Stannane, tetraphenyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid130. ± 90.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δcsolid-3177.2 ± 1.3kcal/molCC-SBAdams, Carson, et al., 1969Please also see Pedley and Rylance, 1977.; MS
Δcsolid-3195.0 ± 3.0kcal/molCC-SBTel'noi and Rabinovich, 1965Please also see Cox and Pilcher, 1970.; MS
Δcsolid-3177.72 ± 0.81kcal/molCC-SBPope and Skinner, 1964Please also see Cox and Pilcher, 1970.; MS
Δcsolid-3242.5 ± 1.7kcal/molCC-SBLautsch, Tröber, et al., 1963Please also see Cox and Pilcher, 1970.; MS
Δcsolid-3307.5 ± 3.0kcal/molCC-SBBirr, 1962MS

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
101.9298.5Smith and Andrews, 1931T = 102 to 346 K. Value is unsmoothed experimental datum.; DH

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner Copyright (C) 1987 by the Coblentz Society
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin DOW CORNING CORP.
Source reference COBLENTZ NO. 5579
Date 1966/05/10
Name(s) tetraphenylstannane
State SOLID (SPLIT MULL)
Instrument PERKIN-ELMER 521 (GRATING)
Instrument parameters FILTERS AT 3150, 2500, 2000, 1150, 700, 410. GRATING CHANGES: 2000, 630
Resolution 2
Melting point 228 C

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Adams, Carson, et al., 1969
Adams, G.P.; Carson, A.S.; Laye, P.G., J. Chem. Thermodyn., 1969, 1, 393. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Tel'noi and Rabinovich, 1965
Tel'noi, V.I.; Rabinovich, I.B., Russ. J. Phys. Chem., 1965, 39, 1239. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Pope and Skinner, 1964
Pope, A.E.; Skinner, H.A., Trans. Faraday Soc., 1964, 60, 1402. [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Birr, 1962
Birr, K.-H., Z. Anorg. Allg. Chem., 1962, 315, 175. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal energy studies. II. Phenyl derivatives of metals, J. Am. Chem. Soc., 1931, 53, 3661-3667. [all data]


Notes

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