CO3 radical anion
- Formula: CO3-
- Molecular weight: 60.0094
- Information on this page:
- Other data available:
- Options:
Gas phase ion energetics data
Go To: Top, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
EAneutral (eV) | Method | Reference | Comment |
---|---|---|---|
>3.33999 | Ther | Hunton, Hofmann, et al., 1985 | |
>3.07885 | LPES | Novich, Engelking, et al., 1979 | |
3.10 ± 0.20 | CIDT | Tiernan and Wu, 1978 | |
3.25 ± 0.15 | PD | Vestal and Mauclaire, 1977 | |
>2.79954 | IMRE | Dotan, Davidson, et al., 1977 | O3- + CO2 <=> CO3- + O2 |
2.69 ± 0.14 | PD | Hong, Woo, et al., 1977 | |
1.80 ± 0.20 | PD | Burt, 1972 | actually photodissociation, Snodgrass, Roehl, et al., 1990 |
Ion clustering data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
CO3- + = C2O5-
By formula: CO3- + CO2 = C2O5-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.90 ± 0.20 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase |
ΔrH° | 7.10 ± 0.10 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1.0 ± 2.0 | kcal/mol | TDAs | Hiraoka and Yamabe, 1992 | gas phase |
ΔrG° | 0.60 ± 0.20 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase |
CO3- + = C3H4O5-
By formula: CO3- + C2H4O2 = C3H4O5-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 11.30 ± 0.20 | kcal/mol | IMRE | Viidanoja, Reiner, et al., 1998 | gas phase |
CO3- + = CH2O4-
By formula: CO3- + H2O = CH2O4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.10 ± 0.20 | kcal/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase |
ΔrH° | 11.5 ± 1.0 | kcal/mol | IMRE | Fehsenfeld and Ferguson, 1974 | gas phase |
ΔrH° | <38.50 | kcal/mol | PDis | Smith, Lee, et al., 1978 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 6.60 ± 0.40 | kcal/mol | TDAs | Keesee, Lee, et al., 1979 | gas phase |
ΔrG° | 6.70 ± 0.40 | kcal/mol | IMRE | Fehsenfeld and Ferguson, 1974 | gas phase |
References
Go To: Top, Gas phase ion energetics data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunton, Hofmann, et al., 1985
Hunton, D.E.; Hofmann, M.; Lindeman, T.G.; Castleman, A.W.,
Photodissociation Dynamics of CO3-,
J. Chem. Phys., 1985, 82, 1, 134, https://doi.org/10.1063/1.448786
. [all data]
Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C.,
Laser photoelectron, photodetachment, and photodestruction spectra of O3-,
J. Chem. Phys., 1979, 70, 2652. [all data]
Tiernan and Wu, 1978
Tiernan, T.O.; Wu, R.L.C.,
Thermochemical Data for Molecular Negative Ions from Collisional Dissociation Thresholds,
Adv. Mass Spectrom., 1978, 7A, 136. [all data]
Vestal and Mauclaire, 1977
Vestal, M.L.; Mauclaire, G.H.,
Photodissociaton of negative ions formed in CO2 and CO2/O2 Mixtures,
J. Chem. Phys., 1977, 67, 3758. [all data]
Dotan, Davidson, et al., 1977
Dotan, I.; Davidson, J.A.; Streit, G.E.; Albritton, D.L.; Fehsenfeld, F.C.,
A study of the reaction O3- + CO2 = CO3- + O2 and its implication on the thermochemistry of CO3 and O3 and their negative ions,
J. Chem. Phys., 1977, 67, 2874. [all data]
Hong, Woo, et al., 1977
Hong, S.P.; Woo, S.B.; Helmy, E.M.,
Photodetachment of thermally relaxed CO3-,
Phys. Rev. A:, 1977, 15, 1563. [all data]
Burt, 1972
Burt, J.A.,
Photodetachment cross sections for CO3- and its first hydrate,
J. Chem. Phys., 1972, 57, 4649. [all data]
Snodgrass, Roehl, et al., 1990
Snodgrass, J.T.; Roehl, C.M.; Vankoppen, P.A.M.; Palke, W.E.; Bowers, M.T.,
Photodissociation of CO3(-) - Product Kinetic Energy Measurements As a Probe of Excited State Potential Surfaces and Dissociation Dynamics,
J. Chem. Phys., 1990, 92, 10, 5935, https://doi.org/10.1063/1.458363
. [all data]
Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S.,
Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n,
J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560
. [all data]
Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr.,
Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions,
J. Chem. Phys., 1980, 73, 2195. [all data]
Viidanoja, Reiner, et al., 1998
Viidanoja, J.; Reiner, T.; Arnold, F.,
Laboratory Investigations of Negative Ion-Molecule Reactions of Formic and Acetic Acid.,
Int. J. Mass Spectrom., 1998, 181, 1-3, 31, https://doi.org/10.1016/S1387-3806(98)14151-9
. [all data]
Keesee, Lee, et al., 1979
Keesee, R.G.; Lee, N.; Castleman Jr.,
Properties of Clusters in the Gas Phase. 3. Hydration Complexes of CO3- and HCO3-,
J. Am. Chem. Soc., 1979, 101, 10, 2599, https://doi.org/10.1021/ja00504a015
. [all data]
Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E.,
Laboratory studies of negative ion reactions with atmospheric trace constituents,
J. Chem. Phys., 1974, 61, 3181. [all data]
Smith, Lee, et al., 1978
Smith, G.P.; Lee, L.C.; Cosby, P.C.; Peterson, J.R.; Moseley, J.T.,
Photodissociation and photodetachment of molecular negative ions. V. Atmospheric ions from 7000 to 8400 A),
J. Chem. Phys., 1978, 68, 3818. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Ion clustering data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.