1,3,5-Benzenetriamine, 2,4,6-trinitro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-17.85 ± 0.71kcal/molCcbBaroody and Peters, 1987 
Δfsolid-33.4 ± 1.2kcal/molCcbRouse, 1976 
Δfsolid-36.9kcal/molCcbFedoroff and Shefield, 1975 
Quantity Value Units Method Reference Comment
Δcsolid-735.9 ± 0.5kcal/molCcbRouse, 1976 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
40.2423.N/ARai, Bhatt, et al., 2008See also Garza, 1979.
40.20417.LEStephenson and Malanowski, 1987Based on data from 402. to 451. K. See also Rosen and Dickinson, 1969.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Baroody and Peters, 1987
Baroody, E.E.; Peters, S.T., Heats of formation of propellant compounds (U), Rpt. IHSP-87-252 by Naval Ordnance Station, Indian Head, MD, 1987, 1-7. [all data]

Rouse, 1976
Rouse, P.E., Jr., Enthalpies of formation and calculated detonation properties of some thermally stable explosives, J. Chem. Eng. Data, 1976, 21, 16-20. [all data]

Fedoroff and Shefield, 1975
Fedoroff, B.T.; Shefield, O.E., Table 1. Standard heats of formation and heats of detonation of common explosives in Encyclopedia of Explosives and Related Items, Part 2700 Volume 7, Picatinny Arsenal, Dover, NJ., 1975, 41-42. [all data]

Rai, Bhatt, et al., 2008
Rai, Neeraj; Bhatt, Divesh; Siepmann, J. Ilja; Fried, Laurence E., Monte Carlo simulations of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB): Pressure and temperature effects for the solid phase and vapor-liquid phase equilibria, J. Chem. Phys., 2008, 129, 19, 194510, https://doi.org/10.1063/1.3006054 . [all data]

Garza, 1979
Garza, R.G., A thermogravimetric study of TATB and two TATB-based explosives, Rpt. UCRL-82723, Lawrence Livermore National Laboratory, Livermore, CA, 1979, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Rosen and Dickinson, 1969
Rosen, Jerome M.; Dickinson, Charles, Vapor pressures and heats of sublimation of some high-melting organic explosives, J. Chem. Eng. Data, 1969, 14, 1, 120-124, https://doi.org/10.1021/je60040a044 . [all data]


Notes

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