Nitrogen cation


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Nitrogen cation + Nitrogen = (Nitrogen cation • Nitrogen)

By formula: N2+ + N2 = (N2+ • N2)

Quantity Value Units Method Reference Comment
Δr24.4 to 24.4kcal/molRNGN/ARange of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr21.0cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase
Δr16.2cal/mol*KPHPMSTeng and Conway, 1973gas phase
Δr19.5cal/mol*KPHPMSPayzant and Kebarle, 1970gas phase
Δr11.cal/mol*KDTVarney, 1968gas phase; Entropy change is questionable
Δr-1.cal/mol*KDTVarney, 1959gas phase; Entropy change is questionable

Nitrogen cation + Argon = (Nitrogen cation • Argon)

By formula: N2+ + Ar = (N2+ • Ar)

Quantity Value Units Method Reference Comment
Δr26.8kcal/molPD/KERDKim and Bowers, 1990gas phase; switching reaction(N2+)N2; Hiraoka and Nakajima, 1988
Δr25.4kcal/molPHPMSTeng and Conway, 1973gas phase; switching reaction(N2+)N2
Quantity Value Units Method Reference Comment
Δr19.5cal/mol*KPD/KERDKim and Bowers, 1990gas phase; switching reaction(N2+)N2; Hiraoka and Nakajima, 1988
Δr13.7cal/mol*KPHPMSTeng and Conway, 1973gas phase; switching reaction(N2+)N2

(Nitrogen cation • 7Argon) + Argon = (Nitrogen cation • 8Argon)

By formula: (N2+ • 7Ar) + Ar = (N2+ • 8Ar)

Quantity Value Units Method Reference Comment
Δr1.53kcal/molPHPMSHiraoka, Mori, et al., 1992gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr17.cal/mol*KN/AHiraoka, Mori, et al., 1992gas phase; Entropy change calculated or estimated

(Nitrogen cation • 8Argon) + Argon = (Nitrogen cation • 9Argon)

By formula: (N2+ • 8Ar) + Ar = (N2+ • 9Ar)

Quantity Value Units Method Reference Comment
Δr1.52kcal/molPHPMSHiraoka, Mori, et al., 1992gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr17.cal/mol*KN/AHiraoka, Mori, et al., 1992gas phase; Entropy change calculated or estimated

(Nitrogen cation • Nitrogen) + Nitrogen = (Nitrogen cation • 2Nitrogen)

By formula: (N2+ • N2) + N2 = (N2+ • 2N2)

Quantity Value Units Method Reference Comment
Δr2.8 ± 0.2kcal/molPHPMSHiraoka and Nakajima, 1988gas phase
Δr1.4kcal/molPILinn, Ono, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Δr15.0cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation • Argon) + Argon = (Nitrogen cation • 2Argon)

By formula: (N2+ • Ar) + Ar = (N2+ • 2Ar)

Quantity Value Units Method Reference Comment
Δr3.8kcal/molPHPMSHiraoka, Mori, et al., 1992gas phase; ΔrH>
Quantity Value Units Method Reference Comment
Δr17.cal/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase; ΔrH>

(Nitrogen cation • 10Nitrogen) + Nitrogen = (Nitrogen cation • 11Nitrogen)

By formula: (N2+ • 10N2) + N2 = (N2+ • 11N2)

Quantity Value Units Method Reference Comment
Δr1.7 ± 0.2kcal/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Δr20.2cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation • 9Nitrogen) + Nitrogen = (Nitrogen cation • 10Nitrogen)

By formula: (N2+ • 9N2) + N2 = (N2+ • 10N2)

Quantity Value Units Method Reference Comment
Δr1.8 ± 0.2kcal/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Δr20.7cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation • 2Nitrogen) + Nitrogen = (Nitrogen cation • 3Nitrogen)

By formula: (N2+ • 2N2) + N2 = (N2+ • 3N2)

Quantity Value Units Method Reference Comment
Δr2.7 ± 0.2kcal/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Δr15.8cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation • 3Nitrogen) + Nitrogen = (Nitrogen cation • 4Nitrogen)

By formula: (N2+ • 3N2) + N2 = (N2+ • 4N2)

Quantity Value Units Method Reference Comment
Δr2.5 ± 0.2kcal/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Δr16.6cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation • 4Nitrogen) + Nitrogen = (Nitrogen cation • 5Nitrogen)

By formula: (N2+ • 4N2) + N2 = (N2+ • 5N2)

Quantity Value Units Method Reference Comment
Δr2.5 ± 0.2kcal/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Δr20.5cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation • 5Nitrogen) + Nitrogen = (Nitrogen cation • 6Nitrogen)

By formula: (N2+ • 5N2) + N2 = (N2+ • 6N2)

Quantity Value Units Method Reference Comment
Δr2.3 ± 0.2kcal/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Δr21.7cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation • 6Nitrogen) + Nitrogen = (Nitrogen cation • 7Nitrogen)

By formula: (N2+ • 6N2) + N2 = (N2+ • 7N2)

Quantity Value Units Method Reference Comment
Δr2.0 ± 0.2kcal/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Δr20.4cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation • 7Nitrogen) + Nitrogen = (Nitrogen cation • 8Nitrogen)

