | 200. | FA | Dunkin, Fehsenfeld, et al., 1971 | gas phase; DG>; M |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1511.6 ± 0.63 | kJ/mol | D-EA | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1484.0 ± 1.4 | kJ/mol | H-TS | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion; B |
By formula: NO- + C3H6O = (NO- • C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 159. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978, ref. to PA(NH3)=872. kJ/mol; M |
By formula: NO- + NO = (NO- • NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 57.7 | kJ/mol | PI | Linn, Ono, et al., 1981 | gas phase; M |
ΔrH° | 56.9 | kJ/mol | PI | Ng, Tiedemann, et al., 1977 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
29. | 296. | SAMS | Puckett and Teague, 1971 | gas phase; M |
By formula: (NO- • 5N2O) + N2O = (NO- • 6N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18.4 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B,M,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -7.9 ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B |
By formula: (NO- • 6N2O) + N2O = (NO- • 7N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17.6 ± 1.3 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B,M,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -11. ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; B |
By formula: NO- + C8H10 = (NO- • C8H10)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 186. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C7H5N = (NO- • C7H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 172. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C7H6O = (NO- • C7H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 183. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C9H12 = (NO- • C9H12)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 189. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C7H8 = (NO- • C7H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 185. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C6H5Cl = (NO- • C6H5Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 161. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C5H10O2 = (NO- • C5H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 176. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C4H8O = (NO- • C4H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 164. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C4H8O2 = (NO- • C4H8O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 174. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C6H5F = (NO- • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 158. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C7H14O = (NO- • C7H14O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 187. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C4H10O = (NO- • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 173. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C3H6O = (NO- • C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 172. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C6H6 = (NO- • C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 172. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C2H4O = (NO- • C2H4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 164. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C4H8O = (NO- • C4H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 177. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C3H6O2 = (NO- • C3H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 167. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C5H10O = (NO- • C5H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 179. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C9H12 = (NO- • C9H12)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 189. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C6H5NO2 = (NO- • C6H5NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 164. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: NO- + C7H5F3 = (NO- • C7H5F3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 150. | kJ/mol | ICR | Reents and Freiser, 1981 | gas phase; switching reaction,Thermochemical ladder(NO+)C2H5OH, Entropy change calculated or estimated; Farid and McMahon, 1978; M |
By formula: (NO- • 2O2) + O2 = (NO- • 3O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.8 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 65.7 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: (NO- • 3O2) + O2 = (NO- • 4O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.2 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 67.4 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: (NO- • 4N2) + N2 = (NO- • 5N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 13. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 89.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
By formula: (NO- • 4O2) + O2 = (NO- • 5O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.8 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 80.3 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
By formula: (NO- • 5N2) + N2 = (NO- • 6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 13. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 95.8 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
By formula: (NO- • 6N2) + N2 = (NO- • 7N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 95.4 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
By formula: (NO- • 7N2) + N2 = (NO- • 8N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 97.5 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
By formula: (NO- • 8N2) + N2 = (NO- • 9N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 81.6 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase; M |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka and Yamabe, 1989
Hiraoka, K.; Yamabe, S.,
