Ethylene oxalate
- Formula: C4H4O4
- Molecular weight: 116.0722
- IUPAC Standard InChIKey: ZNLAHAOCFKBYRH-UHFFFAOYSA-N
- CAS Registry Number: 3524-70-7
- Chemical structure:
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Condensed phase thermochemistry data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -166.6 ± 0.29 | kcal/mol | Ccb | Lebedev, Kulagina, et al., 1982 | see Lebedev, Kulagina, et al., 1981; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -346.20 ± 0.29 | kcal/mol | Ccb | Lebedev, Kulagina, et al., 1982 | see Lebedev, Kulagina, et al., 1981; Corresponding ΔfHºsolid = -166.6 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°solid,1 bar | 37.86 | cal/mol*K | N/A | Lebedev, Kulagina, et al., 1982, 2 | DH |
S°solid,1 bar | 35.78 | cal/mol*K | N/A | Lebedev, Kulagina, et al., 1982, 3 | DH |
Constant pressure heat capacity of solid
Cp,solid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
33.91 | 298.15 | Lebedev, Kulagina, et al., 1982, 2 | T = 8 to 330 K.; DH |
33.91 | 298.15 | Lebedev, Kulagina, et al., 1982, 3 | T = 8 to 330 K.; DH |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Ttriple | 415. | K | N/A | Lebedev, Kulagina, et al., 1982, 4 | Uncertainty assigned by TRC = 1. K; TRC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
3.2027 | 415. | Lebedev, Kulagina, et al., 1982, 2 | DH |
3.20 | 415. | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
7.717 | 415. | Lebedev, Kulagina, et al., 1982, 2 | DH |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lebedev, Kulagina, et al., 1982
Lebedev, B.V.; Kulagina, T.G.; Kiparisova, E.G.,
Thermodynamics of dl-lactide, ethylene oxalate, and 2,5-dioxopiperazine in the range 0-330 K.,
Russ. J. Phys. Chem. (Engl. Transl.), 1982, 56, 1641-1643. [all data]
Lebedev, Kulagina, et al., 1981
Lebedev, B.V.; Kulagina, T.G.; Kiparisova, E.G.,
Thermodynamics of 2,5-piperazinedione in the range 0-330 K,
J. Gen. Chem. USSR, 1981, 51, 174-177. [all data]
Lebedev, Kulagina, et al., 1982, 2
Lebedev, B.V.; Kulagina, T.G.; Lyudvig, Ye.B.; Ovchinnikova, T.N.,
Calorimetric study of ethylene oxalate, polyethylene oxalate and parameters of the polymerization of ethylene oxalate in the range 8-450 K,
Vysokomol. Soedin., 1982, A24, 1490-1495. [all data]
Lebedev, Kulagina, et al., 1982, 3
Lebedev, B.V.; Kulagina, T.G.; Kiparisova, Y.G.,
Thermodynamics of dl-lactide, ethylene oxalate, and 2,5-dioxopiperazine in the range 0-330 K,
Zhur. Fiz. Khim., 1982, 56, 2665-2669. [all data]
Lebedev, Kulagina, et al., 1982, 4
Lebedev, B.V.; Kulagina, T.G.; Lyudvig, Ye.B.; Ovchinnikova, T.N.,
Calorimetric study of ethylene oxalate,polyethylene oxalate and parameters of the polymerization of ethylene oxalate in the range 8-450 K,
Vysokomol. Soedin, Ser. A, 1982, 24, 1490. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid S°solid,1 bar Entropy of solid at standard conditions (1 bar) Ttriple Triple point temperature ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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