Octaethylcyclotetrasiloxane
- Formula: C16H40O4Si4
- Molecular weight: 408.8284
- IUPAC Standard InChIKey: XOCOMEGNVMCRMP-UHFFFAOYSA-N
- CAS Registry Number: 1451-99-6
- Chemical structure:
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Ttriple | 213.35 | K | N/A | Dzhafarov and Kuliev, 1987 | Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
69.2 | 435. | A | Stephenson and Malanowski, 1987 | Based on data from 420. to 574. K.; AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
13.71 | 213.4 | Domalski and Hearing, 1990 | AC |
Temperature of phase transition
Ttrs (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|
134. | crystaline, III | crystaline, II | Dzhafarov and Kuliev, 1987, 2 | DH |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
12.219 | 208.16 | crystaline, II | crystaline, I | Dzhafarov and Kuliev, 1987, 2 | DH |
13.705 | 213.35 | crystaline, I | liquid | Dzhafarov and Kuliev, 1987, 2 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
58.69 | 208.16 | crystaline, II | crystaline, I | Dzhafarov and Kuliev, 1987, 2 | DH |
64.38 | 213.35 | crystaline, I | liquid | Dzhafarov and Kuliev, 1987, 2 | DH |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dzhafarov and Kuliev, 1987
Dzhafarov, O.I.; Kuliev, A.M.,
Heat capacity, phase transitions, and thermodynamic parameters of octaethylcyclotetrasiloxane,
Zh. Fiz. Khim., 1987, 61, 602-5. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Domalski and Hearing, 1990
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase Volume II,
J. Phys. Chem. Ref. Data, 1990, 19, 4, 881, https://doi.org/10.1063/1.555876
. [all data]
Dzhafarov and Kuliev, 1987, 2
Dzhafarov, O.I.; Kuliev, A.M.,
Heat capacity, phase transitions, and thermodynamic parameters of octaethylcyclotetrasiloxane,
Zhur Fiz. Khim., 1987, 61(3), 602-605. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Ttriple Triple point temperature Ttrs Temperature of phase transition ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔfusH Enthalpy of fusion ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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