beryllium fluoride

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-796.01kJ/molReviewChase, 1998Data last reviewed in June, 1970
Quantity Value Units Method Reference Comment
gas,1 bar227.56J/mol*KReviewChase, 1998Data last reviewed in June, 1970

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 2000. to 6000.
A 61.51108
B 0.469968
C -0.094569
D 0.006520
E -3.228179
F -822.7292
G 289.9374
H -796.0060
ReferenceChase, 1998
Comment Data last reviewed in June, 1970

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid-1022.05kJ/molReviewChase, 1998Data last reviewed in June, 1970
Quantity Value Units Method Reference Comment
liquid,1 bar59.88J/mol*KReviewChase, 1998Data last reviewed in June, 1970
Quantity Value Units Method Reference Comment
Δfsolid-1026.75kJ/molReviewChase, 1998Data last reviewed in June, 1970
Quantity Value Units Method Reference Comment
solid53.47J/mol*KReviewChase, 1998Data last reviewed in June, 1970

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 825. to 2000.
A 50.61468
B 42.61739
C -8.151102
D 1.731340
E -1.135873
F -1042.787
G 102.3808
H -1022.051
ReferenceChase, 1998
Comment Data last reviewed in June, 1970

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 500.500. to 825.
A 114.253347.38715
B -256.786733.40878
C 389.96340.060563
D 0.000000-0.020002
E -1.825756-0.001405
F -1058.920-1041.699
G 240.6896101.9641
H -1026.754-1026.754
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in June, 1970 Data last reviewed in June, 1970

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Fluorine anion + BeF2 = (Fluorine anion • BeF2)

By formula: F- + BeF2 = (F- • BeF2)

Quantity Value Units Method Reference Comment
Δr407. ± 9.6kJ/molTDEqNikitin, Sorokin, et al., 1980gas phase; Fluoride Affinity: 19.9±1.7 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention

AlF4- + BeF2 = (AlF4- • BeF2)

By formula: AlF4- + BeF2 = (AlF4- • BeF2)

Quantity Value Units Method Reference Comment
Δr182. ± 10.kJ/molTDAsNikitin, Sorokin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

Be2F5- + BeF2 = (Be2F5- • BeF2)

By formula: Be2F5- + BeF2 = (Be2F5- • BeF2)

Quantity Value Units Method Reference Comment
Δr175. ± 10.kJ/molN/ANikitin, Sorokin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Nikitin, Sorokin, et al., 1980
Nikitin, M.I.; Sorokin, I.D.; Skokan, E.V.; Sidorov, L.N., Negative Ions in the Saturated Vapors of the Potassium Fluoride - Hafnium Tetrafluoride and Potassium Fluoride - Beryllium Difluoride Systems, Russ. J. Phys. Chem., 1980, 54, page]. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References