Iodine
- Formula: I2
- Molecular weight: 253.80894
- IUPAC Standard InChIKey: PNDPGZBMCMUPRI-UHFFFAOYSA-N
- CAS Registry Number: 7553-56-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: I2; Eranol; Iode; Iodine-127; Iodio; Iosan Superdip; Jod; Jood; Molecular iodine; Tincture iodine; Vistarin; Iodine crystals; Iodine sublimed; Diiodine; Diatomic iodine
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- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 51 to 75
- Henry's Law data
- Gas phase ion energetics data
- Ion clustering data
- Constants of diatomic molecules
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Condensed phase thermochemistry data
Go To: Top, Phase change data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | 13.52 | kJ/mol | Review | Chase, 1998 | Data last reviewed in June, 1982 |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid,1 bar | 150.36 | J/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1982 |
Quantity | Value | Units | Method | Reference | Comment |
S°solid,1 bar | 116.14 ± 0.30 | J/mol*K | Review | Cox, Wagman, et al., 1984 | CODATA Review value |
Quantity | Value | Units | Method | Reference | Comment |
S°solid | 116.14 | J/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1982 |
Liquid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 386.75 to 457.666 |
---|---|
A | 80.66919 |
B | 6.855652×10-8 |
C | -8.724352×10-8 |
D | 3.723132×10-8 |
E | 4.735829×10-10 |
F | -10.52782 |
G | 247.9798 |
H | 13.52302 |
Reference | Chase, 1998 |
Comment | Data last reviewed in June, 1982 |
Solid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 386.75 |
---|---|
A | -195.7635 |
B | 918.8984 |
C | -1079.242 |
D | 534.3219 |
E | 5.156403 |
F | 43.29938 |
G | -322.4780 |
H | 0.000000 |
Reference | Chase, 1998 |
Comment | Data last reviewed in June, 1982 |
Phase change data
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
311.9 to 456. | 3.36429 | 1039.159 | -146.589 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
Reaction thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
+ = I3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 136. ± 10. | kJ/mol | N/A | Taylor, Asmis, et al., 1999 | gas phase; B |
ΔrH° | 126. ± 5.9 | kJ/mol | CIDT | Do, Klein, et al., 1997 | gas phase; B |
ΔrH° | 356.1 | kJ/mol | Ther | Finch, Gates, et al., 1977 | gas phase; This value is far more bound than expected from other studies; B |
ΔrH° | 136.4 | kJ/mol | N/A | Check, Faust, et al., 2001 | gas phase; FeF3-(t); ; ΔS(EA)=2.8; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 94.14 | kJ/mol | N/A | Check, Faust, et al., 2001 | gas phase; FeF3-(t); ; ΔS(EA)=2.8; B |
By formula: C10Mn2O10 (cr) + I2 (cr) = 2C5IMnO5 (cr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -185.0 ± 8.7 | kJ/mol | PC | Harel and Adamson, 1986 | The reaction enthalpy was calculated from the enthalpy of the same reaction in cyclohexane, -187.9 ± 8.4 kJ/mol Harel and Adamson, 1986, and from the solution enthalpies of Mn2(CO)10(cr), 36.0 ± 2.1 kJ/mol, I2(cr), 20.5 ± 0.4 kJ/mol, and Mn(CO)5(I)(cr), 26.8 ± 0.5 kJ/mol Harel and Adamson, 1986. The latter value refers to the solution in benzene and is therefore taken as an approximation; MS |
By formula: C10O10Re2 (cr) + I2 (cr) = 2C5IO5Re (cr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -172. ± 18. | kJ/mol | PC | Harel and Adamson, 1986 | The reaction enthalpy was calculated from the enthalpy of the same reaction in cyclohexane, -157. ± 16. kJ/mol, and from the solution enthalpies of Re2(CO)10(cr), 34.3 ± 2.1 kJ/mol, I2(cr), 20.5 ± 0.4 kJ/mol, and Re(CO)5(I)(cr), 34.7 ± 4.2 kJ/mol Harel and Adamson, 1986; MS |
By formula: HI + C3H5I = C3H6 + I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -33.3 ± 1.4 | kJ/mol | Eqk | Rodgers, Golden, et al., 1966 | gas phase; ALS |
ΔrH° | -39.7 ± 4.2 | kJ/mol | Eqk | Rodgers, Golden, et al., 1966 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -34.9 ± 0.96 kJ/mol; At 527 K; ALS |