By formula: (N2+ • 7N2) + N2 = (N2+ • 8N2)

Quantity Value Units Method Reference Comment
Δr1.9 ± 0.2kcal/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Δr19.3cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation • 8Nitrogen) + Nitrogen = (Nitrogen cation • 9Nitrogen)

By formula: (N2+ • 8N2) + N2 = (N2+ • 9N2)

Quantity Value Units Method Reference Comment
Δr1.8 ± 0.2kcal/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Δr19.5cal/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation • 2Argon) + Argon = (Nitrogen cation • 3Argon)

By formula: (N2+ • 2Ar) + Ar = (N2+ • 3Ar)

Quantity Value Units Method Reference Comment
Δr1.7 ± 0.2kcal/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Δr13.7cal/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

(Nitrogen cation • 3Argon) + Argon = (Nitrogen cation • 4Argon)

By formula: (N2+ • 3Ar) + Ar = (N2+ • 4Ar)

Quantity Value Units Method Reference Comment
Δr1.7 ± 0.2kcal/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Δr17.9cal/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

(Nitrogen cation • 4Argon) + Argon = (Nitrogen cation • 5Argon)

By formula: (N2+ • 4Ar) + Ar = (N2+ • 5Ar)

Quantity Value Units Method Reference Comment
Δr1.6 ± 0.2kcal/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Δr17.0cal/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

(Nitrogen cation • 5Argon) + Argon = (Nitrogen cation • 6Argon)

By formula: (N2+ • 5Ar) + Ar = (N2+ • 6Ar)

Quantity Value Units Method Reference Comment
Δr1.6 ± 0.2kcal/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Δr17.4cal/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

(Nitrogen cation • 6Argon) + Argon = (Nitrogen cation • 7Argon)

By formula: (N2+ • 6Ar) + Ar = (N2+ • 7Ar)

Quantity Value Units Method Reference Comment
Δr1.5 ± 0.2kcal/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Δr17.3cal/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

Nitrogen cation + helium = (Nitrogen cation • helium)

By formula: N2+ + He = (N2+ • He)

Quantity Value Units Method Reference Comment
Δr0.4kcal/molPDissBieske, Soliva, et al., 1990gas phase; same ΔrH for N2+(B) and (N2+)X; ab initio, Miller, Tennyson, et al., 1988

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Nakajima, 1988
Hiraoka, K.; Nakajima, G., A Determination of the Stabilities of N2+(N2)n and O2+(N2)n with n = 1 - 11 from Measurements of the Gas - Phase Ion Equilibria, J. Chem. Phys., 1988, 88, 12, 7709, https://doi.org/10.1063/1.454285 . [all data]

Teng and Conway, 1973
Teng, H.H.; Conway, D.C., Ion - Molecule Equilibria in Mixtures of N2 and Ar, J. Chem. Phys., 1973, 59, 5, 2316, https://doi.org/10.1063/1.1680338 . [all data]

Payzant and Kebarle, 1970
Payzant, J.D.; Kebarle, P., Clustering Equilibrium N2+ + 2N2 = N4+ + N2 and the Bond Dissociation Energy of N4+, J. Chem. Phys., 1970, 53, 12, 4723, https://doi.org/10.1063/1.1674010 . [all data]

Varney, 1968
Varney, R.N., Equilibrium Constant and Rates for the Reversible Reaction N4+ -> N2+ + N2, Phys. Rev., 1968, 174, 1, 165, https://doi.org/10.1103/PhysRev.174.165 . [all data]

Varney, 1959
Varney, R.N., Molecular Ions, J. Chem. Phys., 1959, 31, 5, 1314, https://doi.org/10.1063/1.1730590 . [all data]

Kim and Bowers, 1990
Kim, H.S.; Bowers, M.T., Energetics, Structure and Photodissociation Dynamics of the Cluster Ar.N2+, J. Chem. Phys., 1990, 93, 2, 1158, https://doi.org/10.1063/1.459179 . [all data]

Hiraoka, Mori, et al., 1992
Hiraoka, K.; Mori, T.; Yamabe, S., Gas-Phase Solvation of N2+ with Ar Atoms - A Charge Switch in the Reaction N2+(Ar)...Ar+(N2), Chem. Phys. Lett., 1992, 189, 1, 7, https://doi.org/10.1016/0009-2614(92)85144-Y . [all data]

Linn, Ono, et al., 1981
Linn, S.H.; Ono, Y.; Ng, C.Y., Molecular Beam Photoionization Study of CO, N2, and NO Dimers and Clusters, J. Chem. Phys., 1981, 74, 6, 3342, https://doi.org/10.1063/1.441486 . [all data]

Bieske, Soliva, et al., 1990
Bieske, E.J.; Soliva, A.; Welker, M.A.; Maier, J.P., The B<---X Electronic Spectrum of N2+ He, J. Chem. Phys., 1990, 93, 6, 4477, https://doi.org/10.1063/1.458732 . [all data]

Miller, Tennyson, et al., 1988
Miller, S.; Tennyson, J.; Follmeg, B.; Rosmus, P.; Werner, H., Ab initio Investigation of the Bond Rovibrational States in the Electronic Ground State of HeN2+, J. Chem. Phys., 1988, 89, 4, 2178, https://doi.org/10.1063/1.455062 . [all data]


Notes

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