Propane, 1,1,1,2,3,3,3-heptafluoro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil255.0KN/AHwang, DesMarteau, et al., 1992Uncertainty assigned by TRC = 0.5 K; TRC
Tboil293.KN/APCR Inc., 1990BS
Quantity Value Units Method Reference Comment
Tfus142.KN/ASalvi-Narkhede, Wang, et al., 1992Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Tc374.83KN/ASalvi-Narkhede, Wang, et al., 1992Uncertainty assigned by TRC = 0.2 K; method of measurement not clearly described; TRC
Quantity Value Units Method Reference Comment
Pc29.116barN/ASalvi-Narkhede, Wang, et al., 1992Uncertainty assigned by TRC = 0.03 bar; TRC
Quantity Value Units Method Reference Comment
Vc0.275l/molN/ASalvi-Narkhede, Wang, et al., 1992Uncertainty assigned by TRC = 0.005 l/mol; TRC
Quantity Value Units Method Reference Comment
Δvap18.9kJ/molN/AEckl, Huang, et al., 2007AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
22.7293.Bobbo, Artico, et al., 2002Based on data from 278. to 308. K.; AC
22.6308.Valtz, Coquelet, et al., 2002Based on data from 293. to 353. K.; AC
22.3250.Salvi-Narkhede, Wang, et al., 1992, 2Based on data from 237. to 370. K.; AC
14.5300.Salvi-Narkhede, Wang, et al., 1992, 2Based on data from 237. to 370. K.; AC
12.5325.Salvi-Narkhede, Wang, et al., 1992, 2Based on data from 237. to 370. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hwang, DesMarteau, et al., 1992
Hwang, S.H.; DesMarteau, D.D.; Beyerlein, A.L.; Smith, N.D.; Joyner, P., The heat capacity of fluorinated propane and butane derivatives by differential scanning calorimetry, J. Therm. Anal., 1992, 38, 2515-28. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Salvi-Narkhede, Wang, et al., 1992
Salvi-Narkhede, M.; Wang, B.H.; Adcock, J.I.; Van Hook, W.A., Vapor pressures, liquid molar volumes, vapor non-ideality, and critical properties of some partially fluorinated ethers (CF3OCF2CF2H, CF3OCF2H, and CF3OCH3), some perfluoroethers (CF3OCF2OCF3, c-CF2O, J. Chem. Thermodyn., 1992, 24, 1065-75. [all data]

Eckl, Huang, et al., 2007
Eckl, Bernhard; Huang, Yow-Lin; Vrabec, Jadran; Hans, Hasse, Vapor pressure of R227ea + ethanol at 343.13 K by molecular simulation, Fluid Phase Equilibria, 2007, 260, 2, 177-182, https://doi.org/10.1016/j.fluid.2007.05.011 . [all data]

Bobbo, Artico, et al., 2002
Bobbo, Sergio; Artico, Gianpiero; Fedele, Laura; Scattolini, Mauro; Camporese, Roberto, Vapor-Liquid Equilibrium Measurements and Correlation of the Binary Refrigerant Mixture Propane (HC-290) + 1,1,1,2,3,3,3-Heptafluoropropane (HFC-227ea) at 278.15, 293.15, and 308.15 K, J. Chem. Eng. Data, 2002, 47, 4, 839-842, https://doi.org/10.1021/je010269d . [all data]

Valtz, Coquelet, et al., 2002
Valtz, A.; Coquelet, C.; Baba-Ahmed, A.; Richon, D., Vapor--liquid equilibrium data for the propane+1,1,1,2,3,3,3-heptafluoropropane (R227ea) system at temperatures from 293.16 to 353.18 K and pressures up to 3.4 MPa, Fluid Phase Equilibria, 2002, 202, 1, 29-47, https://doi.org/10.1016/S0378-3812(02)00056-0 . [all data]

Salvi-Narkhede, Wang, et al., 1992, 2
Salvi-Narkhede, M.; Wang, Bao-Huai; Adcock, James L.; Alexander Van Hook, W., Vapor pressures, liquid molar volumes, vapor non-ideality, and critical properties of some partially fluorinated ethers (CF3OCF2CF2H, CF3OCF2H, and CF3OCH3), some perfluoroethers (CF3OCF2OCF3, c-CF2OCF2OCF2, and c-CF2CF2CF2O), and of CHF2Br and CF3CFHCF3, The Journal of Chemical Thermodynamics, 1992, 24, 10, 1065-1075, https://doi.org/10.1016/S0021-9614(05)80017-5 . [all data]


Notes

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