By formula: HI + CH3I = CH4 + I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -52.55 ± 0.54 | kJ/mol | Eqk | Golden, Walsh, et al., 1965 | gas phase; ALS |
ΔrH° | -53.0 ± 0.2 | kJ/mol | Eqk | Goy and Pritchard, 1965 | gas phase; ALS |
ΔrH° | -46.2 ± 5.6 | kJ/mol | Cm | Nichol and Ubbelohde, 1952 | gas phase; ALS |
C12H16Nb (cr) + 2 (cr) = C10H10I2Nb (cr) + 2 (l)
By formula: C12H16Nb (cr) + 2I2 (cr) = C10H10I2Nb (cr) + 2CH3I (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -242.3 ± 2.4 | kJ/mol | RSC | Diogo, Simoni, et al., 1993 | The difference between the enthalpies of formation of Nb(Cp)2(I)2 and Nb(Cp)2(Me)2 is calculated as -215.1 ± 2.6 kJ/mol; MS |
C20H26CoN5O4 (solution) + (solution) = C13H19CoIN5O4 (solution) + (solution)
By formula: C20H26CoN5O4 (solution) + I2 (solution) = C13H19CoIN5O4 (solution) + C7H7I (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -63.2 ± 3.8 | kJ/mol | RSC | Toscano, Seligson, et al., 1989 | solvent: Bromoform; The enthalpy of solution of Co(py)(dmg)2(Bz)(cr) was measured as 11.3 kJ/mol Toscano, Seligson, et al., 1989; MS |
C14H22CoN5O4 (solution) + (solution) = C13H19CoIN5O4 (solution) + (solution)
By formula: C14H22CoN5O4 (solution) + I2 (solution) = C13H19CoIN5O4 (solution) + CH3I (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -92.9 ± 2.5 | kJ/mol | RSC | Toscano, Seligson, et al., 1989 | solvent: Bromoform; The enthalpy of solution of Co(py)(dmg)2(Me)(cr) was measured as 10.9 kJ/mol Toscano, Seligson, et al., 1989; MS |
By formula: C5HMnO5 (l) + I2 (cr) = HI (g) + C5IMnO5 (cr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -108. ± 8. | kJ/mol | RSC | Connor, Zafarani-Moattar, et al., 1982 | The reaction enthalpy relies on -25. ± 5. kJ/mol for the enthalpy of solution of HI(g) in benzene Connor, Zafarani-Moattar, et al., 1982.; MS |
By formula: C2H4 + I2 = C2H4I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -48.1 ± 0.8 | kJ/mol | Eqk | Abrams and Davis, 1954 | gas phase; ALS |
ΔrH° | -56. ± 2. | kJ/mol | Eqk | Cutherbertson and Kistiakowsky, 1935 | gas phase; Heat of dissociation; ALS |
By formula: I2 + CClF3 = CF3I + ClI
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 72.3 ± 1.1 | kJ/mol | Eqk | Lord, Goy, et al., 1967 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 71.55 ± 0.71 kJ/mol; ALS |
By formula: HI + C6H11I = C6H12 + I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -32.6 ± 8.4 | kJ/mol | Cm | Brennan and Ubbelohde, 1956 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -28. ± 4.2 kJ/mol; ALS |
By formula: C2H3F3 + I2 = HI + C2H2F3I
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -64. ± 2. | kJ/mol | Eqk | Wu and Rodgers, 1974 | gas phase; Heat of formation Unpublished results by B.J. Zwolinski; ALS |
By formula: C2H2BrF3 + I2 = C2H2F3I + BrI
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 28. ± 2. | kJ/mol | Eqk | Buckley, Ford, et al., 1980 | gas phase; GLC;hf298_gas[kcal/mol]=-166.8±1.1; Kolesov and Papina, 1983; ALS |
By formula: C2H6Hg (l) + 2I2 (cr) = 2CH3I (l) + HgI2 (cr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -184.5 ± 0.8 | kJ/mol | RSC | Hartley, Pritchard, et al., 1950 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970, 2.; MS |
(solution) + (solution) = 2 (solution)
By formula: C10O10Re2 (solution) + I2 (solution) = 2C5IO5Re (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -157. ± 16. | kJ/mol | PC | Harel and Adamson, 1986 | solvent: Cyclohexane; Please also see Adamson, Vogler, et al., 1978.; MS |
(l) + 3 (cr) = GaI3 (cr) + 3 (l)
By formula: C3H9Ga (l) + 3I2 (cr) = GaI3 (cr) + 3CH3I (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -200.0 ± 8.4 | kJ/mol | RSC | Fowell and Mortimer, 1958 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970, 2.; MS |
(l) + 2 (cr) = CH3GaI2 (cr) + 2 (l)