How are Nitrogen Molecules Bound to NO2+ and NO+?,
J. Chem. Phys., 1989, 90, 6, 3268, https://doi.org/10.1063/1.455880
. [all data]
Gheno and Fitaire, 1987
Gheno, F.; Fitaire, M.,
Association of N2 with NH4+ and H3O+(H2O)n, n = 1,2,3,
J. Chem. Phys., 1987, 87, 2, 953, https://doi.org/10.1063/1.453250
. [all data]
Speller, Fitaire, et al., 1983
Speller, C.V.; Fitaire, M.; Pointu, A.M.,
Three - Body Association Reactions of NO+ and O2+ with N2,
J. Chem. Phys., 1983, 79, 5, 2190, https://doi.org/10.1063/1.446067
. [all data]
Turner and Conway, 1976
Turner, D.L.; Conway, D.C.,
Stability of the NO+.N2 Ion Cluster,
J. Chem. Phys., 1976, 65, 10, 3944, https://doi.org/10.1063/1.432887
. [all data]
Johnsen, Huang, et al., 1975
Johnsen, R.; Huang, C.M.; Biondi, M.A.,
The Formation and Breakup of NO2+.N2 Clusters in N2 at Low Temperatures,
J. Chem. Phys., 1975, 63, 8, 3374, https://doi.org/10.1063/1.431751
. [all data]
Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr.,
Thermochemical data on Ggs-phase ion-molecule association and clustering reactions,
J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]
Dunkin, Fehsenfeld, et al., 1971
Dunkin, D.B.; Fehsenfeld, F.C.; Schelmetekopf, A.L.; Ferguson, E.E.,
Three-Body Association Reactions of NO+ with O2, N2, and CO2,
J. Chem. Phys., 1971, 54, 9, 3817, https://doi.org/10.1063/1.1675432
. [all data]
Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Sato, T.; Yamabe, S.,
Gas-Phase Solavtion of NO+, O2+, N2O+, and H3O+ with N2O,
J. Chem. Phys., 1994, 101, 5, 4073, https://doi.org/10.1063/1.467524
. [all data]
Illies, 1988
Illies, A.J.,
Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures,
J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037
. [all data]
French, Hills, et al., 1973
French, M.A.; Hills, L.P.; Kebarle, P.,
Kinetics and Temperature Dependence of the Hydration of the Nitrosonium Ion in the Gas Phase,
Can. J. Chem., 1973, 51, 3, 456, https://doi.org/10.1139/v73-068
. [all data]
Eaton, Arnold, et al., 1990
Eaton, J.G.; Arnold, S.T.; Bowen, K.H.,
The Negative Ion Photoelectron (Photodetachment) Spectra of NO-(H2O)n=1,2,
Int. J. Mass Spectrom. Ion Proc., 1990, 102, 303, https://doi.org/10.1016/0168-1176(90)80066-C
. [all data]
Burdett and Hayhurst, 1982
Burdett, N.A.; Hayhurst, A.N.,
Hydration of gas phase ions and the measurement of boundary layer cooling during flame sampling into a mass spectrometer.,
J. Chem. Soc. Faraday Trans. 1, 1982, 78, 2997. [all data]
Puckett and Teague, 1971
Puckett, L.J.; Teague, A.W.,
Production of H3O+.nH2O from NO+ Precursor in NO - H2O Gas Mixtures,
J. Chem. Phys., 1971, 54, 6, 2564, https://doi.org/10.1063/1.1675213
. [all data]
McAdams and Bone, 1972
McAdams, M.J.; Bone, L.I.,
Reactions of NO+ with H2O in a Photoionization Mass Spectrometer,
J. Chem. Phys., 1972, 57, 5, 2173, https://doi.org/10.1063/1.1678549
. [all data]
Howard, Rundle, et al., 1971
Howard, C.J.; Rundle, H.W.; Kaufman, F.,
Water Cluster Formation Rates of NO+ in He, Ar, N2, and O2 at 296 K,
J. Chem. Phys., 1971, 55, 10, 4772, https://doi.org/10.1063/1.1675576
. [all data]
Hiraoka and Yamabe, 1991
Hiraoka, K.; Yamabe, S.,
Cluster Ions: Gas Phase Stabilities of NO+(O2)n and NO+(CO2)n with n = 1 - 5,
J. Chem. Phys., 1991, 95, 9, 6800, https://doi.org/10.1063/1.461518
. [all data]
Hendricks, de Clercq, et al., 2002
Hendricks, J.H.; de Clercq, H.L.; Freidhoff, C.B.; Arnold, S.T.; Eaton, J.G.; Fancher, C.; Lyapustina, S.A.; S.,
Anion solvation at the microscopic level: Photoelectron spectroscopy of the solvated anion clusters, NO-(Y)(n), where Y=Ar, Kr, Xe, N2O, H2S, NH3, H2O, and C2H4(OH)(2),
J. Chem. Phys., 2002, 116, 18, 7926-7938, https://doi.org/10.1063/1.1457444
. [all data]
Coe, Snodgrass, et al., 1987
Coe, J.V.; Snodgrass, J.T.; Freidhoff, C.B.; McHugh, K.M.; Bowen, K.H.,
Photoelectron spectroscopy of the negative cluster ions, NO-(N2O)n=1,2,
J. Chem. Phys., 1987, 87, 4302. [all data]
Hiraoka, Fujimaki, et al., 1994, 2
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S.,
Gas-phase clustering reactions of O2(-), NO-, and O- with N2O: Isomeric structures for (NO-N2O)(-),
J. Phys. Chem., 1994, 98, 34, 8295, https://doi.org/10.1021/j100085a006
. [all data]
Coe, Snodgrass, et al., 1986
Coe, J.V.; Snodgrass, J.T.; Freidhoff, C.B.; McHugh, K.M.; Bowen, K.H.,
Negative ion photoelectron spectroscopy of N2O- and (N2O)2-,
Chem. Phys. Lett., 1986, 124, 274. [all data]
Speller and Fitaire, 1983
Speller, C.V.; Fitaire, M.,
Proceedings of the 16th International Conference on Phenomena of Ionized Gases, H. Boetticher, H. Wenk and E. Shulz - Gulde, ed(s)., ICPIG, Dusseldorf, 1983, 568. [all data]
Travers, Cowles, et al., 1989
Travers, M.J.; Cowles, D.C.; Ellison, G.B.,
Reinvestigation of the Electron Affinities of O2 and NO,
Chem. Phys. Lett., 1989, 164, 5, 449, https://doi.org/10.1016/0009-2614(89)85237-6
. [all data]
Reents and Freiser, 1981
Reents, W.D.; Freiser, B.S.,
Gas-Phase Binding Energies and Spectroscopic Properties of NO+ Charge-Transfer Complexes,
J. Am. Chem. Soc., 1981, 103, 2791. [all data]
Farid and McMahon, 1978
Farid, R.; McMahon, T.B.,
Gas-Phase Ion-Molecule Reactions of Alkyl Nitrites by Ion Cyclotron Resonance Spectroscopy,
Int. J. Mass Spectrom. Ion Phys., 1978, 27, 2, 163, https://doi.org/10.1016/0020-7381(78)80037-0
. [all data]
Linn, Ono, et al., 1981
Linn, S.H.; Ono, Y.; Ng, C.Y.,
Molecular Beam Photoionization Study of CO, N2, and NO Dimers and Clusters,
J. Chem. Phys., 1981, 74, 6, 3342, https://doi.org/10.1063/1.441486
. [all data]
Ng, Tiedemann, et al., 1977
Ng, C.Y.; Tiedemann, P.W.; Mahan, B.H.; Lee, Y.T.,
The Binding Energy between NO and NO+,
J. Chem. Phys., 1977, 66, 9, 3985, https://doi.org/10.1063/1.434450
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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