silicon

• Formula: Si
• Molecular weight: 28.0855
• IUPAC Standard InChI: InChI=1S/Si Copy

  
• IUPAC Standard InChIKey: XUIMIQQOPSSXEZ-UHFFFAOYSA-N Copy
• CAS Registry Number: 7440-21-3
• Chemical structure:
  This structure is also available as a 2d Mol file
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Gas phase ion energetics data
  • Ion clustering data
• Data at other public NIST sites:
  • NIST Atomic Spectra Database - Lines Holdings (on physics web site)
  • NIST Atomic Spectra Database - Levels Holdings (on physics web site)
  • NIST Atomic Spectra Database - Ground states and ionization energies (on physics web site)
  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Si₄^- • 4294967295) +  = Si₄^-

By formula: (Si₄^- • 4294967295Si) + Si = Si₄^-

(CAS Reg. No. 11080-58-3 • 4294967295) +  = CAS Reg. No. 11080-58-3

By formula: (CAS Reg. No. 11080-58-3 • 4294967295Si) + Si = CAS Reg. No. 11080-58-3

(CAS Reg. No. 106389-62-2 • 4294967295) +  = CAS Reg. No. 106389-62-2

By formula: (CAS Reg. No. 106389-62-2 • 4294967295Si) + Si = CAS Reg. No. 106389-62-2

(Si₃^- • 4294967295) +  = Si₃^-

By formula: (Si₃^- • 4294967295Si) + Si = Si₃^-

(CAS Reg. No. 64236-73-3 • 4294967295) +  = CAS Reg. No. 64236-73-3

By formula: (CAS Reg. No. 64236-73-3 • 4294967295Si) + Si = CAS Reg. No. 64236-73-3

(HSi^- • 4294967295) +  = HSi^-

By formula: (HSi^- • 4294967295Si) + Si = HSi^-

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nakajima, Taguwa, et al., 1995
Nakajima, A.; Taguwa, T.; Nakao, K.; Gomei, M.; Kishi, R.; Iwata, S.; Kaya, K., Photoelectron Spectroscopy of silicon-carbon cluster Anions (SinCm-), J. Chem. Phys., 1995, 103, 6, 2050, https://doi.org/10.1063/1.469731 . [all data]

Kawamata, Neigishi, et al., 1996
Kawamata, H.; Neigishi, Y.; Kishi, R.; Iwata, S.; Nakajima, A.; Kaya, K., Photoelectron Spectroscopy of Silicon-Fluorine Binary Cluster Anions (SinFm-), J. Chem. Phys., 1996, 105, 13, 5369, https://doi.org/10.1063/1.472377 . [all data]

Xu, Taylor, et al., 1998
Xu, C.S.; Taylor, T.R.; Burton, G.R.; Neumark, D.M., Vibrationally reserved photoelectron spectroscopy of silicon cluster anions Si-n(-) (n=3-7), J. Chem. Phys., 1998, 108, 4, 1395-1406, https://doi.org/10.1063/1.475511 . [all data]

Arnold and Neumark, 1994
Arnold, C.C.; Neumark, D.M., Threshold Photodetachment Zero-Electron Kinetic Energy Spectroscopy of Si-3(-), J. Chem. Phys., 1994, 100, 3, 1797, https://doi.org/10.1063/1.466532 . [all data]

Nimlos, Harding, et al., 1987
Nimlos, M.R.; Harding, L.B.; Ellison, G.B., The Electronic States of Si₂ and Si₂^- as Revealed by Photoelectron Spectroscopy, J. Chem. Phys., 1987, 87, 9, 5116, https://doi.org/10.1063/1.453679 . [all data]

Kasdan, Herbst, et al., 1975
Kasdan, A.; Herbst, E.; Lineberger, W.C., Laser photoelectron spectrometry of the negative ions of silicon and its hydrides, J. Chem. Phys., 1975, 62, 541. [all data]

Notes

Go To: Top, Reaction thermochemistry data, References

• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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