By formula: C3H9Ga (l) + 2I2 (cr) = CH3GaI2 (cr) + 2CH3I (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -158.6 ± 4.2 | kJ/mol | RSC | Fowell and Mortimer, 1958 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970, 2.; MS |
(l) + (cr) = 2C3H9ISn (l)
By formula: C6H18Sn2 (l) + I2 (cr) = 2C3H9ISn (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -184.1 ± 2.9 | kJ/mol | RSC | Pedley, Skinner, et al., 1957 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970, 2.; MS |
By formula: C4H8I2 = C4H8 + I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 50.2 ± 6.3 | kJ/mol | Cm | Cline and Kistiakowsky, 1937 | gas phase; Heat of formation derived by Cox and Pilcher, 1970; ALS |
(cr) + (solution) = (solution) + C8H5IO3W (solution)
By formula: C8H6O3W (cr) + I2 (solution) = HI (solution) + C8H5IO3W (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -67.4 ± 3.8 | kJ/mol | RSC | Landrum and Hoff, 1985 | solvent: Dichloromethane; MS |
C15H12MoO3 (solution) + (solution) = C8H5IMoO3 (solution) + (solution)
By formula: C15H12MoO3 (solution) + I2 (solution) = C8H5IMoO3 (solution) + C7H7I (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -120.5 ± 4.2 | kJ/mol | RSC | Nolan, de la Vega, et al., 1988 | solvent: Tetrahydrofuran; MS |
C8H6MoO3 (cr) + (solution) = C8H5IMoO3 (solution) + (solution)
By formula: C8H6MoO3 (cr) + I2 (solution) = C8H5IMoO3 (solution) + HI (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -75.3 ± 2.5 | kJ/mol | RSC | Landrum and Hoff, 1985 | solvent: Dichloromethane; MS |
C10MnO10Re (solution) + (solution) = (solution) + (solution)
By formula: C10MnO10Re (solution) + I2 (solution) = C5IO5Re (solution) + C5IMnO5 (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -233. ± 13. | kJ/mol | PC | Harel and Adamson, 1986 | solvent: Cyclohexane; MS |
C8H5MoNaO3 (solution) + (cr) = C8H5IMoO3 (solution) + (cr)
By formula: C8H5MoNaO3 (solution) + I2 (cr) = C8H5IMoO3 (solution) + INa (cr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -133.1 ± 5.4 | kJ/mol | RSC | Nolan, López de la Vega, et al., 1986 | solvent: Tetrahydrofuran; MS |
By formula: C2F4I2 = C2F4 + I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 69. ± 2. | kJ/mol | Eqk | Wu, Pickard, et al., 1975 | gas phase; Spectrophotometery at 298.15°K; ALS |
By formula: 2C3H8S + I2 = 2HI + C6H14S2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -124.9 | kJ/mol | Cm | Sunner, 1955 | liquid phase; solvent: Ethanol/water(90/10); ALS |
By formula: 2C5H12S + I2 = 2HI + C10H22S2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -124.9 | kJ/mol | Cm | Sunner, 1955 | liquid phase; solvent: Ethanol/water(90/10); ALS |
By formula: C4H10S2 + I2 = 2HI + C4H8S2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -123.2 | kJ/mol | Cm | Sunner, 1955 | liquid phase; solvent: Ethanol/water(90/10); ALS |
By formula: C8H16O2S2 + I2 = 2HI + C8H14O2S2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -109.6 | kJ/mol | Cm | Sunner, 1955 | liquid phase; solvent: Ethanol/water(90/10); ALS |
C22H36Zr (solution) + 2 (solution) = C20H30I2Zr (solution) + 2 (solution)
By formula: C22H36Zr (solution) + 2I2 (solution) = C20H30I2Zr (solution) + 2CH3I (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -292.9 ± 2.5 | kJ/mol | RSC | Schock and Marks, 1988 | solvent: Toluene; MS |
By formula: C3H8S2 + I2 = 2HI + C3H6S2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -107.7 | kJ/mol | Cm | Sunner, 1955 | liquid phase; solvent: Ethanol/water(90/10); ALS |
C12H16Zr (solution) + 2 (solution) = C10H10I2Zr (solution) + 2 (solution)
By formula: C12H16Zr (solution) + 2I2 (solution) = C10H10I2Zr (solution) + 2CH3I (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -291.2 ± 2.5 | kJ/mol | RSC | Schock and Marks, 1988 | solvent: Toluene; MS |
C22H30O2Zr (solution) + (solution) = C20H30I2Zr (solution) + 2 (solution)
By formula: C22H30O2Zr (solution) + I2 (solution) = C20H30I2Zr (solution) + 2CO (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -191.6 ± 1.7 | kJ/mol | RSC | Schock and Marks, 1988 | solvent: Toluene; MS |
