α-D-Glucose
- Formula: C6H12O6
- Molecular weight: 180.1559
- IUPAC Standard InChIKey: WQZGKKKJIJFFOK-MDMQIMBFSA-N
- CAS Registry Number: 492-62-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Stereoisomers:
- Other names: α-D-Glucopyranose
- Information on this page:
- Other data available:
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Condensed phase thermochemistry data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔcH°solid | -2805.0 ± 1.3 | kJ/mol | Ccb | Ponomarev and Migarskaya, 1960 | Reanalyzed by Cox and Pilcher, 1970, Original value = -2806.2 ± 1.3 kJ/mol; Corresponding ΔfHºsolid = -1271.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°solid,1 bar | 209.19 | J/mol*K | N/A | Boerio-Goates, 1991 | DH |
Constant pressure heat capacity of solid
Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
219.19 | 298.15 | Boerio-Goates, 1991 | T = 7 to 347 K.; DH |
221. | 300. | Finegold, Franks, et al., 1989 | T(glass) = 312 K.; DH |
219.79 | 298.15 | Lian, Chen, et al., 1982 | DH |
224. | 303. | Kawaizumi, Kushida, et al., 1981 | T = 300 to 315 K.; DH |
218.8 | 298.15 | Douglas, Ball, et al., 1951 | T = 273 to 368 K.; DH |
218.0 | 298. | Nelson and Newton, 1941 | T = 0 to 60°C. Equation only.; DH |
220.9 | 298. | Parks and Thomas, 1934 | T = 273 to 318 K. Curve given also for undercooled liquid.; DH |
211.3 | 298.1 | Parks, Kelley, et al., 1929 | Extrapolation below 90 K, 55.23 J/mol*K.; DH |
229.3 | 300. | Simon, 1922 | T = 20 to 287 K.; DH |
Reaction thermochemistry data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C6H11O6- + =
By formula: C6H11O6- + H+ = C6H12O6
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1389. ± 17. | kJ/mol | IMRB | Cai and Cole, 2002 | gas phase |
References
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ponomarev and Migarskaya, 1960
Ponomarev, V.V.; Migarskaya, L.B.,
Heats of combustion of some amino-acids,
Russ. J. Phys. Chem. (Engl. Transl.), 1960, 34, 1182-1183. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Boerio-Goates, 1991
Boerio-Goates, J.,
Heat-capacity measurements and thermodynamic functions of crystalline a-D-glucose at temperatures from 10K to 340K,
J. Chem. Thermodynam., 1991, 23, 403-409. [all data]
Finegold, Franks, et al., 1989
Finegold, L.; Franks, F.; Hatley, R.H.M.,
Glass/rubber transitions and heat capacities of binary sugar blends, J. Chem. Soc.,
Faraday Trans., 1989, 1 85(9), 2945-2951. [all data]
Lian, Chen, et al., 1982
Lian, Y.N.; Chen, A.T.; Suurkuusk, J.; Wadsoe, I.,
Polyol-water interactions as reflected by aqueous heat capacity values,
Acta Chem. Scand., 1982, A36(9), 735-739. [all data]
Kawaizumi, Kushida, et al., 1981
Kawaizumi, F.; Kushida, S.; Miyahara, Y.,
Determination of the specific heat capacities of aqueous solutions of pentose,
Bull. Chem. Soc. Japan, 1981, 54(8), 2282-2285. [all data]
Douglas, Ball, et al., 1951
Douglas, T.B.; Ball, A.F.; Torgeson, J.L.,
Heat capacity of crystalline dextrose between 25 and 95°C,
J. Am. Chem. Soc., 1951, 73, 1360-1361. [all data]
Nelson and Newton, 1941
Nelson, E.W.; Newton, R.F.,
The heat capacity of glucose glass,
J. Am. Chem. Soc., 1941, 63, 2178-2182. [all data]
Parks and Thomas, 1934
Parks, G.S.; Thomas, S.B.,
The heat capacities of crystalline, glassy and undercooled liquid glucose,
J. Am. Chem. Soc., 1934, 56, 1423. [all data]
Parks, Kelley, et al., 1929
Parks, G.S.; Kelley, K.K.; Huffman, H.M.,
Thermal data on organic compounds. V. A revision of the entropies and free energies of nineteen organic compounds,
J. Am. Chem. Soc., 1929, 51, 1969-1973. [all data]
Simon, 1922
Simon, F.,
Untersuchungen über die spezifische Wärme bei tiefen Temperaturen,
Ann. Physik. [4], 1922, 68, 241-280. [all data]
Cai and Cole, 2002
Cai, Y.; Cole, R.B.,
Stabilization of anionic adducts in negative ion electrospray mass spectrometry,
Anal. Chem., 2002, 74, 5, 985-991, https://doi.org/10.1021/ac0108818
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔrG° Free energy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.