Benzene, 1-methyl-3-nitro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-46.0kJ/molCcbSwarts, 1914See 14SWA2; ALS
Quantity Value Units Method Reference Comment
Δcliquid-3723.5 ± 3.3kJ/molCcbLenchitz, Velicky, et al., 1971ALS
Δcliquid-3737.kJ/molCcbGarner and Abernethy, 1921ALS
Δcliquid-3721.9kJ/molCcbSwarts, 1914See 14SWA2; ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
202.1302.4de Kolossowsky and Udowenko, 1934DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil503.7KN/AAldrich Chemical Company Inc., 1990BS
Tboil505.8KN/AWeast and Grasselli, 1989BS
Tboil503.95KN/ALecat, 1930Uncertainty assigned by TRC = 0.4 K; not clear that this is a new measurement; TRC
Tboil504.KN/ADessart, 1926Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Tfus288.59KN/AGross, Saylor, et al., 1933Uncertainty assigned by TRC = 0.2 K; TRC
Tfus289.KN/ADessart, 1926Uncertainty assigned by TRC = 2. K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
56.6 ± 2.5303.GSWidegren and Bruno, 2010Based on data from 293. to 313. K.; AC
52.8413.EBAim, 1994Based on data from 397. to 452. K.; AC
49.8368.AStephenson and Malanowski, 1987Based on data from 353. to 505. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Swarts, 1914
Swarts, F., Sur la chaleur de combustion de quelques derives nitres aromatlques, Recl. Trav. Chim. Pays-Bas, 1914, 33, 281-298. [all data]

Lenchitz, Velicky, et al., 1971
Lenchitz, C.; Velicky, R.W.; Silvestro, G.; Schlosberg, L.P., Thermodynamic properties of several nitrotoluenes, J. Chem. Thermodyn., 1971, 3, 689-692. [all data]

Garner and Abernethy, 1921
Garner, W.E.; Abernethy, C.L., Heats of combustion and formation of nitro-compounds. Part I. - Benzene, toluene, phenol and methylaniline series, Proc. Roy. Soc. London A, 1921, 213-235. [all data]

de Kolossowsky and Udowenko, 1934
de Kolossowsky, N.; Udowenko, W.W., Determination des chaleurs specifiques des liquides, Compt. rend., 1934, 198, 1394-1395. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Lecat, 1930
Lecat, M., Azeotropism in Binary Mixtures Containing an Alcohol Mixed with an amine, a nitro derivative, an ether or water., Z. Anorg. Allg. Chem., 1930, 186, 119. [all data]

Dessart, 1926
Dessart, A., Theory of Concentrated Solutions: III. Physical Constants of Mixtures of m-Nitrotoluene and m-Toluidine with Some Hydrocarbons, Bull. Soc. Chim. Belg., 1926, 35, 9. [all data]

Gross, Saylor, et al., 1933
Gross, P.M.; Saylor, J.H.; Gorman, M.A., Solubility studies: IV the solubilities of certain slightly soluble organic compounds in water, J. Am. Chem. Soc., 1933, 55, 650-2. [all data]

Widegren and Bruno, 2010
Widegren, Jason A.; Bruno, Thomas J., Gas Saturation Vapor Pressure Measurements of Mononitrotoluene Isomers from (283.15 to 313.15) K «8224», J. Chem. Eng. Data, 2010, 55, 1, 159-164, https://doi.org/10.1021/je900293j . [all data]

Aim, 1994
Aim, Karel, Saturated Vapor Pressure Measurements on Isomeric Mononitrotoluenes at Temperatures between 380 and 460 K, J. Chem. Eng. Data, 1994, 39, 3, 591-594, https://doi.org/10.1021/je00015a044 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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