1,4-Dioxane-2,5-dione
- Formula: C4H4O4
- Molecular weight: 116.0722
- IUPAC Standard InChIKey: RKDVKSZUMVYZHH-UHFFFAOYSA-N
- CAS Registry Number: 502-97-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Glycollide; p-Dioxane-2,5-dione; Acetic acid, hydroxy-, bimol. cyclic ester; Glycolide
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -168.3 ± 0.1 | kcal/mol | Ccb | Lebedev, Kulagina, et al., 1988 | see Lebedev, Yevstropov, et al., 1978 and Evstropov, Belov, et al., 1978; ALS |
ΔfH°solid | -167.4 ± 0.14 | kcal/mol | Ccb | Kiparisova, Bykova, et al., 1977 | crystal phase; ALS |
ΔfH°solid | -167.4 ± 0.1 | kcal/mol | Ccb | Lebedev, Evstropov, et al., 1977 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -344.6 ± 0.1 | kcal/mol | Ccb | Lebedev, Kulagina, et al., 1988 | see Lebedev, Yevstropov, et al., 1978 and Evstropov, Belov, et al., 1978; Corresponding ΔfHºsolid = -168.2 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°solid | -345.46 ± 0.14 | kcal/mol | Ccb | Kiparisova, Bykova, et al., 1977 | crystal phase; Corresponding ΔfHºsolid = -167.4 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°solid | -345.5 ± 0.1 | kcal/mol | Ccb | Lebedev, Evstropov, et al., 1977 | Corresponding ΔfHºsolid = -167.4 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°solid,1 bar | 37.579 | cal/mol*K | N/A | Lebedev, Kulagina, et al., 1988 | crystaline, II phase; DH |
S°solid,1 bar | 37.57 | cal/mol*K | N/A | Lebedev, Yevstropov, et al., 1978, 2 | crystaline, II phase; DH |
S°solid,1 bar | 37.57 | cal/mol*K | N/A | Lebedev, Evstropov, et al., 1977, 2 | crystaline, II phase; DH |
S°solid,1 bar | 37.57 | cal/mol*K | N/A | Evstropov, Belov, et al., 1978, 2 | crystaline, II phase; DH |
Constant pressure heat capacity of solid
Cp,solid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
31.855 | 298.15 | Lebedev, Kulagina, et al., 1988 | crystaline, II phase; T = 13.8 to 400 K.; DH |
31.84 | 298.15 | Evstropov, Belov, et al., 1978, 2 | crystaline, II phase; T = 14 to 350 K. Complete data deposited in VINITI, No. 2144-77, 2 June 1977.; DH |
31.86 | 298.15 | Lebedev, Yevstropov, et al., 1978, 2 | crystaline, II phase; T = 13.8 to 550 K.; DH |
31.86 | 298.15 | Lebedev, Evstropov, et al., 1977, 2 | crystaline, II phase; T = 13.8 to 550 K.; DH |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lebedev, Kulagina, et al., 1988
Lebedev, B.V.; Kulagina, T.G.; Smirnova, N.N.,
Thermodynamics of 4-methylcyclo-hexene, glycollide, and 1,1,3,3,5,5-hexaethylcyclotrisiloxane from 13.4 to 400 K,
J. Chem. Thermodyn., 1988, 20, 1383-1396. [all data]
Lebedev, Yevstropov, et al., 1978
Lebedev, B.V.; Yevstropov, A.A.; Kiparisova, Ye.G.; Belov, V.I.,
The thermodynamics of glycollide, polyglycollide and of polymerization of glycollide in the temperature range of 0-550°K,
Polym. Sci. USSR (Engl. Transl.), 1978, 20, 32-42. [all data]
Evstropov, Belov, et al., 1978
Evstropov, A.A.; Belov, V.I.; Lebedev, B.V.; Kiparisova, E.G.; Bykova, T.A.,
Thermodynamic properties of glycolide in the temperature range 0-400 K,
Russ. J. Phys. Chem. (Engl. Transl.), 1978, 52, 136. [all data]
Kiparisova, Bykova, et al., 1977
Kiparisova, E.G.; Bykova, T.A.; Lebedev, B.V.,
Standard enthalpy of formation and combustion of glycolide and polyglycolide,
Vses. Konf. Kalorim. Rasshir. Tezisy Dokl. 7th, 1977, 1, 106-110. [all data]
Lebedev, Evstropov, et al., 1977
Lebedev, B.V.; Evstropov, A.A.; Kiparisova, E.G.; Lyudvig, R.B.; Sanina, G.S.,
Thermodynamics of the polymerization of glycolide,
Dokl. Akad. Nauk SSSR, 1977, 236, 925-928. [all data]
Lebedev, Yevstropov, et al., 1978, 2
Lebedev, B.V.; Yevstropov, A.A.; Kiparisova, Y.G.; Belov, V.I.,
The thermodynamics of glycollide, polyglycollide and of polymerization of glycollide in the temperature range of 0-550°K,
Vysokomol. Soedin., 1978, A20, 29-37. [all data]
Lebedev, Evstropov, et al., 1977, 2
Lebedev, B.V.; Evstropov, A.A.; Milov, V.I.; Sladkov, A.M.; Vasneva, N.A.,
Thermodynamic properties of polyvinylenediphenylsilane in the range 13-334,
Zhur. Fiz. Khim., 1977, 51, 275. [all data]
Evstropov, Belov, et al., 1978, 2
Evstropov, A.A.; Belov, V.I.; Lebedev, B.V.; Kiparisova, Y.G.; Bykova, T.A.,
Thermodynamic properties of glycolide in the 0-400 K range,
Zhur. Fiz. Khim., 1978, 52, 242. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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