Cyclopropane, 1,1-dimethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas-8.2 ± 1.2kJ/molCcbGood, Moore, et al., 1974ALS

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
34.5350.Thermodynamics Research Center, 1997p=1 bar. Selected values are lower than other statistically calculated values [ Kabo G.Y., 1973] up to 2.2 and 1.1 J/mol*K for S(T) and Cp(T), respectively.; GT
46.12100.
60.44150.
74.83200.
98.04273.15
106.37298.15
106.99300.
139.28400.
167.17500.
190.30600.
209.64700.
226.09800.
240.23900.
252.451000.
263.041100.
272.231200.
280.211300.
287.141400.
293.191500.
305.21750.
313.92000.
320.42250.
325.32500.
329.02750.
332.03000.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-33.3 ± 0.79kJ/molCcbGood, Moore, et al., 1974 
Quantity Value Units Method Reference Comment
Δcliquid-3363.4 ± 0.71kJ/molCcbGood, Moore, et al., 1974Corresponding Δfliquid = -33.3 kJ/mol (simple calculation by NIST; no Washburn corrections)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Good, Moore, et al., 1974
Good, W.D.; Moore, R.T.; Osborn, A.G.; Douslin, D.R., The enthalpies of formation of ethylcyclobutane, methylenecyclobutane, and 1,1-dimethylcyclopropane, J. Chem. Thermodyn., 1974, 6, 303-310. [all data]

Thermodynamics Research Center, 1997
Thermodynamics Research Center, Selected Values of Properties of Chemical Compounds., Thermodynamics Research Center, Texas A&M University, College Station, Texas, 1997. [all data]

Kabo G.Y., 1973
Kabo G.Y., Thermodynamic properties of some hydrocarbons containing three-membered rings, Vestn. Beloruss. Univ., Ser. 2, 1973, 3-6. [all data]


Notes

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