Perfluorobicyclo-[4.4.0]-dec-1,6-ene
- Formula: C10F16
- Molecular weight: 424.0815
- IUPAC Standard InChIKey: LSBZKGFVMTVTCT-UHFFFAOYSA-N
- CAS Registry Number: 54939-04-7
- Chemical structure:
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -765.7 ± 1.1 | kcal/mol | Ccr | Zhogina, Papina, et al., 1988 | Uc=-3560.0±4.6 kJ/mol |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -776.5 ± 1.1 | kcal/mol | Ccr | Zhogina, Papina, et al., 1988 | Uc=-3560.0±4.6 kJ/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -848.5 ± 1.1 | kcal/mol | Ccr | Zhogina, Papina, et al., 1988 | Uc=-3560.0±4.6 kJ/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 117.4 | cal/mol*K | N/A | Zhogin, Kosarukina, et al., 1981 | DH |
Constant pressure heat capacity of liquid
Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
102.4 | 298.15 | Zhogin, Kosarukina, et al., 1981 | T = 6 to 300 K. 0.41 mole % impurity of sample; DH |
Phase change data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Ttriple | 264.09 | K | N/A | Zhogin, Kosarukina, et al., 1981 | Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 10.8 ± 0.02 | kcal/mol | C | Varushchenko, Druzhinina, et al., 1996 | AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
2.502 | 263. | Domalski and Hearing, 1996 | AC |
Enthalpy of phase transition
ΔHtrs (kcal/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
0.190 | 200.0 | crystaline, III | crystaline, II | Zhogin, Kosarukina, et al., 1981 | DH |
0.2660 | 233.4 | crystaline, II | crystaline, I | Zhogin, Kosarukina, et al., 1981 | DH |
2.5031 | 264.09 | crystaline, I | liquid | Zhogin, Kosarukina, et al., 1981 | DH |
Entropy of phase transition
ΔStrs (cal/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
0.901 | 200.0 | crystaline, III | crystaline, II | Zhogin, Kosarukina, et al., 1981 | DH |
1.14 | 233.4 | crystaline, II | crystaline, I | Zhogin, Kosarukina, et al., 1981 | DH |
9.479 | 264.09 | crystaline, I | liquid | Zhogin, Kosarukina, et al., 1981 | DH |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zhogina, Papina, et al., 1988
Zhogina, E.V.; Papina, T.S.; Kolesov, V.P.; Prokudin, I.P.; Mel'nichenko, B.A.,
Standard enthalpy of formation of perfluorobicyclo-[4,4,0]-dec-1,6-ene,
Russ. J. Phys. Chem. (Engl. Transl.), 1988, 62, 569-570. [all data]
Zhogin, Kosarukina, et al., 1981
Zhogin, D.Yu.; Kosarukina, E.A.; Kolesov, V.P.; Prokudin, I.P.; Mel'nichenko, B.A.,
The heat capacity in the temperature range 6-300 K, phase transformations, and thermodynamic functions of perfluorobicyclo(4,4,0)dec-1,6-ene,
Zhur. Fiz. Khim., 1981, 55, 98-103. [all data]
Varushchenko, Druzhinina, et al., 1996
Varushchenko, Raisa M.; Druzhinina, Anna I.; Pashchenko, Larisa L.,
Thermodynamics of vaporization of some cyclic perfluorocarbons,
Fluid Phase Equilibria, 1996, 126, 1, 93-104, https://doi.org/10.1016/S0378-3812(96)03111-1
. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid S°liquid Entropy of liquid at standard conditions Ttriple Triple point temperature ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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