C22H36Hf (solution) + 2 (solution) = C20H30HfI2 (solution) + 2 (solution)
By formula: C22H36Hf (solution) + 2I2 (solution) = C20H30HfI2 (solution) + 2CH3I (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -265.3 ± 3.3 | kJ/mol | RSC | Schock and Marks, 1988 | solvent: Toluene; MS |
C37H30ClIrO3P2S (solution) + (solution) = C37H30ClI2IrOP2 (solution) + (solution)
By formula: C37H30ClIrO3P2S (solution) + I2 (solution) = C37H30ClI2IrOP2 (solution) + O2S (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -102.9 ± 0.4 | kJ/mol | RSC | Drago, Nozari, et al., 1979 | solvent: Benzene; MS |
By formula: HI + C7H7I = C7H8 + I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -33. ± 4.6 | kJ/mol | Cm | Graham, Nichol, et al., 1955 | liquid phase; solvent: p-Xylene; ALS |
By formula: H2 + 2CH3I = 2CH4 + I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -126. ± 3. | kJ/mol | Chyd | Carson, Carter, et al., 1961 | liquid phase; solvent: Ether; ALS |
C20H32Zr (solution) + (solution) = C20H30I2Zr (solution) + (g)
By formula: C20H32Zr (solution) + I2 (solution) = C20H30I2Zr (solution) + H2 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -309.2 ± 3.3 | kJ/mol | RSC | Schock and Marks, 1988 | solvent: Toluene; MS |
C20H32Hf (solution) + (solution) = C20H30HfI2 (solution) + (g)
By formula: C20H32Hf (solution) + I2 (solution) = C20H30HfI2 (solution) + H2 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -296.6 ± 2.9 | kJ/mol | RSC | Schock and Marks, 1988 | solvent: Toluene; MS |
C16H10O6W2 (cr) + (solution) = 2C8H5IO3W (solution)
By formula: C16H10O6W2 (cr) + I2 (solution) = 2C8H5IO3W (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -146.4 ± 3.8 | kJ/mol | RSC | Landrum and Hoff, 1985 | solvent: Dichloromethane; MS |
C16H10Mo2O6 (cr) + (solution) = 2C8H5IMoO3 (solution)
By formula: C16H10Mo2O6 (cr) + I2 (solution) = 2C8H5IMoO3 (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -133.1 ± 4.2 | kJ/mol | RSC | Landrum and Hoff, 1985 | solvent: Dichloromethane; MS |
(solution) + (solution) = 2 (solution)
By formula: C10Mn2O10 (solution) + I2 (solution) = 2C5IMnO5 (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -187.9 ± 8.4 | kJ/mol | PC | Harel and Adamson, 1986 | solvent: Cyclohexane; MS |
By formula: I- + I2 = (I- • I2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 100. | kJ/mol | N/A | Downs and Adams, 1973 | gas phase; from ΔrH(f); M |
By formula: H2 + 2C2H5I = 2C2H6 + I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -88.7 ± 3.3 | kJ/mol | Chyd | Ashcroft, Carson, et al., 1965 | liquid phase; ALS |
2 + = C6H14Hg + 2
By formula: 2C3H7I + HgI2 = C6H14Hg + 2I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 242.3 ± 1.9 | kJ/mol | Cm | Mortimer, Pritchard, et al., 1952 | liquid phase; ALS |
2 + = C6H14Hg + 2
By formula: 2C3H7I + HgI2 = C6H14Hg + 2I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 215.7 ± 2.4 | kJ/mol | Cm | Mortimer, Pritchard, et al., 1952 | liquid phase; ALS |
By formula: HI + CH3IS = CH4S + I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -12.0 ± 2.3 | kJ/mol | Eqk | Shum and Benson, 1983 | gas phase; ALS |
By formula: C3H6O + I2 = HI + C3H5IO
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 50.6 ± 5.0 | kJ/mol | Eqk | Solly, Golden, et al., 1970 | gas phase; ALS |
By formula: I2 + CBrF3 = CF3I + BrI
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 40.0 ± 0.1 | kJ/mol | Eqk | Lord, Goy, et al., 1967 | gas phase; ALS |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A.,
CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Taylor, Asmis, et al., 1999
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Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References
- Symbols used in this document:
S°liquid,1 bar Entropy of liquid at standard conditions (1 bar) S°solid Entropy of solid at standard conditions S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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